4 Material und Umwelt
Filtern
Dokumenttyp
- Posterpräsentation (137) (entfernen)
Sprache
- Englisch (137) (entfernen)
Referierte Publikation
- nein (137)
Schlagworte
- Biocides (19)
- Corrosion (10)
- Antimicrobial resistance (9)
- Biofilm (8)
- Methanogens (7)
- Persistence (7)
- Biocide (6)
- Horizontal gene transfer HGT (6)
- Microbiology (6)
- Resistance (6)
- Resistance evolution (6)
- Archaea (5)
- Bacteria (5)
- MIC (5)
- Biofilms (4)
- Evolution (4)
- Nano (4)
- Per- and Polyfluoroalkyl substances (PFAS) (4)
- Raman spectroscopy (4)
- VOC (4)
- Bacterial adhesion (3)
- Biocide tolerance (3)
- DHN melanin (3)
- Disinfection (3)
- E. coli (3)
- Environmental Simulation (3)
- Fertilzer (3)
- Fungus (3)
- Genetics (3)
- Ground water (3)
- Ink (3)
- Knufia petricola (3)
- LIPSS (3)
- Microbiologically influenced corrosion (3)
- OECD (3)
- PFAS (3)
- Reference material (3)
- Single cell analysis (3)
- Wastewater (3)
- XRF (3)
- ATR (2)
- Aluminium (2)
- Analytical method (2)
- Antibiotic resisitance (2)
- Antibiotics (2)
- Antimicrobials (2)
- Biofilm formation (2)
- Capsules (2)
- Cascade impactor (2)
- Chamber test (2)
- Combustion ion chromatography (2)
- Construction products (2)
- Corrosion products (2)
- Cross-resistance (2)
- Desinfectant (2)
- E.coli (2)
- EN 16516 (2)
- Emission (2)
- FIB/SEM (2)
- Glutaraldehyde (2)
- Halomonas CRISPR Ectoine (2)
- Heterogeneity (2)
- Horizontal gene transfer (2)
- ISO 16000-6 (2)
- Inks (2)
- Iron (2)
- Laser-induced periodic surface structures (LIPSS) (2)
- Leaching (2)
- Manuscript (2)
- Material emissions (2)
- Melanin (2)
- Mutation rate (2)
- NAP-XPS (2)
- Non-invasive analysis (2)
- Optics (2)
- Persister cells (2)
- Phosphorus (2)
- Phosphorus recovery (2)
- Prüfrichtlinie (2)
- Quality assurance (2)
- Raman Spectroscopy (2)
- Reference materials (2)
- Reflectography (2)
- Reverse glass painting (2)
- Risk assesment (2)
- Rock-inhabiting fungus (2)
- Round robin test (2)
- SC-ICP-ToF-MS (2)
- Sc-ICP-ToF-MS (2)
- Tolerance (2)
- VVOCs (2)
- Volatile organic compounds (2)
- XANES spectroscopy (2)
- Adsorbable organically bound fluorine (AOF) (1)
- Aerosol (1)
- Aerosol element alanysis (1)
- Aerosol element mass concentration (1)
- Affinity chromatography (1)
- Affinity extraction (1)
- Affinity support (1)
- Agronomic performance (1)
- Air exchange rate (1)
- Alginate (1)
- Alite (1)
- Aluminum (1)
- Aluminum oxide (1)
- Amino acid analysis (1)
- Analytical standards (1)
- Anodization (1)
- Antagonism (1)
- Anti-microbial effects (1)
- Antibodies (1)
- Antibody purification (1)
- Antimicrobial (1)
- Antimicrobial surfaces (1)
- Antimony (1)
- Aromatic amino acid analysis AAAA (1)
- Artificial ageing (1)
- Astrobiology (1)
- BFR (1)
- BSA (1)
- Bacterial growth (1)
- Bio-receptive (1)
- Bioactive glass (1)
- Bioavailability (1)
- Biocorrosion (1)
- Biodegradation (1)
- Biodiversity (1)
- Biofilm growth (1)
- Biosynthesis (1)
- Biotechnology (1)
- Black fungus (1)
- Bottom ash (1)
- Bovine serum albumin (1)
- Building product (1)
- Carbon steel corrosion (1)
- Chamber-test (1)
- Chicken manure (1)
- Chromium (1)
- Circular economy (1)
- Co-combustion (1)
- Combustion Ion Chromatography (1)
