Refine
Year of publication
Document Type
- Article (peer reviewed) (19)
- Conference Proceeding (15)
- Other (9)
- Report (4)
- Contribution to a Periodical (2)
- Book (1)
- Part of a Book (1)
- Doctoral Thesis (1)
Language
- English (52) (remove)
Has Fulltext
- no (52)
Is part of the Bibliography
- no (52) (remove)
Keywords
- Case Study (7)
- Thin Film Transistors (7)
- Timber engineering (7)
- Cement (6)
- Construction Chemistry (6)
- Laminated veneer (5)
- Temporary soil nailing (5)
- Latex-Particles (4)
- Bioeconomy (2)
- Semiconductor Industry (2)
Institute
- Fakultät für Holztechnik und Bau (52) (remove)
Teachers should be able to balance content knowledge, pedagogical knowledge and technological knowledge (TPACK) in their various activities on curriculum, instruction, and assessment. Our Germany-wide study focused on measuring intrapreneurship competence. To ensure a valid and reliable assessment, we followed the three-step assessment triangle: cognition, observation and interpretation. We modeled the intended IP competence as an interdisciplinary and interprofessional team, designed a technology-based performance assessment tool that uses authentic work tasks, and analyzed apprentices’ behavior via a model-based IRT (Rasch model) approach. Our results identify the distribution of the IP competence of apprentices on four proficiency levels. Since these results are generalizable, single IP tasks can be used by teachers to support and guide apprentices individually with regard to these proficiency levels. Our approach is a blueprint for evidence-based teaching that tackles all areas of TPACK.
Driving forest machines on wet soils causes irreversible soil compaction, often associated with intensive rut formation and inaccessibility of wheeled forest machines for future forest operations. The German forestry equipment manufacturer FHS, Forsttechnik Handel & Service GmbH, engineered a forwarder, the Trac 81/11, equipped with conventional, well-proved bogie-axles embraced by a closed rubber track. At the center of the bogie-axle, four additional supportive rollers are placed to increase the load-carrying section between the tires of the bogie-axle. The study aimed to characterize the principle concept and the trafficability of the forwarder by analyzing the footprint area, the contact pressure, the rut formation on forest sites and the slippage during driving. Therefore, the effective contact area was measured on steel plates and rut formation was analyzed on a case study basis. Results showed that the supportive rollers increase the contact surface area by about 1/3. By this, a decrease of peak loads below the wheels and a more homogenous load distribution were observed. However, the contact surface area is still clearly divided into three parts; the area between the supportive rollers and the wheels does not take any load. Results of the rut formation were diverse: After 20 passes with 26,700 kg total mass, rut depth varied between 12.6 and 212.5 mm. Overall, the new undercarriage concept of FHS demonstrated a generally positive performance. The engineered forwarder contributes to reduce the environmental impact associated with log extraction.
This paper presents a method which allows to assess the wettability of thermomechanical pulp (TMP) with thermoplastic. The method is based on the usage of laboratory sheets made of TMP and plastic granules which form drops under heat. The contact angle of the drops after re-solidification on the surface of the laboratory sheets serves as the wetting characteristic. This method enables a direct and evaluable testing of wood fiber thermoplastic combinations. The exemplary results indicate that wood species, pulping temperature and mercerization influence the wettability of TMP with thermoplastic.
Environmental scanning electron microscopy (ESEM) and complementary methods were employed to study the time dependent film formation of a latex dispersion in water and cement pore solution. First, a model carboxylated styrene/n-butyl acrylate latex dispersion possessing a minimum film forming temperature (MFFT) of 18 °C was synthesized in aqueous media via emulsion polymerization. Its film forming property was at a temperature of 40 °C, studied under an ESEM. The analysis revealed that upon removal of water, film formation occurs as a result of particle packing, particle deformation and finally particle coalescence. Film formation is significantly retarded when the latex dispersion is present in cement pore solution. This effect can be ascribed to adsorption of Ca2+ ions onto the surface of the anionic latex particles and to interfacial secondary phases. This layer of adsorbed Ca2+ ions hinders interdiffusion of the macromolecules and subsequent film formation of the latex polymer.
Novel hybrid admixtures for construction applications were prepared by layer-by-layer deposition technique. Colloidal core templates consisting of styrene/n-butylacrylate latex particles were coated with multilayers of superplasticizers commonly used in concrete. This way, core-shell particles possessing both dispersing and film-forming properties were achieved. Incorporation of the latex@dispersant hybrid additive into a cement paste results in a slow release of the superplasticizer as a result of gradual shell disintegration which instigates prolonged plastification (long ”slump life”) of the cement slurry. Once the shell has been dissolved, latex particles are released into the pore solution and can coalesce into a polymer film which improves the mechanical properties of the hardened cement. Characterization of the templates and novel additives was performed by means of zeta potential measurement, dynamic light scattering and electron microscopy. Our method allows to synthesize multifunctional additives with time-controlled release effect.
Novel microcapsules were prepared from colloidal core–shell particles by acid dissolution of the organic core. Weakly crosslinked, monodisperse and spherical melamine-formaldehyde polycondensate particles (diameter ∼ 1 μm) were synthesized as core template and coated with multilayers of an anionic polyelectrolyte via layer-by-layer deposition technique. As polyelectrolytes, an anionic naphthalenesulfonate formaldehyde polycondensate that is a common concrete superplasticizer and thus industrially available, and cationic poly(allylamine hydrochloride) were used. Core removal was achieved by soaking the core–shell particles in aqueous hydrochloric acid at pH 1.6, resulting in hollow microcapsules consisting of the polyelectrolytes. Characterization of the template, the core–shell particles, and the microcapsules plus tracking of the layer-by-layer polyelectrolyte deposition was performed by means of zeta potential measurement and scanning electron microscopy. The microcapsules might be useful as microcontainers for cement additives.
Novel hybrid admixtures for construction applications were prepared by layer-by-layer deposition technique. Colloidal core templates consisting of styrene/acrylate latex particles were coated with multilayers of polycondensate-based dispersants commonly used in concrete. This way, core–shell particles possessing both dispersing and film-forming properties were achieved. Incorporation of the latex@dispersant hybrid additive into a cement paste results in a slow release of the dispersant which instigates prolonged plastification of the cement slurry. Following disintegration of the shell, the latex core particles are released into the pore solution and coalesce into a polymer film which improves the mechanical properties of the hardened cement. Characterization of the templates and novel additives plus tracking of the layer-by-layer polyelectrolyte adsorption was performed by means of zeta potential measurement, dynamic light scattering and electron microscopy. Our method allows to synthesize multifunctional additives with time-controlled release effect.
Several methods were employed to study the time dependent film formation of a self synthesized anionic latex dispersion in water and cement pore solution. First, a model carboxylated styrene/n-butyl acrylate latex dispersion possessing a minimum film forming temperature (MFFT) of 18 °C and a glass transition temperature (Tg) of 30 °C was synthesized via emulsion polymerization. Next, its film forming behaviour was studied at 40 °C, using an ESEM instrument. The analysis revealed that upon removal of water, film formation occurs as a result of particle packing, particle deformation and finally particle coalescence. Film formation is significantly hindered in synthetic cement pore solution. This effect can be ascribed to adsorption of Ca2+ ions onto the surface of the anionic latex particles and to interfacial secondary phases. This layer of adsorbed Ca2+ ions hinders interdiffusion of the macromolecules and subsequent film formation of the latex polymer.