Filtern
Erscheinungsjahr
- 2015 (2295) (entfernen)
Dokumenttyp
- Vortrag (1030)
- Zeitschriftenartikel (463)
- Posterpräsentation (398)
- Beitrag zu einem Tagungsband (301)
- Forschungsbericht (26)
- Dissertation (19)
- Beitrag zu einem Sammelband (18)
- Buchkapitel (15)
- Sonstiges (13)
- Zeitschriftenheft (Herausgeberschaft für das komplette Heft) (5)
Sprache
- Deutsch (1566)
- Englisch (722)
- Mehrsprachig (6)
- Französisch (1)
Schlagworte
- Concrete (17)
- Corrosion (17)
- Monitoring (15)
- Non-destructive testing (13)
- Nanoparticles (11)
- Simulation (11)
- Prozessanalytik (10)
- Zerstörungsfreie Prüfung (10)
- Fluorescence (9)
- Ultrasound (9)
Eingeladener Vortrag
- nein (1030)
The ground vibrations, which are generated by trains on different tracks, have been calculated by finite-element boundary-element models. The ballasted track is modelled in detail by the finite element method. The infinite soil is modelled by the boundary element method as a homogeneous or layered half-space. The track-soil system is coupled to a simple rigid mass model of the vehicle so that the vehicle-track interaction is completely included. Transfer functions are calculated in frequency domain without and with vehicle-track interaction, the compliance of the track and the mobilities of the soil at different distances from the track. Finally, the ratios between the ground vibration amplitudes with and without mitigation measures are calculated to quantify the effectiveness of the mitigation measures.
Tracks with under-sleeper pads have been investigated in a wide parameter study for the RIVAS project. The main parameters that influence the reduction of ground vibration are the stiffness of the under-sleeper pad, the mass and the width of the sleeper. The softest sleeper pad yields the best reduction of the ground vibration. The influence of the sleeper mass is not so strong, as the characteristic frequency is ruled by the mass of the sleeper and the mass of the wheelset as well.
Behavior of dust/air mixtures is very complex and difficult to predict since it depends on material properties as well as boundary conditions. Without other influences airborne particles deposit due to gravity but the time it takes for total deposition as well as easiness of resurrection depends very much on the specific dust sample and the boundary conditions. It still lacks a complete understanding of all interacting reasons and one approach is using experimentally determined characteristics, one is named dustiness.
Dustiness is the tendency of dust to form clouds and to stay airborne. Dustiness is determined with two basic principles, which are light attenuation and ratio of filled-in and measured mass. Assessment of dustiness of industrial powders has been done for a long time regarding work place safety. Dustiness is used there to determine inhalable fraction and to evaluate health risks. Lately it became interesting in dust explosion protection as well. Dustiness could be used to optimize determination of zones, adaption of venting area and/or for positioning of suppression systems.
Dustiness can be useful in many ways but is not a physical property of dusts, therefore it depends on material properties such as density, particle size distribution, shape and water content as well as boundary conditions or determination method. This makes it very difficult to compare dustiness for different techniques and apparatuses and determination method as well as results should be considered carefully. This work gives an overview of existing standards, recent research and suggests improvements to the new dustiness as proposed for dust explosion protection.
Pd/TiO2 coatings with template-controlled mesopore structure as highly active hydrogenation catalyst
(2015)
Micro-structured reactors offer excellent mass and heat transport capabilities and can therefore sustain very high reaction rates and space–time-yields also for highly exothermic catalytic reactions. However, such high rates cannot be reached when the reactors are coated or filled with conventional catalysts powders. We present a strategy for the direct synthesis of highly active wall-coated supported catalysts via co-deposition of a pore template (here micelles formed from PEO-b-PPO-b-PEO) and a precursors for the metal oxide (TiCl4) along with a compatible precursor for the active metal (PdCl2). The obtained catalytic coatings possess a template-controlled open pore structure and excellent mechanical stability. Moreover, the active metal is highly dispersed and well-distributed across the coating also at high Pd loadings. The corresponding high activity along with rapid mass transfer enabled by the open pore system results in the best space–time-yields in the gas-phase hydrogenation of butadiene reported so far in literature for a supported catalyst.
The hepatotoxin phomopsin A (PHO-A), a secondary metabolite mainly produced by the fungus Diaporthe toxica, occurs predominantly on sweet lupins. Along with the growing interest in sweet lupins for food and feed commodities, concerns have been raised about fungal infestations, and consequently, about the determination of PHO-A.
High performance liquid chromatography coupled to tandem mass spectrometry (LC-MS/MS) represents the most suitable analytical technique for sensitive and selective detection of mycotoxins including PHO-A. However, isotopic labeled substances are needed as internal standards for a reliable and convenient quantification.
As no isotope standard for PHO-A is currently available, a biosynthesis of fully 15N6-labeled PHO-A was established by cultivation of D. toxica on defined media containing Na15NO3 and 15N-labeled yeast extract as the only nitrogen sources. The identity of 15N6-PHO-A was confirmed by high resolution mass spectrometry.
The new 15N6-labeled standard will facilitate the method development for PHO-A including a more accurate quantification by LC-MS/MS.
Für Spannstähle muss im Rahmen der Überwachung die Beständigkeit gegenüber Spannungsrisskorrosion nach DIN EN ISO 15630-3 nachgewiesen werden. Die Stähle werden hierbei entweder einer konzentrierten Ammoniumthiocyanatlösung oder einer verdünnten Lösung, die eher die Verhältnisse in der Baupraxis wiedergibt, ausgesetzt. In den vergangenen Jahren gab es an Spannstäben der Festigkeitsklasse St 950/1050 immer wieder Probleme mit dem Erreichen der erforderlichen Standzeiten in der konzentrierten Lösung. Der Ringversuch sollte nun klären, inwieweit Unsicherheiten hinsichtlich der Zuverlässigkeit und Aussagekraft der Ergebnisse von Spannungsrisskorrosionsprüfungen bestehen. Außerdem sollten die Prüfanweisungen, die Prüfeinrichtungen sowie die Vor-Ort-Inspektion der Prüfstände kritisch beurteilt werden, um eventuell vorhandene versuchstechnische Probleme zu identifizieren und ggf. zu beheben.
Basics of statistic
(2015)