- Combustion ion chromatography (CIC) (1)
- Comsumer good samples (1)
- Concrete (1)
- Conservation (1)
- Consumer articles (1)
- Coptic (1)
- Crispr-Cas9 (1)
- Cryptoendolithic black fungus (1)
- Crystallization (1)
- DGT (1)
- DRIFTS (1)
- DSLT (1)
- Damage repair (1)
- Diffusive Gradients in thin films (DGT) (1)
- Diffusive gradients in thin films (DGT) (1)
- Diffusive sampling (1)
- Downstream processing (1)
- EDX Analysis (1)
- ESEM (1)
- Emission chamber testing (1)
- Emissions (1)
- European standard (1)
- Experimental evolution (1)
- Extracellular polymeric substances (1)
- Extractable organically bound fluorine (EOF) (1)
- Extremotolerance (1)
- Façade (1)
- Femtosecond laser processing (1)
- Fertilizer (1)
- Fiber (1)
- Fibre (1)
- Flow Model (1)
- Flow chamber system (1)
- Flow-System (1)
- Fluorescence (1)
- Fluorescent proteins (1)
- Food safety (1)
- Foward genetics (1)
- Fractional factorial (1)
- Gas chromatography - mass spectrometry (GC-MS) (1)
- Genetic engineering (1)
- Genome sequence (1)
- Geosynthetics (1)
- Glass paints (1)
- Guideline (1)
- Gypsum recycling (1)
- HAXPES (1)
- Headspace GC-MS (1)
- Herculaneum (1)
- Herteogeneous phenotypes (1)
- Heterologous expression (1)
- Hi-Tension (1)
- High resolution-continuum source-graphite furnace molecular absorption spectrometry (HR-CS-GFMAS) (1)
- Historic buildings (1)
- Human plasma (1)
- IAQ (1)
- ISO22196 (1)
- Implants (1)
- In-vivo mutagenesis (1)
- Iodine (1)
- Ir DNA staining approach (1)
- Iron oxide nanoparticles (1)
- Korrosion (1)
- LCA (1)
- LIBS (1)
- Laser structuring (1)
- Laser-induced pariodic surface structures (1)
- Loading factor (1)
- Lysimeter (1)
- MDG ICP-ToF-MS (1)
- MIC projekt (1)
- Manuscripts (1)
- Material degradation (1)
- Mathematical modelling (1)
- Medieval glasses (1)
- Metal organic frameworks (1)
- Method development (1)
- Micro plastic (1)
- Microbiological influenced corrosion MIC (1)
- Microbiologically Influrenced Corrosion (MIC) (1)
- Microcolonial fungi (1)
- Microdroplet generator (1)
- Microfluidics (1)
- Mikrobiell beeinflusste Korrosion (1)
- Mikroplastik (1)
- Mobile anodisation (1)
- Mobile application (1)
- Modelling (1)
- Modern painting (1)
- Mycotoxins (1)
- Nano particle (1)
- NanoSIMS (1)
- Nanomaterial (1)
- Nanomaterials (1)
- Nanoparticles (1)
- Nanopartikel (1)
- Nitrification inhibitor (1)
- Nitrogen (1)
- Non invasive analysis (1)
- Odour (1)
- Organo fluorine analysis (1)
- PAK (1)
- PP (1)
- PS (1)
- Papyrus (1)
- Parchment (1)
- Particle size (1)
- Particle size distributuion (1)
- Passive sampling (1)
- Per- and polyfluorinated alkyl substances (PFASs) (1)
- Perceived Intensity (1)
- Perfluorocarboxylic acid (PFCA) (1)
- Phosphonic acids (1)
- Phosphorus recycling (1)
- Pigment (1)
- Plant growth test (1)
- Plant-availability (1)
- Pollutant (1)
- Polyfluorinated alcohol (PFOH) (1)
- Polyglycerol (1)
- Polymer (1)
- Portland Cement (1)
- Poster presentation (1)
- Pot experiment (1)
- Proficiency Test (1)
- Protein a (1)
- Protein hydrolysis (1)
- Protein immobilization (1)
- Protein quantification (1)
- Pseudomonas (1)
- QA/QC (1)
- Reactive oxygen species (1)
- Red Mud (1)
- Reductive amination (1)
- Reductive iron assimilation (1)
