Andreas Schönhals, Paulina Szymoniak, Mohamed Aejaz Kolmangadi, Martin Böhning, M. Zamponi, B. Frick, M. Appel, G. Günther, M. Russina, D. Alentiev, M. Bermeshev, R. Zorn
- The molecular dynamics of addition-type poly(tricyclononenes) with Si-substituted bulky side groups has been investigated by a combination of neutron time-of-flight and neutron backscattering spectroscopy methods on a time scale from 0.1 ps to ca. 3 ns. The investigated poly(tricyclononenes) PTCNSi1 and PTCNSi2g both bear a high microporosity which makes them promising candidates for active separation layers for gas separation membranes. At least for larger gas molecules it is assumed that the pathways for diffusion require an enlargement of pre-existing micropores in terms of an activated zone. A low temperature relaxation process was found for both polymers by the performed neutron scattering experiments. This process was assigned to the methyl group rotation. It was analysed in terms of a jump diffusion in a three-fold potential. The analysis of the dependence of the elastic incoherent structure factor on the scattering vector yields the number of methyl groups which might beThe molecular dynamics of addition-type poly(tricyclononenes) with Si-substituted bulky side groups has been investigated by a combination of neutron time-of-flight and neutron backscattering spectroscopy methods on a time scale from 0.1 ps to ca. 3 ns. The investigated poly(tricyclononenes) PTCNSi1 and PTCNSi2g both bear a high microporosity which makes them promising candidates for active separation layers for gas separation membranes. At least for larger gas molecules it is assumed that the pathways for diffusion require an enlargement of pre-existing micropores in terms of an activated zone. A low temperature relaxation process was found for both polymers by the performed neutron scattering experiments. This process was assigned to the methyl group rotation. It was analysed in terms of a jump diffusion in a three-fold potential. The analysis of the dependence of the elastic incoherent structure factor on the scattering vector yields the number of methyl groups which might be immobilized. For PTCNSi1 (3 methyl groups in the monomeric unit) it was found that all methyl groups take part in the methyl group rotation whereas for PTCNSi2g (6 methyl groups in monomeric unit) a considerable number of methyl groups are blocked in their rotation. This immobilization of methyl groups is due to the sterically demanding arrangement of the methyl groups in PTCNSi2g. This conclusion is further supported by the result that the activation energy for the methyl group rotation is three times higher for PTCNSi2g than that of PTCNSi1.…
MetadatenAutor*innen: | Andreas SchönhalsORCiD, Paulina SzymoniakORCiD, Mohamed Aejaz Kolmangadi, Martin BöhningORCiD, M. Zamponi, B. Frick, M. Appel, G. Günther, M. Russina, D. Alentiev, M. Bermeshev, R. Zorn |
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Dokumenttyp: | Zeitschriftenartikel |
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Veröffentlichungsform: | Verlagsliteratur |
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Sprache: | Englisch |
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Titel des übergeordneten Werkes (Englisch): | Journal of Membrane Science |
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Jahr der Erstveröffentlichung: | 2021 |
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Organisationseinheit der BAM: | 6 Materialchemie |
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| 6 Materialchemie / 6.6 Physik und chemische Analytik der Polymere |
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| 7 Bauwerkssicherheit |
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| 7 Bauwerkssicherheit / 7.5 Technische Eigenschaften von Polymerwerkstoffen |
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Verlag: | Elesevier B.V. |
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Jahrgang/Band: | 642 |
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Aufsatznummer: | 119972 |
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DDC-Klassifikation: | Naturwissenschaften und Mathematik / Chemie / Analytische Chemie |
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| Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten |
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| Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Angewandte Physik |
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Freie Schlagwörter: | Gas separation membranes; Highly permeably polynorbornenes; Polymers of intrinsic microporosity; Quasielastic neutron scattering |
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Themenfelder/Aktivitätsfelder der BAM: | Chemie und Prozesstechnik |
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| Energie |
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| Energie / Wasserstoff |
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| Material |
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DOI: | 10.1016/j.memsci.2021.119972 |
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ISSN: | 0376-7388 |
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Verfügbarkeit des Dokuments: | Datei im Netzwerk der BAM verfügbar ("Closed Access") |
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Datum der Freischaltung: | 13.10.2021 |
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Referierte Publikation: | Ja |
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Datum der Eintragung als referierte Publikation: | 17.11.2021 |
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