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Aspects of gas generation caused by residual water inside ILW packages

  • Packages for intermediate level waste (ILW) often contain residual water besides the actual waste. The water either exists as obvious free water or it may be bound physically or chemically, e.g. as pore water. Water driven gas generation could occur by vaporisation and by radiolysis. Steam as the result of vaporisation causes an increasing pressure inside a package and can affect corrosion. Vaporisation and condensation processes itself change the thermal behaviour of the content especially during strongly unsteady thermal situations like accident fire situations. Radiolysis changes the chemical composition of the content which could cause an unexpected interaction, e.g. hydrogen embrittlement. Besides the pressure build-up the radiolysis of water generates hydrogen and oxygen, which can be highly flammable respectively explosive. The gas generation caused by vaporisation and radiolysis must be taken into account during the design and the safety assessment of a package. PressurePackages for intermediate level waste (ILW) often contain residual water besides the actual waste. The water either exists as obvious free water or it may be bound physically or chemically, e.g. as pore water. Water driven gas generation could occur by vaporisation and by radiolysis. Steam as the result of vaporisation causes an increasing pressure inside a package and can affect corrosion. Vaporisation and condensation processes itself change the thermal behaviour of the content especially during strongly unsteady thermal situations like accident fire situations. Radiolysis changes the chemical composition of the content which could cause an unexpected interaction, e.g. hydrogen embrittlement. Besides the pressure build-up the radiolysis of water generates hydrogen and oxygen, which can be highly flammable respectively explosive. The gas generation caused by vaporisation and radiolysis must be taken into account during the design and the safety assessment of a package. Pressure build-up, a changed thermal behaviour and content chemistry, and especially the risk of accumulation of combustible gases exceeding the limiting concentration for inflammability has to be considered in the safety assessment. Approaches to ensure the transportability of stored packages due to radiolysis will be discussed.zeige mehrzeige weniger

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Metadaten
Autor*innen:Marko Nehrig, Frank Wille, Martin Feldkamp, Annette Rolle
Dokumenttyp:Beitrag zu einem Tagungsband
Veröffentlichungsform:Graue Literatur
Sprache:Englisch
Titel des übergeordneten Werkes (Englisch):RAMTRANS 2015 - 10th International conference on radioactive materials transport and storage (Proceedings)
Jahr der Erstveröffentlichung:2015
Erste Seite:1
Letzte Seite:7
Freie Schlagwörter:Gas generation; ILW package; Radiolysis; Typ-B; Wet content
Veranstaltung:RAMTRANS 2015 - 10th International conference on radioactive materials transport and storage
Veranstaltungsort:Oxford, UK
Beginndatum der Veranstaltung:19.05.2015
Enddatum der Veranstaltung:21.05.2015
Verfügbarkeit des Dokuments:Datei im Netzwerk der BAM verfügbar ("Closed Access")
Datum der Freischaltung:20.02.2016
Referierte Publikation:Nein
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