- Remediation (1)
- Reverse painting on glass (1)
- Rock-inhabiting fungi (1)
- SCALE (1)
- SDS-PAGE (1)
- SPE extraction (1)
- Sapphire (1)
- Scandium (1)
- Schwermetalle (1)
- Selection (1)
- Sewage extraction (1)
- Sewage sludge (1)
- Sewage sludge ash (1)
- Siderophore (1)
- Signal transduction (1)
- Single cell (1)
- Sintering (1)
- Size distribution (1)
- Small angle x-ray scattering (1)
- Soil (1)
- Soil P species (1)
- Soil extraction (1)
- Solubility (1)
- Sorption (1)
- Spectroscopy (1)
- Stained glass windows (1)
- Stained glasses (1)
- Standardized test and quantification procedure (1)
- Steelmaking slag (1)
- Structural color (1)
- Sugarcane bagasse (1)
- Sum parameter analyis (1)
- Superhydrophilic surface (1)
- Superhydrophobic surface (1)
- Surfacewaters (1)
- Synchrotron (1)
- Synchrotron-XPS (1)
- Synthetic organic pigments (1)
- TED-GC/MS (1)
- TEM (1)
- TXRF (1)
- TXRF ambient air aerosol chemical analysis aerosol element composition (1)
- Termites (1)
- Test Guideline (1)
- Testguideline (1)
- Thermal extraction (1)
- Transmission electron microscopy (1)
- Tricalcium-silicate (1)
- Tyrosine (1)
- UFP (1)
- Ultrashort PFAS (1)
- Ultrashort laser processing (1)
- Uptake rate (1)
- VOC-Emission (1)
- VOC-emission (1)
- Velocimetry (1)
- Volatile organic compound (1)
- Weathering (1)
- X-ray adsorption near-edge structure (XANES) spectroscopy (1)
- X-rays (1)
- XPS (1)
- XRF Analysis (1)
- Zeolite (1)
- biocide tolerance (1)
- black fungi (1)
- disinfection (1)
- evolution (1)
- fs-laser processing (1)
- genetics (1)
- genomics (1)
- heterogeneity (1)
Organisationseinheit der BAM
- 4 Material und Umwelt (137) (entfernen)
19th and 20th centuries glass paint layers consist of a colour body and a colourless lead silicate flux, in which borax or boric acid was added as further component to improve the paint ability and to reduce the firing temperature for multiple layers of paint. Model glasses were used in laboratory tests to investigate the stability of glass paints with additions of boron oxide. To determine boron in paint layers, a LIBS-system with pulsed NdYAG-laser was used.
The church of Koszewko (Poland) is a brick building edified in the 15th century built on cobblestone foundations. There are five windows in the sanctuary. Three of them enclose heraldic panels from the Küssow’s family from the 15th century which are surrounded with Goethe glass from the 18th century to complete the windows. The colored heraldic panels are strongly damaged and corroded with massive paint layer losses, glass- and leadbreakages. Those medieval glass fragments have been shortly discovered and are of particular interest for Poland since only few medieval glazing have been conserved.
The damages as well as the glass compositions have been investigated with ESEM/EDX. Two categories of medieval glass compositions have been identified. The blue glass is particularly sensible to corrosion because of his high content in K2O. The colorless and the red glass samples belong to a stable glass type. Due to the thickness of the gel layer, it is easy to see that the degradation is strongly proceeded. The protection of those medieval stained-glass panels is absolute necessary.
