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This work aims at investigating the kinetic mechanisms of the reduction/oxidation (redox) reactions of iron oxide/iron pellets under different operating conditions. The reaction principle is the basis of a thermochemical hydrogen storage system. To simulate the charging phase, a single pellet consisting of iron oxide (90% Fe2O3, 10% stabilising cement) is reduced with different hydrogen (H2) concentrations at temperatures between 600 and 800 °C. The discharge phase is initiated by the oxidation of the previously reduced pellet by water vapour (H2O) at different concentrations in the same temperature range. In both reactions, nitrogen (N2) is used as a carrier gas. The redox reactions have been experimentally measured in a thermogravimetric analyser (TGA) at a flow rate of 250 mL/min. An extensive literature review has been conducted on the existing reactions’ kinetic mechanisms along with their applicability to describe the obtained results. It turned out that the measured kinetic results can be excellently described with the so-called shrinking core model. Using the geometrical contracting sphere reaction mechanism model, the concentration- and temperature-dependent reduction and oxidation rates can be reproduced with a maximum deviation of less than 5%. In contrast to the reduction process, the temperature has a smaller effect on the oxidation reaction kinetics, which is attributed to 71% less activation energy (Ea,Re=56.9 kJ/mol versus Ea,Ox=16.0 kJ/mol). The concentration of the reacting gas showed, however, an opposite trend: namely, to have an almost twofold impact on the oxidation reaction rate constant compared to the reduction rate constant.
With steadily rising CO2 concentrations in the ambient air and fast-changing concretecompositions with reduced clinker contents, the availability of reliable and accelerated concrete car-bonation tests is of crucial importance to design durable structures. This paper focuses on the effectsof moisture under accelerated conditions and the effects of different CO2 exposure conditions. Mor-tar prisms incorporating three different cement types were cured and stored at either 50% or 65%relative humidity (RH). Afterwards, the prisms were carbonated at different ambient humidities(50, 57 and 65%), different CO2 concentrations (0.04, 1 and 3 vol.%) and complemented by a seriesof tests at increased gas pressure (2 barg). High-resolution test methods were used to explain theunderlying carbonation mechanisms. The results show that pre-conditioning for two weeks—ascurrently suggested by the European Standard—seems to be too short because the initial inner mois-ture content severely affects the carbonation rate. Relative humidity during carbonation of 57% ledto higher carbonation rates compared to 50% and 65%. In addition, climate data needs to be period-ically (preferably permanently) recorded in research experiments and in laboratory testing to ensurefair interpretation of experimental results.
Exoskeletons were invented over 100 years ago but have only become popular in the last two decades, especially in the working industry as they can decrease work-related loads significantly. The most often used exoskeletons are for the lower back and shoulder since these are commonly affected body regions. All devices have in common that their purpose is to reduce internal loads of vulnerable body regions. Nevertheless, there is still little understanding on how biomechanical loading in the human body changes when exoskeletons are used. Therefore, further analyses are needed. A promising candidate for these are musculoskeletal models, which are based on an inverse dynamics approach and can calculate external parameters such as ground reaction forces or other interaction forces as well as internal parameters such as joint reaction forces or muscle activities. The various examples in the literature show that these models are increasingly used for assessing the biomechanical effects of exoskeletons on the human body. Furthermore, musculoskeletal models can calculate biomechanical loadings of humans with and without exoskeletons for all kinds of applications and allow an evaluation of their purpose.
Practical Relevance: This article highlights the possibilities of musculoskeletal models for assessing the design and efficiency of occupational exoskeletons. Several practical use cases are described along with distinct descriptions of common implications of musculoskeletal and exoskeleton modeling.
In der Vergangenheit wurde beklagt, dass in der empirischen Forschung zur Bildungsbeteiligung Erwachsener selten eine Integration von Theorie und Empirie erfolge und die mangelnde empirische Prüfung eine theoretische Weiterentwicklung des Forschungsfeldes erschwere. Mittels einer Qualitativen Inhaltsanalyse von Beiträgen ausgewählter Fachzeitschriften der Erwachsenen‑/Weiterbildungsforschung wurde versucht, die Aktualität dieser Feststellung empirisch zu überprüfen. Dazu wurden 38 empirische Forschungsbeiträge zur Bildungsbeteiligung der Jahrgänge 2018 bis 2020 von neun Fachzeitschriften mit Peer-Review untersucht. Die Einschätzung der Beiträge erfolgte hinsichtlich des Grades der Theorieeinbindung. Die Ergebnisse der Analyse zeigen ein gemischtes Bild: neun Beiträge (24 %) binden keine Theorie in den Forschungsprozess ein, ein Beitrag (3 %) zitiert Theorie lediglich, ohne sie weiter einzubinden. Am häufigsten ist eine Einbindung zum theoriegeleiteten Vorgehen (16 Beiträge, 42 %). Eine tiefergehende Theorieanwendung findet sich in sechs Beiträgen (16 %). Eine theorieprüfende oder -bildende Einbindung liegt mit je drei Beiträgen (je 8 %) seltener vor. Die rezipierten Theorien sind vielfältig: es werden 20 verschiedene Theorieansätze festgestellt. Den Forderungen nach einer verstärkten Einbindung von Theorie in den Forschungsprozess kann somit weiterhin Gültigkeit attestiert werden: ein substanzieller Teil der Beiträge berichtet keine Theorieeinbindung, eine empirische Prüfung oder Weiterentwicklung findet relativ selten statt.
