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The development of new technologies like advanced driver assistance systems or automated driving requires a flexible simulation environment of sufficient complexity. In general this flexibility is not provided by commercial software packages. This paper presents a three-dimensional and nonlinear hand-made model for heavy commercial vehicles including tractor and trailer as well as tractor and semitrailer combinations that can be used in different simulation environments, as well as in real-time applications. As typical for trucks, the torsional flexibility of the frame and a suspended driver's cabin are taken into account. The design kinematics makes it possible to handle different and quite complex axle suspensions very efficiently. Appropriate force elements are used to model various couplings between tractor and trailer or tractor and semitrailer, respectively. The virtual test truck environment (VTT) coded in ANSI C is extremely portable and can easily be embedded in commercial simulation packages like MATLAB/Simulink. It includes the TMeasy tyre model and offers flexible interfaces to third-party software tools.
All known locomotion principles are limited respective to environmental conditions. Often, the occurrence of obstacles or gaps means the break-off for the operating motion systems. For such circumstances, a controllable jumping locomotion is required to cross these barriers. However, this locomotion demands sophisticated requirements to the actuation. The abrupt actuation is commonly realized by high dynamic actuators or complex mechanisms. In this work, a simple solution utilizing the multistability of a compliant tensegrity structure is described. Therefore, a two-dimensional tensegrity structure featuring four stable equilibria is considered. Based on bifurcation analyses a feasible actuation to control the current equilibrium configuration is derived. Changing between selected equilibrium states enables a great difference in potential energy, which yields a jumping motion of the structure. Based on numerical simulations a suitable actuation strategy is chosen to overcome obstacle and steps by jumping forward or backward, respectively. The theoretical approach is examined experimentally with a prototype of the multistable tensegrity structure.
(c) 2020 Elsevier Ltd. All rights reserved.
All known locomotion principles are limited respective to environmental conditions. Often, the occurrence of obstacles or gaps means the break-off for the operating motion systems. For such circumstances, a controllable jumping locomotion is required to cross these barriers. However, this locomotion demands sophisticated requirements to the actuation. The abrupt actuation is commonly realized by high dynamic actuators or complex mechanisms. In this work, a simple solution utilizing the multistability of a compliant tensegrity structure is described. Therefore, a two-dimensional tensegrity structure featuring four stable equilibria is considered. Based on bifurcation analyses a feasible actuation to control the current equilibrium configuration is derived. Changing between selected equilibrium states enables a great difference in potential energy, which yields a jumping motion of the structure. Based on numerical simulations a suitable actuation strategy is chosen to overcome obstacle and steps by jumping forward or backward, respectively. The theoretical approach is examined experimentally with a prototype of the multistable tensegrity structure.
Handling tire models like Pacejka (Tire and Vehicle Dynamics, 3rd edn., Elsevier, Amsterdam, 2012) or TMeasy (Rill in Proc. of the XV Int. Symp. on Dynamic Problems of Mechanics, Buzios, RJ, Brazil, 2013) consider the contact patch as one coherent plane. As a consequence, the irregularities of a rough road profile must be approximated by an appropriate local road plane that serves as an effective road plane in order to calculate the geometric contact point and the corresponding contact velocities. The Pacejka/SWIFT tire model employs a road enveloping model that generates the effective height and slope by elliptical cams. TMeasy just uses four representative road points for that purpose. In addition, TMeasy replaces the geometric contact point by the static contact point and shifts it finally to the dynamic contact point that represents the point where the contact forces are applied. In doing so, a rather sophisticated but still simple contact calculation is possible. Simulations obtained with a virtual tire test rig and fully nonlinear three-dimensional multibody system models of a motor-scooter and a passenger car demonstrate the potential of this contact approach.
The growing efforts for the development of clean and efficient energy systems require the use of a multi-disciplinary approach and the integration of multiple generation appliances. Among the fields that can be considered enabling technologies, adsorption systems for air conditioning and thermal energy storages, are constantly increasing their maturity. However, for a proper design and integration of such systems, there is the need for a simulation framework that is reliable and computationally convenient. In the present paper, the implementation of a dynamic model for adsorption systems is presented, which includes different components (adsorber, phase changer, sorption materials) and is structured as a library. Modelica language and the commercial software Dymola (R) are used for the analysis. Data for different heat exchangers and working pairs are calibrated using experimental results and the calibrated model is subsequently used for the design of an adsorber based on a plate heat exchanger for thermal energy storage applications. The results proved that the model is fast and can reproduce experimental results with good accuracy, thus being a useful tool for the design and optimization of the different components of sorption systems.
Basics for inline measurement of tribological conditions in series production of car body parts
(2019)
The quality of car body parts in series production is strongly dependent on the tribological behavior. Fluctuating material properties such as the sheet roughness and the amount of lubricant have an influence on the forming process. On the basis of large amounts of data it is possible to investigate the friction behavior in series production and to make process adjustments if required. Therefore, inline measurement systems have a great potential to detect the sheet roughness during the cutting process of blanks in the coil line. Furthermore, contactless systems are advantageous as they do not damage the surface. Nevertheless, the optical measuring is influenced by the lubricant layer on top of the surface. Therefore, the previously unknown impact of the lubricant on the measuring result is investigated.
Within this study, stationary optical roughness measurements have been conducted using different amounts of lubricant on hot-dip galvanized EDT steel. The results demonstrate the influence of different amounts of lubricant on the sheet roughness measurement. Hence, it is possible to correct the inline measuring results and gain knowledge of fluctuating surface roughness. In addition, strip drawing test has been carried out to investigate the effect of fluctuating tribological conditions.
