Structure analysis of dispersible SnO2 nanoparticlesStructure analysis of dispersible SnO2 nanoparticles
- Previous work in the Dunne Group targeted dispersibility of metal oxide nanoparticles, which had been synthesised via an aqueous sol-gel route. Dispersibility was attained by solvothermal surface modification of the particles with trifluoro acetic acid (TFA). Part of the studies were tin oxide particles, which is known for its predominant rutile phase. Besides the dispersibility in acetone of the particles, an unexpected peak splitting of the (110) reflection was observed, which could be an unknown phase of SnO2 . For crystal growth long-term reaction studies on the tin oxide particles were performed. Interestingly these studies exhibited a time dependent extend of the peak splitting observed in XRD characterisation. Further extended analysis using multinuclear solid-state MAS-NMR spectroscopy indicate a size dependent structure change due to partial fluorination of the particles during the solvothermal treatment.
Autor*innen: | Christian HeinekampORCiD |
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Koautor*innen: | P. W. Dunne, N. Pinna |
Dokumenttyp: | Posterpräsentation |
Veröffentlichungsform: | Präsentation |
Sprache: | Englisch |
Jahr der Erstveröffentlichung: | 2022 |
Organisationseinheit der BAM: | 6 Materialchemie |
6 Materialchemie / 6.3 Strukturanalytik | |
DDC-Klassifikation: | Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten |
Freie Schlagwörter: | Nanoparticles; SnO2 |
Themenfelder/Aktivitätsfelder der BAM: | Material |
Material / Materialdesign | |
Veranstaltung: | SALSA Make and Measure 2022 |
Veranstaltungsort: | Online meeting |
Beginndatum der Veranstaltung: | 07.09.2022 |
Enddatum der Veranstaltung: | 07.09.2022 |
Verfügbarkeit des Dokuments: | Datei im Netzwerk der BAM verfügbar ("Closed Access") |
Datum der Freischaltung: | 24.03.2023 |
Referierte Publikation: | Nein |