Special issue ISARC 2021
(2022)
The research filed of construction robotics broadens increasingly in terms of complexity, approaches, technologies used, active stakeholders, and application areas. Worldwide labour and resource shortages, the need to increase circularity and resource efficiency, new materials and the increasing utilisation of digital construction tools in the planning and construction industry massively spur the uptake of robotic solutions for on-site construction.
The initial boom of construction robots happened in the 1970s, driven by the Japanese construction industry. In the 1980s, a combination with parallel developments was supposed to achieve complete, integrated robotic on-site factories. From the mid-1980s onwards, the global interest in construction robots decreased gradually. Bulky and expensive systems, complex on-site navigation and logistics approaches, a narrow scope of tasks, inflexibility, incompatibility with on-site work organisation and professional qualification, low usability and insufficient inter-robot coordination capabilities revealed the immaturity of the systems. Only a few organisations predominantly situated in Asia such as Takenaka, Obayashi, Kajima Corporation, Nihon Bisho Co., Samsung, and Hitachi maintained development activities.
However, since the mid-2010s, development activities are gaining traction again. On the application side, this is mainly driven by trends such as the need to upgrade the energy performance of buildings in Europe, a global necessity to remove asbestos from existing structures, and a demand for enormous quantities of high-rise buildings all over East Asia. On the system side, the renewed interest stems from major advances in physical–mechanical robot technology in other automation-driven industries such as the automotive industry. Robots became lighter, more flexible, their parts modular and interchangeable, more user friendly as well as significantly cheaper. On the digital side, the BIM-to-Robot pipeline was subject of intensive reserach and development. More and more methods and tools help to increase the usability of robots and facilitate the simulation and optimisation of robot-driven construction processes.
In the last 4–5 years, the worldwide growing need and interest in construction robotics became highly evident. More than 200 robot systems are pushed by start-ups and spin-offs and their investors to the market. This is backed by an enormous number of activities and projects carried out in the academic area pushing to the boundaries of what is technologically possible.
Major associations and their conferences increase significantly in popularity such as ISARC (International Association for Automation and Robotics in Construction), EC3 (European Council of Computing in Construction), and Robots in Architecture. Competency in digital construction, automation and robotics becomes a key for all stakeholders in the construction industry and many universities worldwide launch dedicated interdisciplinary programs. Powerful governments (China) and major funding programs such as Horizon Europe (Europe) massively request and fund the development of robotic solutions for construction such as drones, mobile robots, 3D-printing solutions, cable-driven robots, and exoskeletons. Regulators and standardisation organisation start to develop the first certification and standardisation schemes for construction robots and large software companies make attempts to allow to simulate and program robotic construction processes efficiently and robustly based on digital building and construction data.
To showcase the diversity of cutting-edge research in the area, this special issue invited eight extended versions of selected papers from the ISARC 2021 conference. As such, this issue covers digital approaches to embed fabrication and robot information in BIM and IFC and program robots directly from digital building models. New robot systems spur novel robotic production processes, and machine learning enable novel logistics approaches for building components that may ultimately lead to robotic cranes and other robotic on-site logistics and handling solutions (including autonomous construction machines). In parallel, systematic evaluation and robot development methods are developed that allow to shed light on their performance in the construction process.
