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- Tensile properties (15)
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- Werkstoffkennwerte (1)
- X2CrNiN23-4 (1)
- Zeitstandbeanspruchung (1)
- dangerous goods packagings (1)
- polyethylene terephthalate (1)
- stress cracking resistance (1)
- test methods (1)
Organisationseinheit der BAM
- 3 Gefahrgutumschließungen; Energiespeicher (27)
- 3.2 Gefahrguttanks und Unfallmechanik (27)
- 7 Bauwerkssicherheit (9)
- 7.6 Korrosion und Korrosionsschutz (9)
- 1 Analytische Chemie; Referenzmaterialien (3)
- 1.4 Prozessanalytik (3)
- 2 Prozess- und Anlagensicherheit (3)
- 2.1 Sicherheit von Energieträgern (3)
- 8 Zerstörungsfreie Prüfung (3)
- 8.1 Sensorik, mess- und prüftechnische Verfahren (3)
Eingeladener Vortrag
- nein (89)
Beständigkeitsbewertungen von Werkstoffen für den Transport von Gefahrgütern durch die BAM-Liste
(2005)
Evaluation of the resistance of alloy 31 and alloy 59 for the transport of mixed acids in tanks
(2007)
Resistance to stress cracking by wetting solution is one of the selected properties together with the corresponding test method FNCT and tolerances for a comparison of polyethylene grades of one design type in the procedural rule on suitability proof for alternative plastic resins used for packagings and intermediate bulk Containers (IBCs) for the transport of dangerous goods.
The environmental stress crack resistance determined by Full Notch Creep Test (FNCT) represents the impacts from the stacking tests at 40 °C performed with Standard liquid wetting solution (without pre-storage) and with normal butyl acetate saturated wetting solution (pre-storage with normal butyl acetate). Environmental stress crack resistance determined with FNCT for the polyethylene grades was related to the times to failure of different jerrican samples made of these grades in stacking tests with 5 % wetting solution and a n-butyl acetate saturated wetting solution (pre-storage with n-butyl acetate) at 40 °C. The FNCT is suitable for comparison of polyethylene grades in relation to environmental stress crack resistance independent of their use as drum, IBC or jerrican material. The stiffness of polyethylene grades should be taken into account to the comparison as jerricans are not only chemically but also mechanically stressed.
Use of Higher Alloyed Metallic Materials and Duplex Steels for Transport Tanks of Dangerous Goods
(2011)
Compatibility of high density polyethylene grades with bioethanol-gasoline blends and biodiesel
(2012)
Compatibility of high density polyethylene grades with bioehanol-gasoline blends and biodiesel
(2012)
Biofuels including ethanol and biodiesel (fatty acid methyl ester) represent an impor-tant renewable fuel alternative to petroleum-derived transport fuels. Increasing bio-fuel use would bring some benefits, such as a reduction in oil demands and green-house gas emissions, and an improvement in air quality.
Materials compatibility is a major concern whenever the fuel composition is changed in a fuel system.
The aim of this work is to study the interaction between sealing materials such as FKM (fluorocarbon rubber), EPDM (ethylene-propylene-diene rubber), CR (chloro-prene rubber), CSM (chlorosulfonated polyethylene), NBR (acrylonitrile-butadiene rubber), IIR (butyl rubber), VMQ (methyl-vinyl-silicone rubber) and FVMQ (methyl-fluoro-silicone rubber) and biofuels such as biodiesel, E85 (fuel with 85% ethanol) and B10 (heating oil with 10% biodiesel) at 70°C for 84 days. Experiments were con-ducted with tests specimens of theses elastomers to document the changes in the mass and tensile properties of these sealing materials according to ISO 1817.
The exposure tests of the elastomers in E85 at 70°C showed that the weight gain caused by swelling of the test specimens was in the range of 3% to 12%. However, the weight gain of the fluorinated elastomers was at the lower end of this range. Tensile strength and breaking elongation decreased by 22% to 61% or 13% to 77%. The lowest decrease in the tensile properties was determined for FKM, EPDM und IIR. These sealing materials were evaluated as resistant to E85 up to a temperature of 70°C.
Biodiesel absorbed water more quickly and aged faster than conventional diesel fuel. The weight loss of the elastomers varied between 9% (FKM) and 126% (CSM) in biodiesel. FKM was evaluated as resistant with a 16% reduction in tensile strength, a 2% reduction in breaking elongation and low weight loss. NBR, EPDM, CSM and VMQ were evaluated as not resistant. CSM even lost 84% of its original tensile strength and 78% of its breaking elongation.
The highest weight gain as a result of swelling was measured for CSM with 86%, for EPDM with 84% and for VMQ with 54% in B10, while the fluorine-containing elasto-mers FKM (1%) and FVMQ (3%) absorbed much less B10 and swelled less. FKM lost 23% in tensile strength and 17% in breaking elongation; FMVQ lost 29% in ten-sile strength and 36% in breaking elongation. FMVQ was, therefore, only limited in its resistance to B10.
The elastomers NBR, EPDM, CSM and VMQ were not resistant to B10 at all as the decrease in the tensile properties was significantly over 50%. NBR lost about 93% and CSM about 100% of its breaking elongation.
The conclusion of the investigations at 70°C is that FKM is the most resistant sealing material in biodiesel, E85 (fuel with 85% ethanol) and B10 (heating oil with 10% biodiesel).
Oxidative damage of an Intermediate Bulk Container (IBC) made of polyethylene by 53 % nitric acid
(2013)
Biofuels including ethanol and biodiesel (fatty acid methyl ester) represent an important renewable fuel alternative to petroleum-derived transport fuels. Increasing biofuel use would bring some benefits, such as a reduction in oil demands and greenhouse gas emissions, and an improvement in air quality.
