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Dieses Dokument fasst den Projektfortschritt des BAM-Projektes "Hybrider Einsatz von LTT-Schweißzusätzen zur Schwingfestigkeitsverbesserung hochfester Stahlbauteile" im Rahmen des Sitzung des DVS Fachausschuss FA09 - Konstruktion und Festigkeit für die Projektquartale Q4 2025 und Q1 2026 zusammen und stellt die wichtigsten Ergebnisse in Kurzform vor.
Towards the Use of Representative Specimens for the Qualification of Additively Manufactured Parts
(2024)
The understanding of the process-structure-property-performance relationship is the key challenge for the qualification of safety-relevant parts made of additively manufactured metallic materials. The complexity of the manufacturing process and the number of influencing parameters affect the properties of test coupons and parts even fabricated in the same batch. This poses the problem of using reliable witness specimens for part qualification.
This work presents a new approach which aims at the fabrication of test coupons tailored to the specific microstructure and fatigue properties of a component. The first step consisted in the evaluation of the temperature field by means of process monitoring during the production of parts. The results were used to tailor finite element models which were then used to design witness specimens representative of the thermal history in the component. Finally, the fatigue properties of designed specimens were compared to coupons machined out of the component.
This study examines the impact of varying oxidation levels in nickel-based Haynes 282 powder on particle degradation during laser powder bed fusion (PBF-LB|M). Four powder batches with oxygen content levels of approximately from 140 ppm to1400 ppm were processed using PBF-LB|M. A powder collection container was fabricated to sample unmelted powder from heat-affected regions of the powder bed. Recoating and melting proceeded without issues; however, increased fume emissions were observed at higher oxidation levels, indicating intensified spatter formation. Post-process analysis revealed that finer particles exhibited greater surface oxidation due to their higher surface-to-volume ratio. Despite significant oxygen uptake, chemical analysis showed no measurable changes in key alloying elements in either the unmelted or spatter particles. Additionally, changes in particle size distribution became more pronounced at high oxidation levels. These findings provide a basis for understanding oxidation-driven degradation and optimizing powder reuse strategies to maintain material performance.
Green hydrogen has become an essential energy carrier to achieve a climate-neutral economy. The production, storage, transport and usage of green hydrogen require safe and sustainable facilities and systems. The present contribution provides a procedure guideline to investigate the compatibility of steel welds for pressurised gaseous hydrogen applications under quasi-static mechanical loads, utilising the slow strain rate test and hollow specimen technique. Exemplarily, a weld of the low-alloyed steel P355NL1 was investigated and compared to an X65 weld. The results indicate that the base metal exhibits a higher ductility than the weld metal for both steels. Generally, hydrogen-exposed specimens exhibited a reduced strain, as compared to reference specimens. The hydrogen degradation, evaluated by the hydrogen embrittlement index, was more pronounced in the weld metal compared to the base P355NL1 material, whereas the X65 exhibited a larger hydrogen degradation of the base material than in the weld metal. Fractographic analysis of the test specimens revealed that hydrogen causes a transition from ductile to brittle features. Generally, the results of this study indicate a mild but significant degradation of the mechanical properties in terms of the ductility of the welds in the respective pressurised hydrogen atmosphere.
Designing an effective drilling mud is a critical aspect of the drilling process. A well-designed drilling mud should not only provide efficient mud hydraulics but also fulfill three important functions: enhancing mud rheology, inhibiting hydrate formation in deepwater drilling, and suppressing shale swelling when drilling through shale formations. Achieving these functions often requires the use of various additives, but these additives are often expensive, non-biodegradable, and have significant environmental impacts. To address these concerns, researchers have explored the potential applications of ionic liquids and deep eutectic solvents in drilling mud design, which have shown promising results. However, an even more environmentally friendly alternative has emerged in the form of natural deep eutectic solvents (NADES). This research focuses on an in-house-prepared NADES based on calcium chloride and glycerine, with a ratio of 1:4, prepared at 60 °C, and utilizes it as a drilling mud additive following the API 13 B-1 standards and checks its candidacy as a rheology modifier, hydrates, and shale inhibitor. The findings of the study demonstrate that the NADES-based mud significantly improves the overall yield point to plastic viscosity ratio (YP/PV) of the mud, provides good gel strength, and inhibits hydrate formation by up to 80%. Additionally, it has shown an impressive 62.8% inhibition of shale swelling while allowing for 84.1% improved shale recovery. Moreover, the NADES-based mud exhibits a 28% and 25% reduction in mud filtrate and mud cake thickness, respectively, which is further supported by the results of XRD, zeta potential, and surface tension. Based on these positive outcomes, the calcium chloride–glycerine NADES-based mud is recommended as a versatile drilling mud additive suitable for various industrial applications. Furthermore, it presents a more environmentally friendly option compared to traditional additives, addressing concerns about cost, biodegradability, and environmental impact in the drilling process for an ultimate global impact.
