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Combining diffusive gradients in thin-films (DGT) and 31P NMR spectroscopy to determine phosphorus species in soil
- The diffusive gradients in thin-films (DGT) technique shows in many publications a superior correlation to the amount of plant-available phosphorus (P) in soil. However, this technique cannot give information on the plant-available P species in soil. Therefore, we combined DGT with solution 31P nuclear magnetic resonance (NMR) spectroscopy. This was achieved by using a modified DGT device in which the diffusive layer had a larger pore size, the binding layer incorporated an adsorption material with a higher capacity, and the device had a larger exposure area. The spectroscopic investigation was undertaken after elution of the deployed DGT binding layer in a NaOH solution. Adsorption tests using solutions of known organic P compounds showed that a sufficient amount of these compounds could be adsorbed on the binding layer in order for them to be analyzed by solution 31P NMR spectroscopy. Furthermore, various intermediates of the hydrolysis of trimetaphosphate in soil could be alsoThe diffusive gradients in thin-films (DGT) technique shows in many publications a superior correlation to the amount of plant-available phosphorus (P) in soil. However, this technique cannot give information on the plant-available P species in soil. Therefore, we combined DGT with solution 31P nuclear magnetic resonance (NMR) spectroscopy. This was achieved by using a modified DGT device in which the diffusive layer had a larger pore size, the binding layer incorporated an adsorption material with a higher capacity, and the device had a larger exposure area. The spectroscopic investigation was undertaken after elution of the deployed DGT binding layer in a NaOH solution. Adsorption tests using solutions of known organic P compounds showed that a sufficient amount of these compounds could be adsorbed on the binding layer in order for them to be analyzed by solution 31P NMR spectroscopy. Furthermore, various intermediates of the hydrolysis of trimetaphosphate in soil could be also analyzed over time.…
Autor*innen: | Christian VogelORCiD, A. Doolette, J. Huang |
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Dokumenttyp: | Zeitschriftenartikel |
Veröffentlichungsform: | Verlagsliteratur |
Sprache: | Englisch |
Titel des übergeordneten Werkes (Englisch): | Agricultural & Environmental Letters |
Jahr der Erstveröffentlichung: | 2022 |
Organisationseinheit der BAM: | 4 Material und Umwelt |
4 Material und Umwelt / 4.3 Schadstofftransfer und Umwelttechnologien | |
4 Material und Umwelt / 4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung | |
Veröffentlichende Institution: | Bundesanstalt für Materialforschung und -prüfung (BAM) |
Verlag: | Wiley online library |
Jahrgang/Band: | 7 |
Ausgabe/Heft: | 1 |
Erste Seite: | e20068 |
DDC-Klassifikation: | Naturwissenschaften und Mathematik / Chemie / Analytische Chemie |
Technik, Medizin, angewandte Wissenschaften / Ingenieurwissenschaften / Sanitär- und Kommunaltechnik; Umwelttechnik | |
Freie Schlagwörter: | Diffusive gradients in thin-films (DGT); Passive sampling; Phosphorus; fertilizer |
Themenfelder/Aktivitätsfelder der BAM: | Chemie und Prozesstechnik |
Umwelt | |
Umwelt / Circular Economy | |
DOI: | 10.1002/ael2.20068 |
URN: | urn:nbn:de:kobv:b43-545759 |
Verfügbarkeit des Dokuments: | Datei für die Öffentlichkeit verfügbar ("Open Access") |
Lizenz (Deutsch): | Creative Commons - CC BY - Namensnennung 4.0 International |
Datum der Freischaltung: | 04.04.2022 |
Referierte Publikation: | Ja |
Datum der Eintragung als referierte Publikation: | 20.04.2022 |
Schriftenreihen ohne Nummerierung: | Wissenschaftliche Artikel der BAM |