To reduce particulate emissions, the use of particulate filters in diesel engines is meanwhile state of the art, while the integration of such systems in gasoline engines is now also necessary in order to comply with today's regulations. Over its lifetime, a gasoline particulate filter (GPF) collects ash components of fuel, lubrication oil, and materials originating from the catalytic coating and from engine abrasion. In the development and application process, synthetic ashing from GPFs is challenging. The ash of the lubrication oil can be increased in various ways, like oil-doped fuel, a separate oil burner, or changes in the piston-cylinder system of the engine. However, these methods show major disadvantages. For this reason, an improved approach is presented in this study, which allows a quick response to changes in combustion (e.g., engine knocking) and producing ash, which is more realistic due to its primary particle size and the density of ash plugs, in a shorter time. Therefore, an approach to accelerate ash loading by active oil injection using a multi-point injection (MPI) system is introduced. With the help of this methodology, an ashing capacity of 1.21 g/h is implemented, which is a high rate compared to other investigations. The primary particle size (evaluated by means of a transmission electron microscope), is in the same size range as those detected at the full-load curve during regular operation. A computer tomographic (CT) analysis of the incinerated particulate filter also shows that a very high density of ash plugs can be realized, which has also been found in the literature for real applications. In addition, with the help of a mass spectrometer (MS) and an intermediate weighing of the particulate filter, the current ash loading of the GPF could be determined with an accuracy of 1%.
This review gives a worldwide overview on Power-to-Gas projects producing hydrogen or renewable substitute natural gas focusing projects in central Europe. It deepens and completes the content of previous reviews by including hitherto unreviewed projects and by combining project names with details such as plant location. It is based on data from 153 completed, recent and planned projects since 1988 which were evaluated with regards to plant allocation, installed power development, plant size, shares and amounts of hydrogen or substitute natural gas producing examinations and product utilization phases. Cost development for electrolysis and carbon dioxide methanation was analyzed and a projection until 2030 is given with an outlook to 2050. The results show substantial cost reductions for electrolysis as well as for methanation during the recent years and a further price decline to less than 500 euro per kilowatt electric power input for both technologies until 2050 is estimated if cost projection follows the current trend. Most of the projects examined are located in Germany, Denmark, the United States of America and Canada. Following an exponential global trend to increase installed power, today's Power-to-Gas applications are operated at about 39 megawatt. Hydrogen and substitute natural gas were investigated on equal terms concerning the number of projects.
Avoiding ice accumulation on aerodynamic components is of enormous importance to flight safety. Novel approaches utilizing surface dielectric barrier discharges (SDBDs) are expected to be more efficient and effective than conventional solutions for preventing ice accretion on aerodynamic components. In this work, the realization of SDBDs based on thin-film substrates by means of micro-electro-mechanical-systems (MEMS) technology is presented. The anti-icing performance of the MEMS SDBDs is presented and compared to SDBDs manufactured by printed circuit board (PCB) technology. It was observed that the 35 mu m thick electrodes of the PCB SDBDs favor surface icing with an initial accumulation of supercooled water droplets at the electrode impact edges. This effect was not observed for 0.3 mu m thick MEMS-fabricated electrodes indicating a clear advantage for MEMS-technology SDBDs for anti-icing applications. Titanium was identified as the most suitable material for MEMS electrodes. In addition, an optimization of the MEMS-SDBDs with respect to the dielectric materials as well as SDBD design is discussed.
Germany's energy transition, known as 'Energiewende', was always very progressive. However, it came technically to a halt at the question of large-scale, seasonal energy storage for wind and solar, which was not available. At the end of the 2000s, we combined our knowledge of both electrical and process engineering, imitated nature by copying photosynthesis and developed Power-to-Gas by combining water electrolysis with CO2-methanation to convert water and CO2 together with wind and solar power to synthetic natural gas. Storing green energy by coupling the electricity with the gas sector using its vast TWh-scale storage facility was the solution for the biggest energy problem of our time. This was the first concept that created the term 'sector coupling' or 'sectoral integration'. We first implemented demo sites, presented our work in research, industry and ministries, and applied it in many macroeconomic studies. It was an initial idea that inspired others to rethink electricity as well as eFuels as an energy source and energy carrier. We developed the concept further to include Power-to-Liquid, Power-to-Chemicals and other ways to 'convert' electricity into molecules and climate-neutral feedstocks, and named it 'Power-to-X'at the beginning of the 2010s.
To support a rational and efficient use of electrical energy in residential and industrial environments, Non-Intrusive Load Monitoring (NILM) provides several techniques to identify state and power consumption profiles of connected appliances. Design requirements for such systems include a low hardware and installations costs for residential, reliability and high-availability for industrial purposes, while keeping invasive interventions into the electrical infrastructure to a minimum. This work introduces a reference hardware setup that allows an in depth analysis of electrical energy consumption in industrial environments. To identify appliances and their consumption profile, appropriate identification algorithms are developed by the NILM community. To enable an evaluation of these algorithms on industrial appliances, we introduce the Laboratory-measured IndustriaL Appliance Characteristics (LILAC) dataset: 1302 measurements from one, two, and three concurrently running appliances of 15 appliance types, measured with the introduced testbed. To allow in-depth appliance consumption analysis, measurements were carried out with a sampling rate of 50 kHz and 16-bit amplitude resolution for voltage and current signals. We show in experiments that signal signatures, contained in the measurement data, allows one to distinguish the single measured electrical appliances with a baseline machine learning approach of nearly 100% accuracy.