The medieval panels have been restored and surrounded from a copper frame. Then they have been fixed on the wood frame in the church. The exterior glazing has been closed with a panel of Goethe glass. The gap between the Goethe- and the medieval glass is about 3 cm. The Goethe glass panel has been stabilized with a film based on polyester to protect the medieval glasses against any damages. In this way, a low cost protective glazing has been installed for a long-term conservation of each medieval stained-glass panels. The climate measurements over the period of one year on the restored windows are in process. The temperature and the relative humidity are recorded in the church interior, in the gap between the original and the Goethe glass and outdoors.
The halophilic bacterium Halomonas elongata can tolerate salt concentrations above 10% NaCl and uses the accumulation of the compatible solute ectoine as a major osmoregulatory mechanism. Ectoine can be accumalted inside the cell through import from the medium or de novo synthesis and establishes an osmotic equilibrium with the surrounding1. Ectoine also protects proteins from the effects of freezing, drying and high temperatures4 and DNA from ionizing radiation2. These features make ectoine a valuable compound for cosmetics and medical devices.
H. elongata was originally isolated from a solar salt facility, where it thrives under high salt concentrations. It was found that marine prokaryotes, which are exposed to high oxidative stress in their environment, vary glycolytic strategies5. A variation in the use of the glucose metabolic pathways is also assumed for H. elongata.
The halophilic bacterium Halomonas elongata can tolerate salt concentrations above 10% NaCl and uses the accumulation of the compatible solute ectoine as a major osmoregulatory mechanism. Ectoine can be accumalted inside the cell through import from the medium or de novo synthesis and establishes an osmotic equilibrium with the surrounding1. Ectoine also protects proteins from the effects of freezing, drying and high temperatures4 and DNA from ionizing radiation2. These features make ectoine a valuable compound for cosmetics and medical devices.
H. elongata was originally isolated from a solar salt facility, where it thrives under high salt concentrations. It was found that marine prokaryotes, which are exposed to high oxidative stress in their environment, vary glycolytic strategies5. A variation in the use of the glucose metabolic pathways is also assumed for H. elongata.
Per- and polyfluoroalkyl substances (PFAS) are a large group of organofluorine surfactants used in the formulations of thousands of consumer goods, including aqueous film-forming foams (AFFF) used to suppress aviation fires in training scenarios, non-stick cookware, fast-food wrappers, water-repellent fabrics, medical equipment, and plastic and leather products. As a result of the perpetual use of PFAS containing products, effluents and sewage sludge from wastewater treatment plants (WWTPs) have been observed to be an important pathway for PFAS into the environment. In Germany, phosphorus and other nutrients from sewage sludge and wastewater should be recycled in WWTPs of cities with a large population. However, it is not clear if PFAS contamination from wastewater and sewage sludge end up in novel wastewater-based fertilizers. Normally, PFAS are analyzed using PFAS protocols typically with time-consuming extraction steps and LC-MS-MS quantification. However, for screening of PFAS contaminations in sewage sludge or wastewater-based fertilizers also passive sampler based on the Diffusive Gradients in Thin-films (DGT) technique can be used for the PFAS extraction. Afterwards, combustion ion chromatography (CIC) can be applied to analyse the “total” amount of PFAS on the passive sampler. Here, we show results from the DGT method in comparison to those of the extractable organic fluorine (EOF) method for a variety of wastewater-based fertilizers. Additionally, we analysed the adsorption of PFAS on the weak anion exchanger (WAX) based DGT passive sampler binding layer by infrared and fluorine K-edge X-ray adsorption near-edge structure (XANES) spectroscopy.