Mechanische Eigenschaften der Längsschweissnaht einer X65-Pipeline in Druckwasserstoffatmosphäre
(2024)
Die stetig steigende Nachfrage nach erneuerbaren Energieträgern führt dazu, dass große Mengen an Wasserstoff transportiert werden müssen. Da Pipelines eine kostengünstige Möglichkeit zur Verteilung von gasförmigem Wasserstoff bieten, muss die Wechselwirkung zwischen Wasserstoff und den Rohrleitungsmaterialien sorgfältig untersucht werden, da Wasserstoff unter bestimmten Bedingungen eine Verschlechterung der mechanischen Eigenschaften bewirken kann.
Insbesondere Schweißnähte, von denen man annimmt, dass sie anfälliger für die Degradation durch Wasserstoff sind, sind von großem Interesse. Ziel dieser Studie ist es, die Auswirkungen von gasförmigem Wasserstoff auf die mechanischen Eigenschaften einer X65-Rohrleitung und der längs verlaufenden Unterpulverschweißnaht zu untersuchen. Die Prüfungen werden mit Hilfe der Hohlkörpertechnik an zwei Arten von Proben durchgeführt: eine aus dem Grundwerkstoff (GW) und die andere als Querzugprobe (QZ), bestehend aus Grundwerkstoff und Schweißnaht, entnommen. Die Proben werden in-situ mit einem Druck von 60 bar beaufschlagt und in Zugversuchen mit langsamer Dehnrate (SSR) und einer nominellen Dehnrate von 10-5 s-1 geprüft. Die durchgeführten Versuche zeigen eine Verringerung der Einschnürung (RA) von 72 % in inerter Atmosphäre auf 52 % in Wasserstoffatmosphäre für die QZ-Probe und einen Rückgang von 73 % in inerter Atmosphäre auf 51 % für die GW-Probe. Metallographische Analysen zeigten die Rissbildung zwischen der feinkörnigen Wärmeeinflusszone (FGHAZ) und des GW sowohl für die in Wasserstoffatmosphäre geprüften Proben als auch für die Vergleichsproben. Dies lässt den Schluss zu, dass sich der Ort der Rissentstehung durch die Anwesenheit von gasförmigem Wasserstoff nicht ändert.
Die klassische Prüfung der verzögerten, wasserstoffunterstützten Kaltrissbildung von Schweißnähten umfasst mehr als 200 mögliche Prüfverfahren. Von diesen hat aber nur ein kleiner Teil praktische Bedeutung. Unabhängig davon, sind die Prüfverfahren typischerweise auf kleine Bauteilgeometrien beschränkt bzw. hinsichtlich ihrer Anwendungsfähigkeit für große Struktruren oder dickwandige, UP-geschweißte Komponenten wie Monopiles. Als Gründundgsstrukturen für Offshore-Windenergieanlagen können die Monopiles Größen bis zu 9 m Durchmesser, Längen bis zu 100 m, bei Gewichten bis zu 1.300 t erreichen. Hier ist eine Prüfung auf verzögerte Kaltrissbildung schwer durchführbar bzw. muss eine Wartezeit von bis zu 48 h eingehalten werden. Die voliegenende Präsentation gibt einen Überblick über an der BAM entwickelte Demonstratorgeometrien um eine praktikable Kaltrissprüfung auf Laborebene zu ermöglichen. Allerdings unter Beibehaltung der realen Steifigkeits- und Wärmeableitungsbedingungen, wie bei realen Großkomponenten. Zusätzlich wird ein Überblick über die Möglichkeiten von Wasserstoffdiffusionsmessungen zur Ermittlung von Diffusionskoeffizienten gegeben, die wiederum Anwendung in der numerischen Simulation der Wasserstoffdiffusion finden.