The purpose of this study was to investigate the characteristic of nanoparticles under consideration of sub-23-nm particles from a 1.8-l direct injection (DI) gasoline engine under stoichiometric air/fuel conditions in the exhaust gas system. For future CO2 challenges, the usage of DI-instead of port fuel injection (PFI)-gasoline engines is unavoidable. Therefore, a state of the art particle management program-particle number (PN) system, the Horiba SPCS (2100) with an integrated CPC (condensation particle counter), was recalibrated from a 50% cutoff (D-50%) at 23 nm down to a cutoff at 10 nm and the PCRF (particle concentration reduction factor) for sizes smaller than 23 nm was checked. Two different modal points, out of a representative Real Driving Emission (RDE) cycle, were investigated with both calibrations, D-50%=10 nm and D-50%=23 nm. For these different load points, the fuel pressure (FUP) and the start of injection (SOI) were varied, to represent the difference in the structure and the ratio conc((10 nm))/conc((23 nm)) of the nanoparticle emissions. The particle characterization includes the particle number (PN), the particle size distribution (PSD), and the particle mass (PM). The particle number was measured with Horiba SPCS (2100). The particle size distribution was analyzed with a Grimm differential mobility analyzer (DMA) in combination with a Faraday cup electrometer (FCE). Micro Soot and Pegasor were used to determine the PM, and an optical characterization was done with a 120-kV Phillips CM12 transmission electron microscope (TEM). The position of all particle measurement systems was downstream the three-way catalyst (TWC). The results of this investigation showed that a higher injection pressure decreases the PN (without consideration of sub-23-nm particles) in general. The ratio conc((10 nm))/conc((23 nm)) was therefore higher, because smaller particles, especially ash particles, were less reduced from the FUP. This means higher FUP tends to a higher ratio. For the SOI, the main reasons of the ratio differences were explained by an encroachment between the injection jet and the piston, the valve and the wall.
Insulation of thermal energy storage tanks is fundamental to reduce heat losses and to achieve high energy storage efficiency. Although water tanks were extensively studied in the literature, the enhancement of the insulation quality is often overlooked. The use of vacuum insulation has the potential to significantly reduce heat losses without affecting the dimension of the storage system. This paper shows for the first time the results of the heat losses tests done for a 0.535 m3 water tank for residential building applications built with a double wall vacuum insulation. The different tests show that the rate of heat losses strictly depends on the temperature distribution inside the tank at the beginning of the experiment. Compared to a conventional water tank insulated with conventional materials, the U-value of the lateral surface was reduced by almost three times (from 1.05 W/K·m2 to 0.38 W/K·m2) using vacuum insulation. However, the bottom part, which is usually used to place the support parts and the piping, is the critical design part of those tanks acting as a thermal bridge with the ambient and enhancing heat losses.
A numerical parameter sensitivity analysis of the design parameters of the recently published solar selective thermal insulation system (SATIS) has been carried out to enhance its thermal and optical properties. It turned out that the insulation properties of SATIS can be effectively improved by reducing the length of the glass closure element. Increasing the area share of the light conducting elements (LCEs) and decreasing their length-to-diameter (L/D) ratio were identified as key parameters in order to increase the solar gain. Two SATIS variants were compared with the same wall insulation without SATIS in a yearly energetic performance assessment. The SATIS variant with 10 mm length of the closure element, 44.2% area share of LCE, as well as front and rear diameters of 12 mm/9 mm shows an 11.8% lower transmission heat loss over the heating period than the wall insulation without SATIS. A new methodology was developed to enable the implementation of the computed solar gains of SATIS in 1D simulation tools. The result is a radiant heat flow map for integration as a heat source in 1D simulation models. A comparison between the 1D and 3D models of the inside wall heat fluxes showed an integral yearly agreement of 98%.
Method of Measuring Deformations of Magnetoactive Elastomers under the Action of Magnetic Fields
(2019)
The hydrogen gas-to-liquid mass transfer is the limiting factor in biological methanation. In trickle-bed reactors, mass transfer can be increased by high flow velocities in the liquid phase, by adding a packing material with high liquid hold-up or by using methanogenic archaea with a high methane productivity. This study developed a polyphasic approach to address all methods at once. Various methanogenic strains and packings were investigated from a microbial and hydrodynamic perspective. Analyzing the ability to produce high-quality methane and to form biofilms, pure cultures of Methanothermobacter performed better than those of the genus Methanothermococcus. Liquid and static hold-up of a packing material and its capability to facilitate attachment was not attributable to a single property. Consequently, it is recommended to carefully match organism and packing for optimized performance of trickle-bed reactors. The ideal combination for the ORBIT system was identified as Methanothermobacter thermoautotrophicus IM5 and DuraTop (R).
he hydrogen gas-to-liquid mass transfer is the limiting factor in biological methanation. In a trickle-bed reactor, mass transfer can be increased by high flow velocities in the liquid phase, by adding a packing material with high liquid hold-up, or by choosing methanogenic archaea with a high methane productivity. This study analyzed various packings and methanogenic strains from a hydrodynamic and microbial perspective. By analyzing twelve pure cultures of thermophilic methanogens for their ability to produce high quality methane and to form biofilms on different packings, strains of Methanothermobacter were found to perform better than thus of the genus Methanothermococcus. Best methane production and adherence was observed on DuraTop®, Bioflow 9, and filter foam. DuraTop® and Bioflow 9 had also a high dynamic liquid hold-up, but the maximum hold-up was determined for expanded clay. The ideal combination for use in the ORBIT-trickle-bed reactor was identified as Methanothermobacter thermoautotrophicus IM5 and DuraTop®.
