Multi-principal element alloy nanoparticle (MPEA-NP) electrocatalysts prepared by pulsed laser ablation for electroreduction of CO2
- The motivation and overall objective of the project are to develop electrocatalysts that are free of noble metals (e.g., Pt or Au) and are instead based on medium and high entropy alloys (MEA\HEA) of transition metals for the electrochemical reduction of CO2. The MEA\HEA are multi principal element alloys (MPEAs) consisting of more than three elements with almost equal alloying proportions, forming solid solutions without intermetallic phases. In such a crystal structure, the individual elements are well mixed, and each atom has different nearest neighbours. In catalysis, especially in selectivity, it is precisely this atomic chaos that matters. Due to the large number of possible combinations of elements, these materials offer excellent conditions to tune their functional properties for specific applications. Especially, catalyst systems in which Cu is combined with another metallic component show a significant increase in catalytic efficiency compared to monometallic systems. SinceThe motivation and overall objective of the project are to develop electrocatalysts that are free of noble metals (e.g., Pt or Au) and are instead based on medium and high entropy alloys (MEA\HEA) of transition metals for the electrochemical reduction of CO2. The MEA\HEA are multi principal element alloys (MPEAs) consisting of more than three elements with almost equal alloying proportions, forming solid solutions without intermetallic phases. In such a crystal structure, the individual elements are well mixed, and each atom has different nearest neighbours. In catalysis, especially in selectivity, it is precisely this atomic chaos that matters. Due to the large number of possible combinations of elements, these materials offer excellent conditions to tune their functional properties for specific applications. Especially, catalyst systems in which Cu is combined with another metallic component show a significant increase in catalytic efficiency compared to monometallic systems. Since the catalytic activity, selectivity, and stability of electrocatalysts strongly depend on the size and surface, systematic studies on the influence of the organic stabilizers on heterogeneous catalysis are also of interest. The focus of this project is to design Cu-based MEA\HEA electrocatalysts on the atomic level. For this purpose, base alloys will be prepared, processed into high-purity nanoparticles by pulsed laser ablation, and tested as electrocatalysts.…
Autor*innen: | Salmin Sediqi |
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Koautor*innen: | Ozlem Ozcan, Julia Witt |
Dokumenttyp: | Posterpräsentation |
Veröffentlichungsform: | Präsentation |
Sprache: | Englisch |
Jahr der Erstveröffentlichung: | 2023 |
Organisationseinheit der BAM: | 6 Materialchemie |
6 Materialchemie / 6.2 Material- und Oberflächentechnologien | |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten |
Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Angewandte Physik | |
Freie Schlagwörter: | CCMat; Chemically Complex Materials; Electrocatalysis |
Themenfelder/Aktivitätsfelder der BAM: | Energie |
Energie / Elektrische Energiespeicher und -umwandlung | |
Material | |
Material / Materialdesign | |
Veranstaltung: | Tag der Chemie 2023 |
Veranstaltungsort: | Berlin, Germany |
Beginndatum der Veranstaltung: | 05.07.2023 |
Verfügbarkeit des Dokuments: | Datei im Netzwerk der BAM verfügbar ("Closed Access") |
Datum der Freischaltung: | 23.01.2024 |
Referierte Publikation: | Nein |