Specific co-fertilization of nutrients can enhance their plant-availability and thus the yield of plants. To investigate this effect, we performed a pot experiment with three different P-fertilizers and ammonium nitrate sulfate as a co-fertilizer, without and with a nitrification inhibitor (NI), and analyzed the form of nitrogen (N) in the soil via novel X-ray spectroscopic method. The application of NI with the N fertilizer led to a higher dry matter yield of maize. Novel N K-edge micro-X-ray absorption near-edge structure (micro-XANES) spectroscopy identified that the application of a NI promotes the temporary formation of a non-exchangeable N in detectable hot-spots in the soil. The subsequent slow release and prolonged availability of N during plant growth leads to higher yield. It can be concluded that NIs lead to a temporary fixation of ammonium-N in a pool that can be accessed by plant roots. Those types of available nutrient pools meet the idea of so-called “next generation fertilizers” as plants have access to nutrients according to their current demand.
Over the past century, a range of synthetic compounds have been produced to improve humanity’s quality of life. These include pharmaceuticals, plastics, and other chemical compounds that possess properties making them potentially harmful when released to the environment (e.g., ecological and health impacts to humans and animals). Per- and polyfluoroalkyl substances (PFAS) are a large group of chemicals used in the formulations of thousands of consumer goods, including aqueous film-forming foams used to suppress aviation fires in training scenarios, non-stick cookware, fast-food wrappers, water-repellent fabrics, medical equipment, and plastic and leather products. Because of the recent regulations and restrictions on the use of long chain (≥C8) PFAS a significant shift in the industry towards short (C4-C7) and ultrashort (C1-C3) chain alternatives has been recognized the last years. Due to the high polarity and water solubility of ultrashort PFAS, the potential for bioaccumulation is low. However, the high persistence of ultrashort-chain PFAS will result in environmental accumulation, especially in aquatic environments, leading to potential risks for aquatic organisms and increased human external exposure through drinking water. Ultrashort PFAS like trifluoroacetic acid (TFA) are low to moderately toxic to a range of organisms. In addition, ultrashort PFAS can penetrate natural and anthropogenic barriers and eventually reach drinking water sources. Because common drinking water treatment techniques do not sufficiently remove them, they may reach human consumption. In the project we are focusing on detecting and removing PFAS, especially ultrashort-chain PFAS from contaminated groundwater. We are designing passive sampling devices, which can collect and monitor the temporal profile of PFAS species in groundwater. This will allow us to analyze PFAS contaminations in German and Israeli groundwater using state-of-the-art and novel analytical techniques and understand the extent of contamination. In addition to quantification, PFAS contaminated groundwater will be treated via a two-stage process to produce PFAS-free drinking water. As ultrashort-chain PFAS are difficult to analyze with the current target (LC-MS/MS) and sum parameter (AOF, EOF) analysis methods, we additionally using gas chromatography – mass spectrometry (GC-MS). Therefore, an analytical method based on GC-MS is in development to analyze the volatile ultrashort-chain PFAS (TFA, PFPrA, TFMS, PFEtS, PFPrS, trifluoroethanol, pentafluoropropanol and hexafluoro isopropanol) directly in contaminated groundwater samples with the headspace technique and in eluates of organic solvents from the developed passive sampler after direct injection. Moreover, a two-stages process is designed to increase the low concentrations found in groundwater using novel membranes processes such as closed-circuit reverse osmosis (CCRO) and mixed matrix composite nanofiltration membranes (MMCM). Next, the rejected streams containing higher concentrations of PFAS will be treated by coagulation, and the remaining PFAS adsorbed onto carbonaceous nanomaterials (CNMs). The DEFEAT-PFAS project will result in the development of novel tools to detect, quantify, and remove PFAS, especially ultrashort-chain PFAS from contaminated groundwater, and will acquire a new understanding of the extent of these contaminations.