Globally, PV prosumers account for a significant share of the total installed solar PV capacity, which is a growing trend with ever-increasing retail electricity prices. Further propelled by performance improvements of solar PV and innovations that allow for greater consumer choice, with additional benefits such as cost reductions and availability of incentives. PV prosumers may be one of the most important enablers of the energy transition. PV prosumers are set to gain the most by maximising self-consumption, while avoiding large amounts of excess electricity being fed into the grid. Additionally, electricity and heat storage technologies, heat pumps and battery electric vehicles are complementary to achieve the highest possible self-consumption shares for residential PV prosumer systems, which can reach grid-parity within this decade in most regions of the world. This research finds the cost optimal mix of the various complementary technologies such as batteries, electric vehicles, heat pumps and thermal heat storage for PV prosumers across the world by exploring 4 different scenarios. Furthermore, the research presents the threshold for economical maximum battery capacity per installed PV capacity, along with self-consumption ratios, demand cover ratios and heat cover ratios for 145 different regions across the world. This is a first of its kind study to conduct a global analysis of PV prosumers with a range of options to meet their complete energy demand from a future perspective, up to 2050. Maximising self-consumption from solar PV generation to meet all energy needs will be the most economical option in the future, for households across most regions of the world.
In modern manufacturing systems, milk run (MR) systems represent route-based, cyclic material-handling systems that are used widely and enable frequent deliveries of containerized parts in small lot sizes from a central storage area to multiple points of use on the factory floor. Usually, deliveries take place at predetermined, constant time intervals. As in real-world MR systems, the number of containers to deliver in each interval varies in the short term, peaks in the number of deliveries may lead to capacity bottlenecks and late deliveries. In this paper, we develop three alternative strategies to determine starting times of MR cycles in real-time based on the current number of delivery orders in the system aiming to better handle variations in the number of orders. We evaluate the three strategies for different system load scenarios with respect to delivery service levels, order lead times, systems utilization and necessary number of MR trains using a discrete-event simulation model.
The formation of microstructures in magnetoactive polymers (MAPs) is a recently discovered phenomenon found only with very low filler particle concentrations (less than 3 wt %). Due to the degassing process, filler particles collect around an ascending bubble, which dissolves at a certain point leaving particulate rings within the matrix. The formation of toroidal microstructures commences as filler concentration approaches 1 wt %. The development of coherent parallel aligned rings with a compact order continues as particle concentrations increase toward 2 wt %. Between 2 and 3 wt % capillary doublets develop, while mass percentages higher than 3% result in increasing entropy as the random order of particle agglomeration found in higher concentration MAP dominates. Self-structured samples of different filler material and concentrations between 1 and 3 wt % have been investigated using X-ray tomography, where the emerging structures can be observed and visualized. The ring structures resulting from this research represent microinductivities which can be fabricated in a targeted manner, thus enabling new applications in the high-frequency radio field. Furthermore, these anisotropic, but well-organized, structures have magnetic field-dependent implications for optical, thermal, acoustic, and medical applications.
What commonalities are there in sustainable or unsustainable heating practices in five high-income, high-emitting western European countries? What preferences do a nationally representative sample of the public in these countries hold towards low-carbon options? It is imperative that climate policy researchers and practitioners grapple with the difficulty of decarbonizing heat, which remains the largest single end-use service worldwide and which accounts about half of total final energy consumption. Based on a comparative assessment of five representative national surveys in Germany (N = 2009), Italy (N = 2039), Spain (N = 2038), Sweden (N = 2023), and the United Kingdom (N = 2000), this study explores the demographics and geography of household heat decarbonisation in Europe. By analyzing our country level data as well as our combined sample of 10,109 respondents, it investigates how people conceive of the purposes of low-carbon heat, their preferences for particular forms of heat supply, and their (at times odd) practices of heat consumption and temperature settings. Grounded in its original data, the study organizes its findings inductively across the five themes of literacy (heating knowledge, awareness and control), sustainability (heating practices, dynamics and conflicts), temperature (heating satisfaction and preferences), desirability of change (low-carbon heating priorities, business models and trust), and culture (country and national variation). The study also explores intersections between these dimensions, using multivariate analysis, as well as how preferences differ according to varying types of actors as well as geography and space.
This work concerns an area of magnetoactive polymer (MAP) research seldom considered. Traditionally only MAP with high concentrations of magnetic filler (typically between 10 and 90 wt%) have been investigated. This article deals with a hitherto neglected aspect of research, namely MAP containing lower magnetic filler concentrations (1 to 3 wt%). This article utilizes a range of spectroscopic analysis methods (Raman and FTIR) and their applicability to MAP characterization at wavelengths ranging from 2.5 to 25 mu m. Particular attention is paid to low carbonyl iron particle (CIP) concentrations in MAP for which the emergence of capillary doublets at a critical 2 wt% concentration is revealed. This results in measurable magnetic field-dependent changes in IR absorption at a wavelength of 4.255 mu m together with a detectable CO2 susceptibility. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48366.
Power-to-Methane as one part of Power-to-Gas has been recognized globally as one of the key elements for the transition towards a sustainable energy system. While plants that produce methane catalytically have been in operation for a long time, biological methanation has just reached industrial pilot scale and near-term commercial application. The growing importance of the biological method is reflected by an increasing number of scientific articles describing novel approaches to improve this technology. However, these studies are difficult to compare because they lack a coherent nomenclature. In this article, we present a comprehensive set of parameters allowing the characterization and comparison of various biological methanation processes. To identify relevant parameters needed for a proper description of this technology, we summarized existing literature and defined system boundaries for Power-to-Methane process steps. On this basis, we derive system parameters providing information on the methanation system, its performance, the biology and cost aspects. As a result, three different standards are provided as a blueprint matrix for use in academia and industry applicable to both, biological and catalytic methanation. Hence, this review attempts to set the standards for a comprehensive description of biological and chemical methanation processes.