Materials compatibility is a major concern whenever the fuel composition is changed in a fuel system. The question arises of whether sealing materials are resistant to fuels with bioethanol and biodiesel (rapeseed oil fatty acid methyl ester).
The aim of this work is to study the interaction between sealing materials such as FKM (fluorocarbon rubber), EPDM (ethylene-propylene-diene rubber), CR (chloroprene rubber), CSM (chlorosulfonated polyethylene), NBR (acrylonitrile-butadiene rubber), IIR (butyl rubber), VMQ (methyl-vinyl-silicone rubber), FVMQ (methyl-fluoro-silicone rubber) and PA (polyamide) and biofuels such as biodiesel (FAME, non-aged and 2 years aged), E85 (fuel with 85% ethanol) and B10 (heating oil with 10% biodiesel, non-aged and one year aged) compared with premium-grade fuel at 20°C, 40°C and 70°C for 84 days. Exposure experiments were conducted with specimens of these elastomers to document the changes in the mass and tensile properties of these sealing materials. Visual examination of some test specimens clearly showed a great volume increase until breakage or partial dissolution.
The sealing materials FVMQ, VMQ and PA were evaluated as resistant in E85 at 20°C and 40°C with a reduction of tensile properties limited to 15%. None of the examined materials was evaluated as resistant at 70°C with even fluorocarbon rubber losing 20% of its tensile strength in E85.
When exposed to biodiesel, elastomers were affected in two ways: firstly, by absorption of liquid by the elastomers and, secondly, by dissolution of soluble components from the elastomers into the liquid medium. Swelling was the result of the high absorption by the elastomers CR, CSM, EPDM, IIR and NBR in comparison to their dis-solution in non-aged and two years aged biodiesel. FKM, VMQ and PA were evaluated as resistant sealing materials in non-aged biodiesel at 40°C. FKM was still resistant in aged biodiesel at 40°C but only to a limited degree at 70°C.
The sealing materials CR, CSM, EPDM, IIR, NBR and VMQ were damaged to a high extent in non-aged and one year aged B10 as a result of swelling up to 70°C. FVMQ and PA can be evaluated as resistant in non-aged and one year aged B10 at 20°C and 40°C. However, FKM was evaluated as resistant up to 70°C.
The exposure tests showed that all the elastomers tested were resistant in the premium-grade fuel Super at 20°C. On increasing the temperature to 40°C, only FKM, VMQ and PA were resistant to Super. At 70°C FKM showed the best resistance.
In Germany the "BAM-List - Requirements for Tanks for the Transport of Dangerous Goods" is the basis for substance-related prototype approvals for tank Containers undertaken by the BAM - Federal Institute for Materials Research and Testing. Compatibility evaluations of selected metallic materials as well as of polymeric gasket and lining materials under the influence of approximately 7000 dangerous goods have been published in the BAM-List since 1989.
The duplex Steel 1.4362 (2304, UNS S32304) was originally developed as substitute for the austenitic grades 1.4404 (316L, UNS S31603) and 1.4571 (316Ti, UNS S31635). Due to its characteristic profile this Steel was qualified for applications requiring high strength values at concomitant adequate corrosion resistance. Because of its lower content of the alloy elements nickel and molybdenum this duplex Steel is a cost-efficient alternative to the molybdenum containing austenite. Only a limited number of corrosion test results of 1.4362 under the influence of dangerous goods published in the BAM-List were available. Therefore test specimens of this Steel were exposed to selected corrosive substances.
Due to the reduced alloy content a reduced corrosion resistance of the duplex Steel 1.4362 in acidic substances, such as formic acid, acetic acid and sulfuric acid, in comparison to the austenitic CrNiMosteels was observed. Tests in the alkaline medium showed a sufficient resistance.
Transportation of dangerous goods are worldwide regulated in the rules or standards e.g. in the recommendations on the Transport of Dangerous Goods of the United Nations, in the Accord Européen Relatif au Transport International des Marchandises Dangereuses par Route (ADR) etc. Addi-tional to these international regulations also national regulations and stan-dards e.g. Gefahrgutverordnung Straße und Eisenbahn (GGVSE) in Ger-many are bases for the transport of hazardous materials. For the material properties of tanks in the BAM-List Requirements for Tanks for the Transport of Dangerous Goods specifications for the sub-stance prototype approval for tank materials are listed. Further compati-bility evaluations of selected metallic material groups as well as of poly-meric gasket and lining materials under the influence of dangerous goods are published in the List. There are a large number of highly corrosive dangerous goods listed, in which conventional steels are not resistant. Chemical companies, transportation providers and tank producers need tanks made of corrosion-resistant materials (corrosion retardant materi-als) in order to protect the tank shell. The application of high-alloyed stainless steels and nickel alloys as there are alloy 926 (1.4529; X1NiCrMoCuN25-20-7), alloy 31 (1.4562;X1NiCrMoCu31-27-7) and Nickel-Chromium-Molybdenum Alloy 59 (2.4605; NiCr23Mo16Al) is an al-ternative solution compared with the lining of the tanks with a polymeric material. Due to the limited number of corrosion test results with welded test sam-ples of these high-alloyed materials under the influence of corrosive dan-gerous goods BAM, Institute for Corrosion Protection (IKS) Dresden and ThyssenKrupp VDM have been performing a comprehensive test program since 2002. The program comprised corrosion resistance evaluations of the three high-alloyed materials exposed to substances representing cor-rosive dangerous goods such as inorganic halogenides, organic acidic halogenides, sulfonic acids and nitrating acids.