9.2 Versuchsanlagen und Prüftechnik
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- Ultrasonic-assisted milling (4)
- Residual stresses (3)
- Surface integrity (3)
- Additive manufacturing (2)
- High entropy alloy (2)
- Medium entropy alloy (2)
- Welding (2)
- Alloy 36 (1)
- Alloy modification (1)
- Co-Cr-alloy (1)
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The importance of high-temperature materials made of iron aluminides (FeAl) has been increasing in light weight applications, e.g., airplane turbines, due to the high material’s specific strength. However, the highly economic production by means of permanent mold casting involves special microstructures for Fe26Al4Mo0.5Ti1B alloy components leading to difficult machinability for subsequent finishing milling and low surface qualities. Major effects of tool and machining parameter variation incorporating ultrasonic assistance on the milling process and surface integrity are shown. Loads for tool and component surface are significantly adjustable to enable an economic process chain regarding the surface integrity of safety-relevant components.
Commercial high-strength fller metals for wire arc additive manufacturing (WAAM) are already available. However, widespread industrial use is currently limited due to a lack of quantitative knowledge and guidelines regarding welding stresses and component safety during manufacture and operation for WAAM structures. In a joint research project, the process- and material-related as well as design infuences associated with residual stress formation and the risk of cold cracking are being investigated. For this purpose, reference specimens are welded fully automated with defned dimensions and systematic variation of heat control using a special, high-strength WAAM fller metal (yield strength>790 MPa). Heat control is varied by means of heat input (200–650 kJ/m) and interlayer temperature (100–300 °C). The ∆t8/5 cooling times correspond with the recommendations of fller metal producers (approx. 5–20 s). For this purpose, additional thermo-physical forming simulations using a dilatometer allowed the complex heat cycles to be reproduced and the resulting ultimate tensile strength of the weld metal to be determined. Welding parameters and AM geometry are correlated with the resulting microstructure, hardness, and residual stress state. High heat input leads to a lower tensile stress in the component and may cause unfavorable microstructure and mechanical properties. However, a sufciently low interlayer temperature is likely to be suitable for obtaining adequate properties at a reduced tensile stress level when welding with high heat input. The component design afects heat dissipation conditions and the intensity of restraint during welding and has a signifcant infuence on the residual stress. These complex interactions are analyzed within this investigation. The aim is to provide easily applicable processing recommendations and standard specifcations for an economical, appropriate, and crack-safe WAAM of high-strength steels.
The new alloying concept of multi-element systems with defined entropy (HEA—high-entropy alloy; MEA—medium-entropy alloy) is gaining increasing importance in materials research. Significantly improved properties or combinations of properties are shown by some HEA/MEA systems. Thus, primarily the production and resulting microstructures of HEA, as well as its properties, have been investigated so far. Furthermore, processing is a main issue in transferring HEA systems from the laboratory to real components. Since welding is the most important joining process for metals, it is crucial to investigate the influence of welding to guarantee component integrity. Welding leads to residual stresses, which significantly affect the component integrity. Hence, the focus of this study is the residual stress formation and distribution in a CoCrFeMnNi HEA and ternary CoCrNi MEA using two different welding processes: tungsten inert gas (TIG) welding and solid-state friction stir welding (FSW). As a pathway for the application of HEA in this investigation, for the first time, residual stress analyses in realistic near-component specimens were performed. The residual stresses were determined by X-ray diffraction (XRD) on the surfaces of top and root weld side. The results were correlated with the local welding microstructures. The results show that both FSW and TIG generate significant tensile residual stresses on the weld surfaces in, and transverse to, the welding direction. In the case of FSW of the CoCrFeMnNi HEA, the longitudinal residual stresses are in the range of the yield strength of approx. 260 MPa in the weld zone.
High- and medium-entropy alloys (HEAs) are a quite new class of materials. They have a high potential for applications from low to high temperatures due to the excellent combination of their structural properties.