The present work aims at the thermodynamic analysis of different working pairs in adsorption heat transformers (AdHT) for low-temperature waste heat upgrade in industrial processes. Two different AdHT configurations have been simulated, namely with and without heat recovery between the adsorbent beds. Ten working pairs, employing different adsorbent materials and four different refrigerants, have been compared at varying working boundary conditions. The effects of heat recovery and the presence of a temperature gradient for heat transfer between sinks/sources and the AdHT components have been analyzed. The achieved results demonstrate the possibility of increasing the overall performance when internal heat recovery is implemented. They also highlight the relevant role played by the existing temperature gradient between heat transfer fluids and components, that strongly affect the real operating cycle of the AdHT and thus its expected performance. Both extremely low, i.e., 40-50 degrees C, and low (i.e., 80 degrees C) waste heat source temperatures were investigated at variable ambient temperatures, evaluating the achievable COP and specific energy. The main results demonstrate that optimal performance can be achieved when 40-50 K of temperature difference between waste heat source and ambient temperature are guaranteed. Furthermore, composite sorbents demonstrated to be the most promising adsorbent materials for this application, given their high sorption capacity compared to pure adsorbents, which is reflected in much higher achievable specific energy.
Tonal components can be regarded as one of the most relevant components for interior sound quality of electric vehicles, especially at low speeds. Sources for these tones are for example the vehicles' drivetrains but also other technical components. Depending on the driving conditions, due to the interaction of various dominant sources, audible tone complexes can occur. Similar to musical intervals, the different frequency ratios within these complexes can result in consonant or dissonant sensations. The strength of this sensation does not only depend on the frequency relation of the tones but also on their relative levels. In this study, different musical intervals were subjectively rated in terms of their specific consonant or dissonant character. Using an adaptive procedure, sound pairs, each consisting of a two-tone signal, where adjusted to equal dissonance by varying the level of the second tone of one of the two-tone signals. Using the same paradigm, also pairs of equal vehicle sound quality were obtained. With these results, it is possible to quantify dissonance, and theinfluence of dissonance on sound quality expressed in terms of level differences of two-tone signals. These results can help to make the concept of dissonance more useful for sound-engineering applications.
The objectives of this work include the analysis of electrical and magnetic properties of magneto-elastic hybrid materials with the intention of developing new techniques for sensor and actuator applications. This includes the investigation of dielectric properties at both low and high frequencies. The behaviour of capacitors whose dielectrics comprise magnetic hybrid materials is well known. Such interfacial magnetocapacitance can be varied according to magnetic content, magnetic flux density and the relative permittivity of the polymer matrix together with other dielectric content. The basic function of trapping electrical charges in polymers (electrets) is also established technology. However, the combination of magnetoactive polymers and electrets has led to the first electromagnetic device capable of adhering to almost any material, whether magnetically susceptible or not. During the course of this research, in addition to dielectrics, electrically conductive polymers based on (PDMS) matrices were developed in order to vary the electrical properties of the material in a targeted manner. In order to ensure repeatable results, this demanded new fabrication techniques hitherto unavailable. The 3D printing of silicones is far from being a mature technology and much pioneering work was necessary before extending the usual 3 d.o.f. to include orientation about and diffusion of particles in these three axes, thus leading to the concept of 6D printing. In 6D printing, the application of a magnetic field can be used during the curing process to control the particulate distribution and thus the spatial filler particle density as desired. Most of the devices (sensors and actuators) produced by such methods contain levels of carbonyl iron powder (CIP) embedded magnetic filler of up to 70 wt%. Contrary to this, a hitherto neglected research area, namely magnetoactive polymers (MAPs) having significantly lower magnetic particle concentrations (1 to 3 wt% CIP) were also investigated. With filler concentrations lower than 3 wt%, structures are formed which are completely absent at higher filler levels. CIP concentrations in the range of 1wt% demonstrate the formation of toroidal structures. Further development of coherent rings with a compact order results as filler concentrations increase towards 2 wt%. Above 3 wt% the structure eventually disintegrates to the usual random order found in traditional MAP with higher CIP content. Structured samples containing 1%–3 wt% CIP were investigated with the aid of X-ray tomography where solitary ring structures can be observed and eventually the formation of capillary doubles. Over wavelengths ranging from 1 to 25 µm, spectroscopic analysis of thin film MAP samples containing 2 wt% CIP revealed measurable magnetic-field-dependent changes in IR absorption at a wavenumber 2350 (λ = 4.255 µm). This was found to be due to the diamagnetic susceptibility of atmospheric carbon dioxide (CO2). Consequently, the first potential application for sparse matrix MAPs was found.
The electrical properties of rheopectic magnetoactive composites comprising boron-organo-silicon oxide dielectric matrices containing carbonyl iron microparticles are presented for the first time. The increase in interfacial magnetocapacitance is seen to greatly exceed that experienced when using conventional elastomeric matrices such as polydimethylsiloxane. In addition to the increase in capacitance, a simultaneous and sharp decrease in the parallel electrical resistance over several orders of magnitude is also observed. The effects are time dependent but repeatable. Potential applications include magnetically controlled frequency dependent devices, magnetic sensor systems, weighting elements for neural networks, etc.