Non-road sectors, such as agriculture and construction machinery, require high energy densities and flexibility in use, which is why diesel engines are mainly used. The use of climate-neutral fuels, produced from renewable energies, such as Oxymethylene Ether (OME) as a diesel substitute, can significantly reduce CO2 and pollutant emissions in these sectors. In addition to CO2 neutrality, OME also offers improved combustion characteristics compared to diesel fuel, eliminating the soot–NOx trade-off and thus enabling new opportunities in engine design and calibration. In this paper, the combustion of pure OME on a close-to-production, single-cylinder non-road diesel engine with a pump–line–nozzle injection system is analyzed. A variation of the center of combustion at constant power output was performed for diesel and OME at different operating points. Two injectors were investigated with OME. A study on ignition delay and a detailed thermodynamic analysis was carried out. In addition, the exhaust emissions CO, NOx, VOC, as well as particulate-matter, -number and -size distributions were measured. With OME, a significantly shorter ignition delay as well as a shortened combustion duration could be observed, despite a longer injection duration. In addition, the maximum injection pressure increases. VOC and CO emissions are reduced. Particulate matter was reduced by more than 99% and particle number (>10 nm) was reduced by multiple orders of magnitude. The median of the particle size distribution shifts from 60 to 85 nm (diesel) into a diameter range of sub 23 nm (OME). A significant reduction of NOx emissions with OME enables new degrees of freedom in engine calibration and an efficiency advantage without hardware adaption.
We demonstrate the control of wettability of non-structured and microstructured magnetoactive elastomers (MAEs) by magnetic field. The synthesized composite materials have a concentration of carbonyl iron particles of 75 wt.% (≈27 vol.%) and three different stiffnesses of the elastomer matrix. A new method of fabrication of MAE coatings on plastic substrates is presented, which allows one to enhance the response of the apparent contact angle to the magnetic field by exposing the particle-enriched side of MAEs to water. A magnetic field is not applied during crosslinking. The highest variation of the contact angle from (113 ± 1)° in zero field up to (156 ± 2)° at about 400 mT is achieved in the MAE sample with the softest matrix. Several lamellar and pillared MAE structures are fabricated by laser micromachining. The lateral dimension of surface structures is about 50 µm and the depth varies between 3 µm and 60 µm. A systematic investigation of the effects of parameters of laser processing (laser power and the number of passages of the laser beam) on the wetting behavior of these structures in the absence and presence of a magnetic field is performed. In particular, strong anisotropy of the wetting behavior of lamellar structures is observed. The results are qualitatively discussed in the framework of the Wenzel and Cassie-Baxter models. Finally, directions of further research on magnetically controlled wettability of microstructured MAE surfaces are outlined. The obtained results may be useful for the development of magnetically controlled smart surfaces for droplet-based microfluidics.
On analytic properties of the standard zeta function attached to a vector-valued modular form
(2022)
We proof a Garrett–Böcherer decomposition of a vector-valued Siegel Eisenstein series E2l,0 of genus 2 transforming with the Weil representation of Sp2(Z) on the group ring C[(L′/L)2]. We show that the standard zeta function associated to a vector-valued common eigenform f for the Weil representation can be meromorphically continued to the whole s-plane and that it satisfies a functional equation. The proof is based on an integral representation of this zeta function in terms of f and E2l,0.
Elbow stability is derived from a combination of muscular, ligamentous, and bony structures. After an elbow trauma the stability of the joint is an important decision criterion for the subsequent treatment. The decision regarding non-operative/operative care depends mostly on subjective assessments of medical experts. Therefore, the aim of this study is to use musculoskeletal simulations as an objective assessment tool to investigate the extent to which failure of different stabilizers affects the elbow stability and how these observations correspond to the assessment from clinical practice. A musculoskeletal elbow simulation model was developed for this aim. To investigate the stability of the elbow, varus/valgus moments were applied under 0°, 45°and 90° flexion while the respective cubital angle was analyzed. This was performed for nine different injury scenarios, which were also evaluated for stability by clinical experts. With the results, it can be determined by which injury pattern and under which flexion angle the elbow stability is impaired regarding varus/valgus moments. The scenario with a complete failure of the medial and lateral ligaments and a fracture of the radial head was identified as having the greatest instability. The study presented a numerical determination of elbow stability against varus/valgus moments regarding clinical injury patterns, as well as a comparison of the numerical outcome with experience gained in clinical practice. The numerical predictions agree well with the assessments of the clinical specialists. Thus, the results from musculoskeletal simulation can make an important contribution to a more objective assessment of the elbow stability.
Hot pressing of pure Ti and cast iron under vacuum formed a ~15 μm wide TiC-layer through the thermoreactive diffusion process. Nanoindentation testing of the TiC-layer revealed average hardness and elastic
modulus values of ~35 GPa and ~400 GPa, respectively. High-resolution indentation mapping indicated hardness change across the boundary with peak values observed within the TiC-layer. Solid state high temperature diffusion holds significant potential for developing uniform hard coatings on pure Ti/Ti-alloys.