Concerning their application as components; processing properties, such as machinability, have hardly been investigated so far. Hence, machinability analyses with a focus on the influence of the milling process and its basic parameters (cutting speed, feed per cutting edge) on the resulting surface integrity of specimens from an equiatomic high- (CoCrFeMnNi) and a medium- (CoCrNi) entropy alloy have been carried out. A highly innovative milling process with ultrasonic assistance (USAM) was compared to conventional milling processes.
Recent studies have shown that USAM has a high potential to significantly reduce the mechanical load on the tool and workpiece surface during milling. In this study, the basic machining and ultrasonic parameters were systematically varied. After machining, the surface integrity of the alloys was analyzed in terms of topography, defects, subsurface damage, and residual stresses. It was observed that USAM reduces the cutting forces and increases the surface integrity in terms of lower tensile residual stresses and defect density near the surfaces for the CoCrFeMnNi alloy. It was shown that the cutting forces and the metallurgical influence in the sub surface region are reduced by increasing the cutting speed and reducing the feed rate per cutting edge. With the CoCrNi alloy, the tool revealed severe wear. As a result, for this alloy no influence of the parameters on the machinability could be determined.
Influence of Surface Preparation on Cracking Phenomena in TIG-Welded High and Medium Entropy Alloys
(2022)
Multi-element systems with defined entropy (HEA—high entropy alloy or MEA—medium entropy alloy) are rather new material concepts that are becoming increasingly important in materials research and development. Some HEA systems show significantly improved properties or combinations of properties, e.g., the overcoming of the trade-off between high strength and ductility. Thus, the synthesis, the resulting microstructures, and properties of HEA have been primarily investigated so far. In addition, processing is crucial to achieve a transfer of potential HEA/MEA materials to real applications, e.g., highly stressed components. Since fusion welding is the most important joining process for metals, it is of vital importance to investigate the weldability of these materials. However, this has rarely been the subject of research to date. For that reason, in this work, the weldability depending on the surface preparation of a CoCrFeMnNi HEA and a CoCrNi MEA for TIG welding is investigated. The fusion welding of longer plates is described here for the first time for the CoCrNi alloy. The welds of both materials showed distinct formation of cracks in the heat affected Zone (HAZ). Optical and scanning electron microscopy analysis clearly confirmed an intergranular fracture topography. However, based on the results, the crack mechanism cannot be conclusively identified as either a liquid metal embrittlement (LME) or hot cracking-like liquid film separation.
Medium and High Entropy Alloys (MEA/HEA) are recently developed material classes, providing manifold applications, e.g., due to extraordinary structural properties. In that connection, the machinability as important issue for the processing of these materials was not in the scientific focus. This study focusses on experimental analysis of milling process conditions including ultrasonic assisted milling (USAM) and their effects on the resulting surface integrity of equiatomic CoCrFeNi-MEA specimens. For that reason, milling parameters (cutting speed, feed per cutting edge) were systematically varied for both conventional milling and USAM. The surface integrity was analyzed in terms of topography, defects, and residual stresses. Especially USAM leads to a decrease of occurring cutting forces and, hence, to an improvement of the surface integrity. Beneficial effects were observed in terms of lower tensile residual stresses at high cutting speed and feed per cutting edge.
Martensitic 9% Cr steels like P91 and P92 can show an increased susceptibility to delayed hydrogen-assisted cracking. The focus of this study was the microstructure and heat treatment efect on the mechanical properties of P92 base material and P91 multi-layer weld metal in both as-welded and post weld heat treated (PWHT) condition. Tensile tests with hydrogen free reference samples and electrochemically hydrogen charged samples were carried out; the mechanical properties were assessed and supported by detailed fractographic analysis. Finally, a hydrogen and microstructure-dependent fracture criterion is established. All investigated microstructures showed a hydrogen-infuenced degradation of the mechanical properties compared to the hydrogen-free reference samples. The as-welded martensitic P91 weld metal had the highest degree of degradation in the presence of hydrogen. The P91 PWHT weld metal and the P92 base material had comparable properties. From that point of view, a signifcantly increased risk for hydrogen-assisted cold cracking during welding fabrication of P91 weld joints must be considered before any heat treatment is conducted.