The amount of plant-available phosphorus (P) in soil strongly influences the yield of plants in agriculture. Therefore, various simple chemical extraction methods have been developed to estimate the plant-available P pools in soil. More recently, several experiments with the DGT technique have shown that it has a much better correlation to plant-available P in soils than standard chemical extraction methods (e.g. calcium-acetate-lactate (CAL), Colwell, Olsen, water) when soils with different characteristics are considered. However, the DGT technique cannot give information on the plant-available P species in the soil. Therefore, we combined DGT with solution 31P nuclear magnetic resonance (NMR) spectroscopy. This was achieved by using a modified DGT device in which the diffusive layer had a larger pore size, the binding layer incorporated an adsorption material with a higher capacity, and the device had a larger exposure area. The spectroscopic investigation was undertaken after elution of the deployed DGT binding layer in a NaOH solution. Adsorption tests using solutions of known organic P compounds showed that a sufficient amount of these compounds could be adsorbed on the binding layer in order for them to be analyzed by solution 31P NMR spectroscopy. Furthermore, various intermediates of the hydrolysis of trimetaphosphate in soil could be also analyzed over time.
Phosphorus (P) resource availability is declining and the efficiency of applied nutrients in agricultural soils is becoming increasingly important. This is especially true for P-fertilizers from recycled materials which often have a lower plant-availability compared to commercial P-fertilizers but are expected to play an increasingly important role into the future (Kratz et al. 2019). One promising way to increase the plant-availability of the fertilizer P is a co-fertilization with specific nitrogen (N) forms which can enhance the P uptake and make P-fertilizers from recycled material more competitive to commercial phosphate rock-based P-fertilizers (Rahmatullah et al. 2006; Vogel et al. 2018). To investigate this effect, we performed a pot experiment with three different P-fertilizers (sewage sludge-based, phosphate rock and triple superphosphate) and ammonium nitrate sulfate as a co-fertilizer, without and with a nitrification inhibitor (NI), and analyzed the form of N and P in soil via a suite of chemical and novel X-ray spectroscopic methods. The application of NI with the P and N fertilizers led to a higher dry matter yield and a higher P uptake of maize. Novel N K-edge micro-X-ray absorption near-edge structure (micro-XANES) spectroscopy identified that the application of a NI promotes the temporary formation of a non-exchangeable N in detectable hot-spots in the soil. The subsequent slow release and prolonged availability of N during plant growth leads to higher yield and nutrient uptake. It can be concluded that NIs lead to a temporary fixation of ammonium-N in a pool that can be accessed by plant roots. Those types of available nutrient pools meet the idea of so-called “next generation fertilizers” as plants have access to nutrients according to their current demand.
Phosphorus (P) fertilizers from secondary resources became increasingly important in the last years. However, these novel P-fertilizer can also contain toxic pollutants e.g. chromium (Cr) in the hexavalent state (Cr(VI)), which is regulated with low limit values in agricultural products (German fertilizer ordinance limit: 2 mg/kg Cr(VI)). The determination of Cr(VI) in these novel fertilizer matrices can be hampered by redox processes that lead to false results with the standard wet chemical extraction method (German norm DIN EN 15192). Therefore, we analyzed Cr(VI) in various P-fertilizers with the DGT technique. DGT devices equipped with a APA (polyacrylamide) diffusion layer and Cr(VI) selective N-methyl-D-glucamine (NMDG) binding layer were used for the study. After a 24 h conditioning period of the fertilizer at 60% of the water holding capacity (WHC), the fertilizers were brought to 100% WHC, transferred onto the DGT devices and deployed for 24 h at 25°C. The extraction of Cr from the DGT binding layer was carried out with 1 M HNO3 for 24 h. The Cr-concentrations of the extract were determined by means of ICP-MS. We found a good correlation between the standard wet chemical extraction and the DGT method for the whole range of P-fertilizers. However, partly soluble Cr(VI) compounds cannot be detected in full extent by the DGT method that is best suited for mobile Cr(VI). Furthermore, Cr K-edge XANES spectroscopy showed that the Cr(VI)-selective DGT binding layer also adsorbs mobile Cr(III) compounds from acid treatment of phosphates which can therefore cause an overestimation of Cr(VI). The DGT method was very sensitive and in most cases selective for the analysis of Cr(VI) in P-fertilizers made from recycled materials. However, the results of certain types of P-fertilizers containing mobile Cr(III) or partly immobile Cr(VI) show that still some optimization of the method is required to avoid over- or underestimation of Cr(VI).