As part of a systematic approach towards the search for alternative absorption heat pump (AHP) working pairs that could potentially provide comparable performance to conventional ones, a previous work performed a detailed theoretical cycle analysis and simulation that revealed concrete correlations between key working fluid thermophysical properties and AHP performance indicators. Following this work, targeted combinations of two organic refrigerants, 2,2,2-trifluoroethanol (TFE) and 2,2,3,3,3-pentafluoropropanol (5FP) and two organic absorbents, 1,3-dimethyl-2-imidazolidinone (DMI) and 2-pyrrolidone (PYR) were tested in a prototype 5 kW AHP, based on a highly compact plate heat exchanger design, which has been previously introduced. The purpose of this effort was to test the findings of the previous work with experimental measurements. The working pair combinations were also subjected to vapor liquid equilibrium (VLE) and viscosity measurements, in order to determine reliable activity coefficient and improve the accuracy of the simulations. The experimental performance data agree well with the COP simulations and show to be consistent with the conclusions derived from the previous theoretical work.
A review of the current use of multibody dynamics methods in the analysis of the dynamics of vehicles is given. Railway vehicle dynamics as well as road vehicle dynamics are considered, where for the latter the dynamics of cars and trucks and the dynamics of single-track vehicles, in particular motorcycles and bicycles, are reviewed. Commonalities and differences are shown, and open questions and challenges are given as directions for further research in this field.
Ammonia-based selective catalytic reduction (SCR) systems are the most widely used technology for reduction of nitrogen oxide emissions from lean-burn engines such as diesel engines. However, at low exhaust temperatures, the SCR process is limited by difficulties in the decomposition of the ammonia precursor urea, which is carried on-board using an aqueous solution "AdBlue". In this study, the decomposition of AdBlue urea induced by electrical current and the resulting associated pH shifts were investigated in a divided cell configuration in the liquid phase. The decomposition was found to be favored in both electrochemical compartments, anodic and cathodic, at temperatures of 60-80 degrees C compared to a reference without electrochemical treatment. In addition to the determination of ammonia contents using an ammonia sensor, IC/HPLC analyses were carried out for each sample. Different side products such as biuret, nitrate, cyanuric acid, ammelide, and others were formed. In the anodic compartment, nitrate formation could be observed due to oxidation of ammonia at the electrode surface.
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This work aims at investigating the reduction/oxidation (redox) reaction kinetics on iron oxide pellets under different operating conditions of thermochemical hydrogen storage. In order to reduce the iron oxide pellets (90% Fe2O3, 10% stabilizing cement), hydrogen (H2) is applied in different concentrations with nitrogen (N2), as a carrier gas, at temperatures between between 700 ∘C and 900 ∘C, thus simulating the charging phase. The discharge phase is triggered by the flow of a mixture out of steam (H2O) and N2 at different concentrations in the same temperature range, resulting in the oxidizing of the previously reduced pellets. All investigations were carried out in a thermo-gravimetric analyzer (TGA) with a flow rate of 250mL/min. To describe the obtained kinetic results, a simplified analytical model, based on the linear driving force model, was developed. The investigated iron oxide pellets showed a stable redox performance of 23.8% weight reduction/gain, which corresponds to a volumetric storage density of 2.8kWh/(L bulk), also after the 29 performed redox cycles. Recalling that there is no H2 stored during the storage phase but iron, the introduced hydrogen storage technology is deemed very promising for applications in urban areas as day-night or seasonal storage for green hydrogen.
Difficulties in decomposing AdBlue to ammonia limit the applicability of selective catalytic reduction systems at low exhaust temperatures. Investigations on the decomposition of AdBlue in the liquid phase under elevated pressure at temperatures up to 165 degrees C were carried out. Besides effects of inorganic catalysts, the impact of pH on urea decomposition was examined. After dissolution in aqueous phase, the compounds ZnO, WO3, and MoO3 were found to be effective in liquid-phase AdBlue decomposition. However, the efficiency was dropping significantly over few hours. Decomposition of AdBlue urea was also found to be favored for alkaline and acidic conditions.
Ultra-small-angle neutron scattering (USANS) experiments are reported on isotropic magnetoactive elastomer (MAE) samples with different concentrations of micrometer-sized iron particles in the presence of an in-plane magnetic field up to 350 mT. The effect of the magnetic field on the scattering curves is observed in the scattering vector range between 2.5 x 10(-5) and 1.85 x 10(-4) angstrom(-1). It is found that the neutron scattering depends on the magnetization history (hysteresis). The relation of the observed changes to the magnetic-field-induced restructuring of the filler particles is discussed. The perspectives of employing USANS for investigations of the internal microstructure and its changes in magnetic field are considered.
Reliability of structures and infrastructures is a major issue in structural engineering. Structural standards have traditionally been mainly concerned with public safety preventing loss of life or injury; this view has been shifting in recent years towards minimisation of economic loss. This contribution discusses the reliability differentiation principle in modern standards. Its aim is to achieve uniform risk levels for the various classes of structures. Codified criteria for reliability differentiation and risk informed decisions inherent in standards and especially in the Eurocodes are critically reviewed. It is shown that the classification of structures based on consequences of failure is an approach that has not been widely implemented in everyday design. Practical rules for the classification and implementation in design are needed and related proposals are presented.