The implementation of hydrogen as an alternative energy source to fossil fuels necessitates the use of compatible materials for safety purposes, and thermoplastics are widely utilized in this context. The application of polymers in gaseous and liquid hydrogen environments requires careful consideration of their tribological performance, as the operating environment is dramatically different from ambient conditions. Friction, wear, and lubrication are crucial factors to consider in this regard. Researchers have investigated various strategies to enhance the tribological performance of polymers in hydrogen environments, including modifying the composition and structure of polymers by incorporating fillers to improve their friction and wear resistance.
The tribological properties of polymer composites based on matrices of PEEK, PPS, and PI have been mostly investigated using the continuous sliding test method, and the results indicate that these materials are suitable candidates for tribological applications in both gaseous and liquid hydrogen. This project explores the tribological properties of related polymer composites in hydrogen using continuous and reciprocating motion with a pin-on-disc testing method.
Offshore Wind Turbines (OWT) are a key factor in tomorrow's sustainable energy generation. The ever-increasing installation depth and weight of OWTs require suitable foundation concepts such as monopiles or tripods. Typically, mild steels such as S420ML are used with plate thicknesses of up to several hundred mm, resulting in high restraints in the welded joints. The large plate thickness requires high-efficiency welding processes such as submerged arc welding (SAW) with multiple wires. Due to the very high stiffness and plate thickness of the large-scale offshore structure, a susceptibility to time-delayed hydrogen assisted cracking (HAC) may occur. The evaluation of this crack susceptibility is very complex due to the component size and stiffness of real offshore structures. For this purpose, a near-component test geometry was developed to transfer the real stiffness conditions to laboratory (i.e. workshop) scale. The 350 kg mock-up studied consisted of heavy plates (thickness 50 mm, seam length 1,000 m) joined by a 22-pass submerged-arc weld. Additional stiffeners simulated the effect of high restraint or shrinkage restraint of the weld. Extreme scenarios of hydrogen absorption during welding were simulated by using flux in dry (HD < 5 ml/100g Fe) and wet (HD > 15 ml/100g Fe) conditions. Weld residual stresses were determined using a robotic X-ray diffractometer. Areas of critical tensile residual stress (at the level of the yield strength) were found in the weld metal and in the heat affected zone, suggesting that these weld sub-zones are the most critical in the case of hydrogen ingress. To identify possible delayed cracking, the welds were tested by phased array ultrasonic testing (PAUT) after welding, 6 h, 12 h, 24 h, and a maximum of 48 h. Summarized, no significant occurrence of HAC was detected, indicating the high crack resistance of the welded joint, i.e., a suitable combination of base material, welding consumable and parameters.
In Neutron-Bragg-Edge Imaging (NBEI) experiments, we studied the phase transition during butt-welding of martensitic Low Temperature Transformation (LTT) Steel [1]. Tungsten inert gas (TIG) welding was used with a moveable torch allowing for automated weldments. The austenitization in the heat affected zone (HAZ) underneath the welding head could be clearly visualized at λ = 0.39 nm, a wavelength smaller than the Bragg edge wavelengths of both austenite and martensite. Also, the re-transformation upon cooling from austenite into martensitic phase was detected. However, we observed an unexpected additional change in transmission at λ = 0.44 nm that is a wavelength larger than the wavelength of the Bragg edges of both the martensitic and austenitic phases. We attribute this change to the Deybe-Waller-Factor that describes the temperature dependence of coherent scattering at a crystal lattice [2]. The observed two-dimensional attenuation map corresponds well with a temperature distribution modelling by software macros in ANSYS [3]. Here, the absolute temperature values could be achieved by calibrating the modelled attenuation with help of a thermocouple placed at the steel sample plate. This allows in return for a direct two-dimensional temperature reading based on the Debye-Waller-relation between neutron attenuation and sample temperature.