Herein, the effect of an applied moderate (~240 mT) magnetic field on the work of adhesion (WoA) of mechanically soft (the shear modulus ~10 kPa) magnetoactive elastomer (MAE) samples with two different mass fractions (70 and 80 wt%) of carbonyl iron powder (CIP) is concerned. The unfilled elastomer sample is used for comparison. Due to some sedimentation of filling particles, the concentration of inclusions in thin (~10 μm) subsurface layers is different. It is shown that the WoA increases (up to 1.8-fold) on the particle-enriched side (PES) in the magnetic field and its value is higher for higher filler concentration. On the particle-depleted side (PDS), WoA does not depend on particle concentration and on the magnetic field. Adhesion and friction are coupled in MAEs. No statistically significant difference in the friction coefficient, determined from the extended Amontons´ law, depending on sample side, CIP concentration, or presence of magnetic field is found. However, the PDS in the magnetic field demonstrates significantly higher critical shear stress compared to that for the PES or PDS in the absence of magnetic field. Correlations between different surface properties are discussed. Obtained results are useful for the development of magnetically controllable soft robots.
In this work, multiferroic cantilevers comprise a layer of a magnetoactive elastomer (MAE) and a commercially available piezoelectric polymer-based vibration sensor. The structures are fixed at one end in the horizontal plane and the magnetic field is applied vertically. First, the magnetoelectric (ME) response to uniform, triangle-wave magnetic fields with five different slew rates is investigated experimentally. Time and field dependences of the generated voltage, electric charge, and observed mechanical deflection are obtained and compared for four different thicknesses of the MAE layer. The ME responses to triangular and sinusoidal wave excitations are examined in contrast. Second, the ME response at low frequencies (≤3 Hz) is studied by the standard method of harmonic magnetic field modulation. The highest ME coupling coefficient is observed in the bias magnetic field strength of ≈73 kA/m and it is estimated to be about 3.3 ns/m (ME voltage coefficient ≈ 25 V/A) at theoretically vanishing modulation frequency (f→0 Hz). Presented results demonstrate that the investigated heterostructures are promising for applications as magnetic-field sensors and energy harvesting devices.
Dieser Beitrag enthält Überlegungen zum Rechtspopulismus als (komplexe) Problemstellung der Sozialen Arbeit. Eine theoretisch-reflexive Analyse pädagogischer und didaktischer Ansätze, eine qualitative Analyse zu Herausforderungen und Bewältigungsstrategien von Fachkräften in der Kinder- und Jugendhilfe sowie eine Analyse aktueller Veröffentlichungen und Stellungnahmen im Kontext des Rechtspopulismus legen die Vermutung nahe, dass sich die Soziale Arbeit aufgrund der Komplexität dieses gesellschaftlichen und politischen Phänomens in einer Suchbewegung befindet.
Der Beitrag zeigt Ergebnisse einer Begleitstudie zur Restaurierung und energetischen Modernisierung des historischen genossenschaftlichen Wohnquartiers Margaretenau in Regensburg im Projekt MAGGIE. Bei der Gestaltung von Wohnungen und Gelegenheiten für die soziale Einbettung im Quartier wird eine altersgerechte Perspektive eingenommen. Die Darstellung der schriftlichen standardisierten Haushaltsbefragung (n = 195) nimmt die Lebenssituation älterer Menschen ab 65 Jahren in den Fokus. Dazu werden die Themenbereiche Haushaltsstruktur, altersgerechtes Wohnen und Gemeinschaftseinrichtungen präsentiert. Neben der aktuellen Wohnsituation wurden Pläne und Wünsche für das zukünftige Wohnen abgefragt. Im Alter schwindet die Bereitschaft für Veränderungen, was sich am Wunsch zum Altern in der bisherigen Wohnung und Verbleib im Wohnquartier zeigt. Das Interesse am barrierereduzierten Wohnen ist bei älteren Haushalten geringer als bei jüngeren. Es zeigt sich ein überdurchschnittlich hohes Maß an lokalem Sozialkapital, wobei kein signifikanter Unterschied zwischen jüngeren und älteren Haushalten besteht.
Successful transfer of photoacoustic gas sensors from laboratory to real-life applications requires knowledge about potential cross-sensitivities towards environmental and gas matrix changes. Multi-dimensional calibration in case of cross-sensitivities can become very complex or even unfeasible. To address this challenge, we present a novel algorithm to compute the collision based non-radiative efficiency and phase lag of energy relaxation on a molecular level (CoNRad) for photoacoustic signal calculation. This algorithmic approach allows to calculate the entire elaxation cascade of arbitrarily complex systems, yielding a theoretical photoacoustic signal. In this work the influence of varying bulk compositions, i.e. nitrogen (N2), oxygen (O2) and water (H2O) on the photoacoustic signal during methane (CH4) detection is demonstrated. The applicability of the algorithm to other photoacoustic setups is shown exemplary by applying it to the relaxational system investigated in [1]. Hayden et al. examined the effect of water on photoacoustic carbon monoxide (CO) detection.
