Enhanced characterization of pore systems by simultaneous use of SIP, µ-CT and NMR

  • Other than commonly assumed the relaxation times observed in the electrical low-frequency range (1 mHz – 40 kHz) of natural porous media like sandstones and tuff stones cannot be directly related to the dominant (modal) pore throat sizes, measured (e.g.) with mercury intrusion porosimetry (MIP). Working with a great variety of sandstones from very different origins and featuring great variations in textural and chemical compositions as well as in geometrical pore space properties, we observed that particularly samples with narrow pore throats were characterized by long (low-frequency) relaxations. These, however, can (following the current theories) be rather explained by long “characteristic length scales” in these media or low diffusion coefficients along the electrical double layer. However, there is no straightforward way (or single approved method) of getting reliable numbers for properties such as the lengths of pore throats, the diameter and length of the wide pores and theirOther than commonly assumed the relaxation times observed in the electrical low-frequency range (1 mHz – 40 kHz) of natural porous media like sandstones and tuff stones cannot be directly related to the dominant (modal) pore throat sizes, measured (e.g.) with mercury intrusion porosimetry (MIP). Working with a great variety of sandstones from very different origins and featuring great variations in textural and chemical compositions as well as in geometrical pore space properties, we observed that particularly samples with narrow pore throats were characterized by long (low-frequency) relaxations. These, however, can (following the current theories) be rather explained by long “characteristic length scales” in these media or low diffusion coefficients along the electrical double layer. However, there is no straightforward way (or single approved method) of getting reliable numbers for properties such as the lengths of pore throats, the diameter and length of the wide pores and their respective distributions. Consequently we follow a multi-methodical approach and combine the benefits of MIP, micro-computed tomography (µ-CT) and nuclear magnetic resonance (NMR) to achieve much deeper insight due to the different resolutions and sensitivities to either pore constrictions (throats) or wide pores. This helps us to understand, whether the observed electrical relaxation phenomena actually depend on geometric length scales or rather on other properties such as chemical composition, clay content, clay type or cation exchange capacity. Our poster showcases selected results of a systematic study on texturally and petrophysically very different sandstones.zeige mehrzeige weniger

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Metadaten
Autor*innen:Sabine KruschwitzORCiD
Koautor*innen:M. Halisch, R. Dlugosch, Carsten Prinz
Dokumenttyp:Posterpräsentation
Veröffentlichungsform:Präsentation
Sprache:Englisch
Jahr der Erstveröffentlichung:2018
Organisationseinheit der BAM:8 Zerstörungsfreie Prüfung
8 Zerstörungsfreie Prüfung / 8.0 Abteilungsleitung und andere
DDC-Klassifikation:Naturwissenschaften und Mathematik / Chemie / Analytische Chemie
Freie Schlagwörter:NMR; Pore size distribution; Spectral induced polarzation; µ-CT
Themenfelder/Aktivitätsfelder der BAM:Chemie und Prozesstechnik
Veranstaltung:5th Int. Workshop on Induced Polarization
Veranstaltungsort:Rutgers, The State University of New Jersey, Newark, NJ, USA
Beginndatum der Veranstaltung:03.10.2018
Enddatum der Veranstaltung:05.10.2018
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:24.10.2018
Referierte Publikation:Nein
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