Syntheses and characterization of 2-4nm AgInS2/ZnS quantum dots
- Ternary semiconductors Quantum Dots (t-QDs) like AgInS (AIS) QDs are interesting alternatives to Cd-based QDs for applications as optical active materials in light-emitting diodes (LEDs), solar concentrators and solar cells as well as as biodiagnostic tools, respectively. AIS QDs exhibit broad photoluminescence (PL) spectra in the visible and near infrared, which are tunable by size and chemical composition (ratio of components or doping). In order to enhance the PL quantum yield (PL QY or Fpl) and prevent material deterioration and oxidation, these QDs are covered by ZnS shell. Here we show a spectroscopic study of differently colored AIS QDs synthesized in water, evaluating their PL properties, their PL QY and their PL decay. The simple aqueous synthesis that avoids further ligand exchange steps for bioanalytical applications, the tunable emission color, the high PL QY, the high absorption coefficients and the long lifetime make these t-QDs promising Cd-free materials asTernary semiconductors Quantum Dots (t-QDs) like AgInS (AIS) QDs are interesting alternatives to Cd-based QDs for applications as optical active materials in light-emitting diodes (LEDs), solar concentrators and solar cells as well as as biodiagnostic tools, respectively. AIS QDs exhibit broad photoluminescence (PL) spectra in the visible and near infrared, which are tunable by size and chemical composition (ratio of components or doping). In order to enhance the PL quantum yield (PL QY or Fpl) and prevent material deterioration and oxidation, these QDs are covered by ZnS shell. Here we show a spectroscopic study of differently colored AIS QDs synthesized in water, evaluating their PL properties, their PL QY and their PL decay. The simple aqueous synthesis that avoids further ligand exchange steps for bioanalytical applications, the tunable emission color, the high PL QY, the high absorption coefficients and the long lifetime make these t-QDs promising Cd-free materials as biodiagnostic tools or optical active materials.…
Autor*innen: | Lorena Dhamo |
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Koautor*innen: | Christian WürthORCiD, A. E. Raevskaya, O. L. Stroyuk, N. Gaponik, A. Eychmüller, Ute Resch-GengerORCiD |
Dokumenttyp: | Posterpräsentation |
Veröffentlichungsform: | Präsentation |
Sprache: | Englisch |
Jahr der Erstveröffentlichung: | 2017 |
DDC-Klassifikation: | Naturwissenschaften und Mathematik / Chemie / Analytische Chemie |
Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Ingenieurwissenschaften und zugeordnete Tätigkeiten | |
Freie Schlagwörter: | Flourescence; Nanoparticle; Quantum dot; Semiconductor; Spectral multiplexing; Synthesis; Ternary quantum dot |
Veranstaltung: | Summer School "EXCITING NANOSTRUCTURES" |
Veranstaltungsort: | Bad Honnef, Germany |
Beginndatum der Veranstaltung: | 17.07.2017 |
Enddatum der Veranstaltung: | 21.07.2017 |
Verfügbarkeit des Dokuments: | Datei im Netzwerk der BAM verfügbar ("Closed Access") |
Datum der Freischaltung: | 31.07.2017 |
Referierte Publikation: | Nein |