As onshore installation capacity is limited, the increase in the number of offshore wind turbines (OWT) is a major goal. In that connection, the OWTs continuously increase in size and weight and demand adequate foundations concepts like monopiles or tripods. These components are typically manufactured from welded mild steel plates with thickness up to 200 mm. The predominant welding technique is submerged arc welding (SAW). In accordance with the standards, the occurrence of hydrogen-assisted cracking is anticipated by either a minimum waiting time (MWT, before non-destructive testing of the welded joint is allowed) at ambient or a hydrogen removal heat treatment (HRHT) at elevated temperatures. The effectiveness of both can be estimated by calculation of the diffusion time, i.e., diffusion coefficients. In this study, these coefficients are obtained for the first time for a thick-walled S420G2+M offshore steel grade and its multi-layer SAW joint. The electrochemical permeation technique at ambient temperature is used for the determination of diffusion coefficients for both the base material and the weld metal. The coefficients are within a range of 1025 to 1024 mm2/s (whereas the weld metal had the lowest) and are used for an analytical and numerical calculation of the hydrogen diffusion and the related MWT. The results showed that long MWT can occur, which would be necessary to significantly decrease the hydrogen concentration. Weld metal diffusion coefficients at elevated temperatures were calculated from hydrogen desorption experiments by carrier gas hot extraction. They are within a range of 1023 mm2/s and used for the characterization of a HRHT dwell-time. The analytical calculation shows the same tendency of long necessary times also at elevated temperatures. That means the necessary time is strongly influenced by the considered plate thickness and the estimation of any MWT/HRHT via diffusion coefficients should be critically discussed.
Alloy 36 (1.3912) is an alloy with 36% nickel and 64% iron and is generally classified as a difficult-to-cut material. Increasingly complex structures and the optimization of resource efficiency are making additive manufacturing (AM) more and more attractive for the manufacture or repair of components. Subsequent machining of AM components is unavoidable for its final contour. By using modern, hybrid machining processes, e.g., ultrasonic-assisted milling (US), it is possible to improve the cutting situation regarding the resulting surface integrity as well as the cutting force. Part I deals with the influence of the alloying elements Ti, Zr, and Hf on the microstructure and the hardness of the initial alloy 36. Part II focusses on the effect of the alloy modifications and the ultrasonic assistance on machinability as well as on the surface integrity after finish-milling. The results show a highly significant influence of the ultrasonic assistance. The cutting force during the US is reduced by over 50% and the roughness of approx. 50% compared to conventional milling (CM) for all materials investigated. Moreover, the US causes a defect-free surface and induces near-surface compressive residual stresses. CM leads to a near-surface stress state of approx. 0 MPa.
Cobalt chromium alloys are often used in turbine and plant construction. This is based on their high thermal and mechanical stress resistance as well as their high wear resistance to corrosive and abrasive loads. However, cobalt is a cost-intensive material that is difficult to machine. Moreover, increasingly complex structures and the optimisation of resource efficiency also require additive manufacturing steps for the production or repair of components in many sectors. Concerning inhomogeneity and anisotropy of the microstructure and properties as well as manufacturing-related stresses, a lot of knowledge is still necessary for the economic use of additive welding processes in SMEs. As a result of the high stresses on the components
and requirements for a high surface quality, a complementary use of additive and machining manufacturing processes is necessary. Thereby, Co–Cr alloys are extremely challenging for machining with geometrically defined cutting edges because of their low thermal conductivity combined with high strength and toughness. An approach to solve this problem is to refine and homogenise the microstructure. This is achieved by modifying the alloy with elements zirconium and hafnium, which are added up to a maximum of 1 wt.-%. A reduction of the process forces and stresses on the tool and work piece surface is also achievable via hybrid milling processes. There are already studies on the combined use of additive and machining manufacturing processes based on laser technology. However, knowledge based on powder and wire-based arc processes is important, as these processes are more widespread. Furthermore, the effects on the surface zone of additively manufactured components by hybrid finish milling have not yet been a subject of research. The results show that the structural morphology could be significantly influenced with the addition of zirconium and hafnium.