Die vorliegende Studie untersucht Schlüsselfaktoren erfolgrei-
cher CIOs in deutschen Großunternehmen. Mit einer mittleren Verweildauer (Median) von 4,0 Jahren weisen deutsche CIOs, die mit 43 % noch überwiegend an den CFO berichten, im Vergleich zu anderen C-Level-Positionen eine deutlich kürzere Verweildauer im Amt auf. Die Ergebnisse aus 60 Interviews mit erfolgreichen deutschsprachigen CIOs, die primär über eine überdurchschnittlich lange Verweildauer verfügen, lassen verschiedene Schlüsselfaktoren für den Erfolg erkennen: Grundvoraussetzung ist stets die Gewährleistung eines sicheren und effizienten IT-Betriebs. Über effektive und innovative Change-Projekte machen die interviewten CIOs den IT-Mehrwert transparent und agieren als Brückenbauer zwischen IT und Fachbereichen. Dadurch wirken sie positiv auf die Firmenkultur ein und etablieren die IT nachhaltig in den Fachbereichen als Erfolgsfaktor. Erfolgreiche CIOs selbst sind keine „Techies“, sondern zeichnen sich durch hohe Führungskompetenz und ein hohes Geschäftsverständnis, gepaart mit visionärem Denken aus. Dadurch gelingt es ihnen, die IT zukunftsorientiert auszurichten und Anforderungen und Potenziale für und aus den Fachbereichen frühzeitig zu antizipieren. Die zukünftige Entwicklung der CIO-Organisation und der Paradigmen in der IT wird durch die Studienteilnehmer hingegen teilweise kontrovers diskutiert – so gibt es beispielsweise bei der Beurteilung der Sinnhaftigkeit und Relevanz der CDO-Position noch kein einheitliches Meinungsbild.
Final assembly at Krones AG must make the best possible use of its production space and meeting the specified customer due dates is critical. Via a self developed simulation tool, the present scheduling procedure is compared with the one by priority rule shortest slack. As a consequence slack should have a higher importance in the planning
Deep Reinforcement Learning (RL) has considerably advanced over the past decade. At the same time, state-of-the-art RL algorithms require a large computational budget in terms of training time to converge. Recent work has started to approach this problem through the lens of quantum computing, which promises theoretical speed-ups for several traditionally hard tasks. In this work, we examine a class of hybrid quantumclassical RL algorithms that we collectively refer to as variational quantum deep Q-networks (VQ-DQN). We show that VQ-DQN approaches are subject to instabilities that cause the learned policy to diverge, study the extent to which this afflicts reproduciblity of established results based on classical simulation, and perform systematic experiments to identify potential explanations for the observed instabilities. Additionally, and in contrast to most existing work on quantum reinforcement learning, we execute RL algorithms on an actual quantum processing unit (an IBM Quantum Device) and investigate differences in behaviour between simulated and physical quantum systems that suffer from implementation deficiencies. Our experiments show that, contrary to opposite claims in the literature, it cannot be conclusively decided if known quantum approaches, even if simulated without physical imperfections, can provide an advantage as compared to classical approaches. Finally, we provide a robust, universal and well-tested implementation of VQ-DQN as a reproducible testbed for future experiments.
This paper introduces the results of an experimental study on the adsorption and desorption kinetics of a commercially available, open-structured asymmetric plate heat exchanger adapted to act as an adsorber/desorber for the application in adsorption heat transformation processes. In addition, a volumetric large temperature jump (V-LTJ) kinetic setup was applied to measure the adsorption and desorption kinetics of a small-scale adsorbent sample prepared dedicatedly to be representative for the adsorbent domain inside the investigated adsorber plate heat exchanger (APHE). All kinetic results of the small-scale adsorbent sample and the APHE were fitted into exponential forms with a single characteristic time constant (τ) with a coefficient of determination (R2) better than 0.9531. A very good matching between the small-scale and full-scale adsorption kinetic measurements was obtained, with an average relative deviation of 12.3% in the obtained τ-values. In addition, the kinetic data of the small-scale adsorbent sample were utilized for estimating the expected specific instantaneous and moving average powers of the evaporator/condenser heat exchanger. The average relative deviation (ARD) between the moving average specific evaporator powers obtained from the small-scale and the full-scale measurements amounts between 5.4 and 15.1%.