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Effect of Tensile Loading and Temperature on the Hydrogen Solubility of Steels at High Gas Pressure
- The hydrogen solubility in ferritic and martensitic steels is affected by hydrostatic stress, pressure, and temperature. In general, compressive stresses decrease but tensile stresses increase the hydrogen solubility. This important aspect must be considered when qualifying materials for high‐pressure hydrogen applications (e.g., for pipelines or tanks) by using autoclave systems. In this work, a pressure equivalent for compensating the effect of compressive stresses on the hydrogen solubility inside of closed autoclaves is proposed to achieve solubilities that are equivalent to those in pipelines and tanks subjected to tensile stresses. Moreover, it is shown that the temperature effect becomes critical at low temperatures (e.g., under cryogenic conditions for storing liquid hydrogen). Trapping of hydrogen in the microstructure can increase the hydrogen solubility with decreasing temperature, having a solubility minimum at about room temperature. To demonstrate this effect, theThe hydrogen solubility in ferritic and martensitic steels is affected by hydrostatic stress, pressure, and temperature. In general, compressive stresses decrease but tensile stresses increase the hydrogen solubility. This important aspect must be considered when qualifying materials for high‐pressure hydrogen applications (e.g., for pipelines or tanks) by using autoclave systems. In this work, a pressure equivalent for compensating the effect of compressive stresses on the hydrogen solubility inside of closed autoclaves is proposed to achieve solubilities that are equivalent to those in pipelines and tanks subjected to tensile stresses. Moreover, it is shown that the temperature effect becomes critical at low temperatures (e.g., under cryogenic conditions for storing liquid hydrogen). Trapping of hydrogen in the microstructure can increase the hydrogen solubility with decreasing temperature, having a solubility minimum at about room temperature. To demonstrate this effect, the generalized law of the hydrogen solubility is parameterized for different steels using measured contents of gaseous hydrogen. The constant parameter sets are verified and critically discussed with respect to the high‐pressure hydrogen experiments.…
Autor*innen: | A.-K. DrexlerORCiD, Florian Konert, Jonathan Nietzke, E. Hodžić, S. Pastore, J. Domitner, Michael RhodeORCiD, C. Sommitsch, Thomas Böllinghaus |
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Dokumenttyp: | Zeitschriftenartikel |
Veröffentlichungsform: | Verlagsliteratur |
Sprache: | Englisch |
Titel des übergeordneten Werkes (Englisch): | Steel Research International |
Jahr der Erstveröffentlichung: | 2023 |
Organisationseinheit der BAM: | 9 Komponentensicherheit |
9 Komponentensicherheit / 9.0 Abteilungsleitung und andere | |
Veröffentlichende Institution: | Bundesanstalt für Materialforschung und -prüfung (BAM) |
Verlag: | Wiley |
Aufsatznummer: | 202300493 |
Erste Seite: | 1 |
Letzte Seite: | 9 |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten |
Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Angewandte Physik | |
Freie Schlagwörter: | Analytical calculation; Hydrogen; Solubility; Temperature; Tensile loading |
Themenfelder/Aktivitätsfelder der BAM: | Energie |
Energie / Wasserstoff | |
Material | |
Material / Degradation von Werkstoffen | |
DOI: | 10.1002/srin.202300493 |
URN: | urn:nbn:de:kobv:b43-586701 |
ISSN: | 1611-3683 |
Verfügbarkeit des Dokuments: | Datei für die Öffentlichkeit verfügbar ("Open Access") |
Lizenz (Deutsch): | Creative Commons - CC BY - Namensnennung 4.0 International |
Datum der Freischaltung: | 26.10.2023 |
Referierte Publikation: | Ja |
Datum der Eintragung als referierte Publikation: | 06.11.2023 |
Paper des Monats: | Ja |
Schriftenreihen ohne Nummerierung: | Wissenschaftliche Artikel der BAM |