The contribution presents a methodological procedure for the management and planning of interventions after earthquake events in small historic centres. Reference is made to the case study of Castelluccio di Norcia, a village in the Apennine Mountains affected by the seismic sequence that hit Central Italy in 2016. The earthquake risk of the area and the damaging events of 2016 are critically reviewed. The implementation of cognitive analysis and the application of advanced survey techniques involving the use of nmanned Aerial Vehicles (UAVs) for the purposes of emergency management and monitoring of damaged areas are analysed. The outcomes, combined with the direct involvement of the local population, represent a complete and integrated approach allowing the definition of a) possible intervention strategies, b) related decision criteria and c) practical recommendations for the reconstruction and regeneration of Castelluccio, and, in general, of small historic centres damaged by catastrophic events.
Axles with leaf spring suspension systems are still a popular choice in many commercial vehicles. However, leaf springs are not in perfect conformity to standard multibody vehicle models because they combine guidance and suspension in one single element. Combining standard multibody vehicle models with sophisticated finite element leaf spring models results in rather complex and computing time-consuming solutions. Purely kinematic models, defined by lookup tables or the design kinematics approach, cover only some but not all features of the leaf spring suspension. As shown here, the five-link model, which incorporates a quasi-static solution of the leaf spring compliance, provides a very practical model. It is comparatively lean and provides results of sufficient accuracy in the whole application range.
This paper decribes the concept of a course on control theory as a minor subject in the department of electrical engineering at the OTH Regensburg. The basis for a new concept is the idea of contructive alignment. The whole teaching module is devided in two blocks. The first block contains the teaching of the knowledge about control theory with an integrated approach for lectures, exercises and practical sessions. In the second block the students attent a practical work package to have the possibility to applicate and deepen their knowledge. To foster active participation the students are asked to document and reflect their work with the course context in an electronic portfolio. The exam of this module consists of three parts with respect to the different competencies obtained during the module. This concept develops not only the knowledge on control theory but personal and social competencies which are of growing interest. The aim of the paper is to present the idea of the concept. Following papers will illustrate the development process and the results obtained later on.
In order to function as soft actuators, depending on their field of use, magnetorheological elastomers (MREs) must fulfill certain criteria. To name just a few, these can include rapid response to external magnetic fields, mechanical durability, mechanical strength, and/or large deformation. Of particular interest are MREs which produce macroscopic deformation for small external magnetic field variations. This work demonstrates how this can be achieved by just a small change in magnetic field orientation. To achieve this, (super)paramagnetic nickel particles of size ≈ 160 μm were embedded in a non-magnetic polydimethylsiloxan (PDMS) (661–1301 Pa) and their displacement in a stepwise rotated magnetic field (170 mT) recorded using a video microscope. Changes in particle aggregation resulting from very small variations in magnetic field orientation led to the observation of a new strongly magneto-active effect. This configuration is characterized by an interparticle distance in relation to the angle difference between magnetic field and particle axis. This causes a strong matrix deformation which in turn demonstrates hysteresis on relaxation. It is shown that the occurrence strongly depends on the particle size, particle distance, and stiffness of the matrix. Choosing the correct parameter combination, the state can be suppressed and the particle-matrix system demonstrates no displacement or hysteresis. In addition, evidences of non-negligible higher order magnetization effects are experimentally ascertained which is qualitatively in agreement with similar, already theoretically described, particle systems. Even at larger particle geometries, the new strongly magneto-active configuration is preserved and could create macroscopic deformation changes.
Large twists of a soft tube (hollow cylinder) in helical magnetic fields are presented for the first time. Such a phenomenon is usually denoted as the Wiedemann effect. The tube is fabricated from a soft magnetoactive elastomer material with the shear modulus of about 56 kPa. The composite material comprises 80 mass% of micrometer-sized iron particles embedded into a polydimethylsiloxane matrix. The circular magnetic field is generated by an electric current in a straight wire passing through the inner hole of the tube. The maximum value of approximately 350″/cm is observed in a longitudinal magnetic field of a few kA/m overlapped with a circumferential magnetic field of about 1.4 kA/m on the surface of the inner hole. A pronounced hysteresis in the dependence of the Wiedemann effect on the circular magnetic field is found. The ways to enhance the Wiedemann twist in magnetoactive elastomers are discussed. The observed large effect is promising for application in magnetic-field controlled torsional actuators, in particular for soft robotics.
Elongations of magnetoactive elastomers (MAEs) under ascending–descending uniform magnetic fields were studied experimentally using a laboratory apparatus specifically designed to measure large extensional strains (up to 20%) in compliant MAEs. In the literature, such a phenomenon is usually denoted as giant magnetostriction. The synthesized cylindrical MAE samples were based on polydimethylsiloxane matrices filled with micrometer-sized particles of carbonyl iron. The impact of both the macroscopic shape factor of the samples and their magneto-mechanical characteristics were evaluated. For this purpose, the aspect ratio of the MAE cylindrical samples, the concentration of magnetic particles in MAEs and the effective shear modulus were systematically varied. It was shown that the magnetically induced elongation of MAE cylinders in the maximum magnetic field of about 400 kA/m, applied along the cylinder axis, grew with the increasing aspect ratio. The effect of the sample composition is discussed in terms of magnetic filler rearrangements in magnetic fields and the observed experimental tendencies are rationalized by simple theoretical estimates. The obtained results can be used for the design of new smart materials with magnetic-field-controlled deformation properties, e.g., for soft robotics.
