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Hydration and crystallization of Portland cement at 100 C

  • For the construction of hot water storage tanks, ultra high performance concrete proofed to be a suitable building material to ensure water tightness. Common storage tanks build with concrete are designed to endure temperatures up to 90 °C. To increase the energy efficiency however, modern tanks need to withstand temperatures above 100 °C. With increasing temperature and correlating water vapor pressures, the cement must meet new requirements. Thermodynamic modelling is a promising tool for predicting the phase stabilities of minerals in the cement within these temperature and pressure ranges (T/P). Thus, mixture designs can be investigated and optimized with regard to the expected mineral phases in selected T/P-ranges. Additionally, predictions of the long-term material behavior can be derived from thermodynamic data and subsequently the experimental effort can be reduced notably. On the other hand, validation of predictions is needed. The base for the thermodynamic model is aFor the construction of hot water storage tanks, ultra high performance concrete proofed to be a suitable building material to ensure water tightness. Common storage tanks build with concrete are designed to endure temperatures up to 90 °C. To increase the energy efficiency however, modern tanks need to withstand temperatures above 100 °C. With increasing temperature and correlating water vapor pressures, the cement must meet new requirements. Thermodynamic modelling is a promising tool for predicting the phase stabilities of minerals in the cement within these temperature and pressure ranges (T/P). Thus, mixture designs can be investigated and optimized with regard to the expected mineral phases in selected T/P-ranges. Additionally, predictions of the long-term material behavior can be derived from thermodynamic data and subsequently the experimental effort can be reduced notably. On the other hand, validation of predictions is needed. The base for the thermodynamic model is a thermodynamic equilibrium and thus, the experimental data for validation should approach the presumed conditions of the equilibrium. This study investigates variable experimental conditions for the hydration of Portland cement at 100 °C to reach a sufficiently progressed development of the phase composition. In case of Portland cement, the highest degree of hydration achievable within a reasonable time span is the most significant parameter. Therefore, Portland cement pastes with w/c ratios from 0.4 to 0.6 and dwell times up to three weeks were examined with powder X-ray diffraction to identify mineral phase changes. At 100 °C and high humidity, Portland cement paste shows the expected mineral phases like portlandite, katoite, and remaining clinker phases. The cement pastes with high water content and long dwell time seem to have the highest degree of hydration, even though the AFm phases stabilize with increasing w/c ratio. A dwell time of two weeks and a w/c ratio of 0.5 was found to provide the mineral composition with the highest degree of hydration including the major phase transitions.zeige mehrzeige weniger

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Metadaten
Autor*innen:Marieke Voigt
Koautor*innen:T. Hirsch, Birgit Meng, D. Stephan
Dokumenttyp:Vortrag
Veröffentlichungsform:Präsentation
Sprache:Englisch
Jahr der Erstveröffentlichung:2022
Organisationseinheit der BAM:7 Bauwerkssicherheit
7 Bauwerkssicherheit / 7.1 Baustoffe
DDC-Klassifikation:Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten
Freie Schlagwörter:High temperature; Hydration; Portland cement
Themenfelder/Aktivitätsfelder der BAM:Material
Veranstaltung:4th International Conference on the Chemistry of Construction Materials (ICCCM)
Veranstaltungsort:Karlsruhe, Germany
Beginndatum der Veranstaltung:26.09.2022
Enddatum der Veranstaltung:28.09.2022
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:23.01.2023
Referierte Publikation:Nein
Eingeladener Vortrag:Nein
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