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Environmental scanning electron microscopy (ESEM) and complementary methods were employed to study the time dependent film formation of a latex dispersion in water and cement pore solution. First, a model carboxylated styrene/n-butyl acrylate latex dispersion possessing a minimum film forming temperature (MFFT) of 18 °C was synthesized in aqueous media via emulsion polymerization. Its film forming property was at a temperature of 40 °C, studied under an ESEM. The analysis revealed that upon removal of water, film formation occurs as a result of particle packing, particle deformation and finally particle coalescence. Film formation is significantly retarded when the latex dispersion is present in cement pore solution. This effect can be ascribed to adsorption of Ca2+ ions onto the surface of the anionic latex particles and to interfacial secondary phases. This layer of adsorbed Ca2+ ions hinders interdiffusion of the macromolecules and subsequent film formation of the latex polymer.
Novel hybrid admixtures for construction applications were prepared by layer-by-layer deposition technique. Colloidal core templates consisting of styrene/n-butylacrylate latex particles were coated with multilayers of superplasticizers commonly used in concrete. This way, core-shell particles possessing both dispersing and film-forming properties were achieved. Incorporation of the latex@dispersant hybrid additive into a cement paste results in a slow release of the superplasticizer as a result of gradual shell disintegration which instigates prolonged plastification (long ”slump life”) of the cement slurry. Once the shell has been dissolved, latex particles are released into the pore solution and can coalesce into a polymer film which improves the mechanical properties of the hardened cement. Characterization of the templates and novel additives was performed by means of zeta potential measurement, dynamic light scattering and electron microscopy. Our method allows to synthesize multifunctional additives with time-controlled release effect.
Novel microcapsules were prepared from colloidal core–shell particles by acid dissolution of the organic core. Weakly crosslinked, monodisperse and spherical melamine-formaldehyde polycondensate particles (diameter ∼ 1 μm) were synthesized as core template and coated with multilayers of an anionic polyelectrolyte via layer-by-layer deposition technique. As polyelectrolytes, an anionic naphthalenesulfonate formaldehyde polycondensate that is a common concrete superplasticizer and thus industrially available, and cationic poly(allylamine hydrochloride) were used. Core removal was achieved by soaking the core–shell particles in aqueous hydrochloric acid at pH 1.6, resulting in hollow microcapsules consisting of the polyelectrolytes. Characterization of the template, the core–shell particles, and the microcapsules plus tracking of the layer-by-layer polyelectrolyte deposition was performed by means of zeta potential measurement and scanning electron microscopy. The microcapsules might be useful as microcontainers for cement additives.
Novel hybrid admixtures for construction applications were prepared by layer-by-layer deposition technique. Colloidal core templates consisting of styrene/acrylate latex particles were coated with multilayers of polycondensate-based dispersants commonly used in concrete. This way, core–shell particles possessing both dispersing and film-forming properties were achieved. Incorporation of the latex@dispersant hybrid additive into a cement paste results in a slow release of the dispersant which instigates prolonged plastification of the cement slurry. Following disintegration of the shell, the latex core particles are released into the pore solution and coalesce into a polymer film which improves the mechanical properties of the hardened cement. Characterization of the templates and novel additives plus tracking of the layer-by-layer polyelectrolyte adsorption was performed by means of zeta potential measurement, dynamic light scattering and electron microscopy. Our method allows to synthesize multifunctional additives with time-controlled release effect.
Several methods were employed to study the time dependent film formation of a self synthesized anionic latex dispersion in water and cement pore solution. First, a model carboxylated styrene/n-butyl acrylate latex dispersion possessing a minimum film forming temperature (MFFT) of 18 °C and a glass transition temperature (Tg) of 30 °C was synthesized via emulsion polymerization. Next, its film forming behaviour was studied at 40 °C, using an ESEM instrument. The analysis revealed that upon removal of water, film formation occurs as a result of particle packing, particle deformation and finally particle coalescence. Film formation is significantly hindered in synthetic cement pore solution. This effect can be ascribed to adsorption of Ca2+ ions onto the surface of the anionic latex particles and to interfacial secondary phases. This layer of adsorbed Ca2+ ions hinders interdiffusion of the macromolecules and subsequent film formation of the latex polymer.
Investigations on the interaction of cationic and anionic latex particles with Portland cement
(2008)
The interaction between organic latex polymers and the surface of hydrating cement was investigated by measuring the zeta potential and adsorbed amount of polymer on cement. First, differently charged model latex particles were synthesized in aqueous media by well-known emulsion polymerization technique. The latex polymers were characterized by differential scanning calorimetry (DSC), dynamic light scattering (DLS) and environmental scanning electron microscopy (ESEM). Electrokinetic latex surface properties were investigated by means of streaming potential measurements using a particle charge detector (PCD). It is shown that the anionic latexes adsorb a considerable amount of Ca2+ from the cement pore solution. Next, adsorption of the latex polymers on the surface of hydrating cement was confirmed by zeta potential measurements using the electroacoustic method. A water to cement ratio in the cement paste as low as 0.5 was studied, representing actual conditions in mortar and concrete. Additionally, adsorption isotherms were determined in a sedimentation test using the depletion method. For all latex polymers, Langmuir type adsorption isotherms were found. The latex dosages required to achieve saturated adsorption on the cement surface obtained from zeta potential measurements correspond well with those determined in the sedimentation test. Electron microscopy photographs confirm that the charged latex polymers adsorb selectively on surface areas of hydrating cement showing opposite charge. This way, domains of organic latex polymers exist on the cement surface. They provide adhesion between the inorganic cement matrix and the organic polymer film formed later on by particle coalescence as a result of cement hydration and drying.
The use of wood in geotechnical applications has seen renewed interest. However, concerns related to the durability and service life of wood in ground contact applications remain. Wood has the potential to substitute commonly used steel and concrete in the geotechnical engineering sector, but solutions to extending the service life and maintenance intervals require long-lasting wood protection systems capable of inhibiting fungal and bacterial decay. Cement, one of the constituents of concrete was identified as a potential coating material for wood used in soil stabilisation works. Spruce and beech wood rest rolls from commercial veneer peeling has been identified as a potential source for cement-coated geotechnical wood products. Norway spruce and European beech wood was subsequently used in this study.
In this study, a series of tests related to dimensional stability and fungal durability were undertaken to investigate the adhesion of a cement coating to wood and to assess the effect of a cement coating on the resistance to fungal decay. Swelling and shrinkage tests of uncoated specimens were undertaken to investigate dimensional stability. Laboratory fungal durability tests assessed changes in wood durability of specimens coated with a novel, flexural cement coating. Wood impregnated with Polyethyleneglycol-dimethacrylate (PEGDMA) prior to cement coating was investigated to improve wood dimensional stability and reduce cracking of the cement coating under changing wood moisture conditions. Cement coating thickness and delamination tests then assessed the durability of the novel cement coating itself. Results from fungal durability tests showed that a continuous, flexural, and crack-free cement coating was imperative to a wood durability improvement. Double cement-coated spruce wood showed improved resistance to decay by basidiomycetes (Coniphora puteana and Trametes versicolor). Results from swelling and shrinkage tests showed that an improvement in dimensional stability would assist in achieving a durable cement coating and impregnation with Polyethyleneglycol-dimethacrylate (PEGDMA) is one manner to improve dimensional stability and therefore cement adhesion to the wood substrate.