We present a theoretical approach for calculating the state of stress induced by a uniform magnetic field in confined magnetoactive elastomers of arbitrary shape. The theory explicitly includes the magnetic field generated by magnetizable spherical inclusions in the sample interior assuming a non-linear magnetization behavior. The initial spatial distribution of particles and its change in an external magnetic field are considered. This is achieved by the introduction of an effective demagnetizing factor where both the sample shape and the material microstructure are taken into account. Theoretical predictions are fitted to the stress data measured using a specifically designed experimental setup. It is shown that the theory enables the quantification of the effect of material microstructure upon introducing a specific microstructural factor and its derivative with respect to the extensional strain in the undeformed state. The experimentally observed differences between isotropic and anisotropic samples, compliant and stiff elastomer matrices are explained.
An innovative adsorber plate heat exchanger (APHE), which is developed for application in adsorption heat pumps, chillers and thermal energy storage systems, is introduced. A test frame has been constructed as a representative segment of the introduced APHE for applying loose grains of AQSOA-Z02. Adsorption kinetic measurements have been carried out in a volumetric large-temperature-jump setup under typical operating conditions of adsorption processes. A transient 2-D model is developed for the tested sample inside the setup. The measured temporal uptake variations with time have been fed to the model, through which a micro-pore diffusion coefficient at infinite temperature of 2 E−4 [m2s−1] and an activation energy of 42.1 [kJ mol−1] have been estimated. A 3-D model is developed to simulate the combined heat and mass transfer inside the APHE and implemented in a commercial software. Comparing the obtained results with the literature values for an extruded aluminium adsorber heat exchanger coated with a 500 μm layer of the same adsorbent, the differential water uptake obtained after 300 s of adsorption (8.2 g/100 g) implies a sound enhancement of 310%. This result proves the great potential of the introduced APHE to remarkably enhance the performance of adsorption heat transformation appliances.
Die Richtlinie VDI 2500 „Faserseile“ hat 1990 erstmals zusammenfassend den Stand der Technik auf dem Gebiet der Faserseile dargestellt und wertvolle Infor-mationen über Aufbau, Auswahl, Konfek-tionierung und Überwachung von Faser-seilen gegeben. Die jetzt erscheinende zweite Auflage enthält eine Vielzahl wichtiger technischer Neuerungen für die Praxis. Zu nennen sind hier die hochfesten Fasern und deren Beschichtung sowie die erstmals systematisch aufgeführten Sei-lendverbindungen und ein Ausblick auf die zukünftig bedeutsamen sogenannten Hybridseile. Eine Checkliste hilft bei der richtigen Auswahl und Bemessung von Faserseilen. Bei den Normen wurde – soweit möglich – auf europäische Normen verwiesen.
In this contribution, field-induced interactions of magnetizable particles embedded into a soft elastomer matrix are analyzed with regard to the resulting mechanical deformations. By comparing experiments for two-, three- and four-particle systems with the results of finite element simulations, a fully coupled continuum model for magneto-active elastomers is validated with the help of real data for the first time. The model under consideration permits the investigation of magneto-active elastomers with arbitrary particle distances, shapes and volume fractions as well as magnetic and mechanical properties of the individual constituents. It thus represents a basis for future studies on more complex, realistic systems. Our results show a very good agreement between experiments and numerical simulations—the deformation behavior of all systems is captured by the model qualitatively as well as quantitatively. Within a sensitivity analysis, the influence of the initial particle positions on the systems' response is examined. Furthermore, a comparison of the full three-dimensional model with the often used, simplified two-dimensional approach shows the typical overestimation of resulting interactions in magneto-active elastomers.
Many modern composites consist of dielectric polymer matrices containing embedded spherical particles. These particles can be electrically conducting and often have magnetic properties. In order to accurately model and simulate such materials, precise calculation of the electrical capacitance between identically sized spheres is required. This is of particular relevance at microscopic dimensions where many smart material-based micro devices are concerned. This may appear trivial for a small number of particles. However, many methods or their analysis appear to be questionable or not applicable at reduced dimensions. In this work, the various methods of analysis are scrutinized before being compared with both simulation and direct measurements. It is surprising to note that of the many works investigated only 3 are in close agreement with both simulation and measurement.
Graphical abstract
This paper deals with the precise calculation of the electrical capacitance between two conducting spheres of equal, or near equal size.The calculations have been verified by both experimental measurements and simulation. Algorithms in MatLab (Octave) format have been included in the supporting information.
In composite materials, with field-dependent restructuring of the filler material (changes in the mutual arrangement of inclusions), the presence of an external magnetic field induces anisotropy of the dielectric properties, even if the composite is isotropic in the absence of an external field. A modified effective medium approximation is proposed for the calculation of the components of effective permittivity within a class of composites with reconfigurable microstructure, where both phases (the filler and the matrix) are isotropic and the inclusions have spherical shape. The effective physical properties are calculated in the parallel and perpendicular directions to an applied field. The appearance of the anisotropy of the permittivity is simulated by the introduction of two not-equal, possibly variable (field-dependent) percolation thresholds. The implications, of the proposed theoretical approach, are demonstrated for the case of the dielectric properties of magnetoactive elastomers (MAEs). In MAEs with soft polymer matrices, the mutual arrangement of micrometer-sized magnetic inclusions can significantly change in an applied magnetic field. A reasonable agreement between theory and experiment at a measurement frequency of 1 kHz is found, and is improved in comparison to the previous models. The components of the effective permittivity tensor, characterizing the dielectric properties along the direction of the applied magnetic field and in the orthogonal direction, grow with an increasing field. This growth is more pronounced for the permittivity component in the field direction. The possible extensions of the theoretical model and future directions of research are discussed. The presented theoretical approach can be useful for the application-driven development of a number of smart materials, in particular electro- and magnetorheological gels, elastomers and fluids.