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Increasingly stringent emission limits have made particulate filters necessary for gasoline engines. Similar to diesel applications, gasoline particulate filters (GPFs) can be monitored by differential pressure measurement or by the radio-frequency-based filter diagnosis (RF sensor). In addition to measuring the soot loading, ash detection is critical for monitoring the GPF over the entire vehicle lifetime. Because the RF sensor detects the filter loading through a change in the dielectric properties of the GPF, it can detect not only soot but also ash. In diesel applications, the RF sensor has already demonstrated its potential for ash detection. To verify the feasibility of simultaneous ash and soot monitoring for GPFs, filters were loaded with ash on an engine test bench and measured on a lab test bench under defined synthetic exhaust gas conditions. By evaluating resonant modes, soot and ash could be clearly distinguished, as ash mainly affects the resonant frequency, while soot also changes the quality factor due to its high dielectric losses. However, higher soot loadings could not be detected by the resonant parameters, but instead by a frequency-averaged transmission signal. While the presence of ash caused an offset in this signal, its sensitivity to soot was not affected. Thus, the influence of ash can be corrected if the signal in the soot-free filter state is known, e.g., from the behavior of the resonant parameters. Therefore, even with a continuously increasing ash loading over the lifetime of a vehicle, an accurate soot detection is possible with the RF sensor.
Owing to increasingly stringent emission limits, particulate filters have become mandatory for gasoline-engine vehicles. Monitoring their soot loading is necessary for error-free operation. The state-of-the-art differential pressure sensors suffer from inaccuracies due to small amounts of stored soot combined with exhaust gas conditions that lead to partial regeneration. As an alternative approach, radio-frequency-based (RF) sensors can accurately measure the soot loading, even under these conditions, by detecting soot through its dielectric properties. However, they face a different challenge as their sensitivity may depend on the engine operation conditions during soot formation. In this article, this influence is evaluated in more detail. Various soot samples were generated on an engine test bench. Their dielectric properties were measured using the microwave cavity perturbation (MCP) method and compared with the corresponding sensitivity of the RF sensor determined on a lab test bench. Both showed similar behavior. The values for the soot samples themselves, however, differed significantly from each other. A way to correct for this cross-sensitivity was found in the influence of exhaust gas humidity on the RF sensor, which can be correlated with the engine load. By evaluating this influence during significant humidity changes, such as fuel cuts, it could be used to correct the influence of the engineon the RF sensor.
Non-road sectors, such as agriculture and construction machinery, require high energy densities and flexibility in use, which is why diesel engines are mainly used. The use of climate-neutral fuels, produced from renewable energies, such as Oxymethylene Ether (OME) as a diesel substitute, can significantly reduce CO2 and pollutant emissions in these sectors. In addition to CO2 neutrality, OME also offers improved combustion characteristics compared to diesel fuel, eliminating the soot–NOx trade-off and thus enabling new opportunities in engine design and calibration. In this paper, the combustion of pure OME on a close-to-production, single-cylinder non-road diesel engine with a pump–line–nozzle injection system is analyzed. A variation of the center of combustion at constant power output was performed for diesel and OME at different operating points. Two injectors were investigated with OME. A study on ignition delay and a detailed thermodynamic analysis was carried out. In addition, the exhaust emissions CO, NOx, VOC, as well as particulate-matter, -number and -size distributions were measured. With OME, a significantly shorter ignition delay as well as a shortened combustion duration could be observed, despite a longer injection duration. In addition, the maximum injection pressure increases. VOC and CO emissions are reduced. Particulate matter was reduced by more than 99% and particle number (>10 nm) was reduced by multiple orders of magnitude. The median of the particle size distribution shifts from 60 to 85 nm (diesel) into a diameter range of sub 23 nm (OME). A significant reduction of NOx emissions with OME enables new degrees of freedom in engine calibration and an efficiency advantage without hardware adaption.
In recent years, particulate filters have become mandatory in almost all gasoline-powered vehicles to comply with emission standards regarding particulate number. In contrast to diesel applications, monitoring gasoline particulate filters (GPFs) by differential pressure sensors is challenging due to lower soot masses to be deposited in the GPFs. A different approach to determine the soot loading of GPFs is a radio frequency-based sensor (RF sensor). To facilitate sensor development, in previous work, a simulation model was created to determine the RF signal at arbitrary engine operating points. To ensure accuracy, the exact dielectric properties of the soot need to be known. This work has shown how small samples of soot-loaded filter are sufficient to determine the dielectric properties of soot itself using the microwave cavity perturbation method. For this purpose, mixing rules were determined through simulation and measurement, allowing the air and substrate fraction of the sample to be considered. Due to the different geometry of filter substrates compared to crushed soot samples, a different mixing rule had to be derived to calculate the effective filter properties required for the simulation model. The accuracy of the determined mixing rules and the underlying simulation model could be verified by comparative measurements on an engine test bench.
An effective way to reduce greenhouse gas emissions (GHGs) is to use rurally produced straight jatropha oil as a substitute for diesel fuel. However, the different physical and chemical properties of straight vegetable oils (SVOs) require a customized setup of the combustion engine, particularly of the injection timing and quantity. Therefore, this study demonstrates the differences in the injection and combustion processes of jatropha oil compared to diesel fuel, particularly in terms of its compatibility with exhaust gas recirculation (EGR).
A 2.2 l common-rail diesel engine with a two-stage turbocharging concept was used for testing. To examine the differences in injection rate shaping of diesel fuel and jatropha oil, the injector was tested with an injection rate analyzer using both the fuels. To investigate the combustion process, the engine was mounted at an engine test bench and equipped with a cylinder pressure indication system. All limited emissions, as well as fuel consumption, were measured.
Various injection strategies, boost and rail pressure levels were tested at different EGR rates in terms of their impact on the combustion process. EGR in particular offers a great potential in the case of jatropha oil combustion due to its oxygen content. In addition, the investigation of injection rate shaping in combination with cylinder pressure analysis allowed a detailed thermodynamic evaluation of the combustion process. Ignition delay (ID) was also analyzed using a new method to calculate the start of combustion (SOC)
The tightening of the emission legislation and political and social demands for sustainable mobility are forcing the automotive industry to develop complex, high precision mechatronic drive systems. The increasing precision of mechatronic components generally leads to an increase in structural excitation and thus to a rise in noise. The so-called ticking of the fuel injection system has a rather low sound pressure level compared to the residual engine noise. Nevertheless, the impulsive and high frequency noise character leads to a decline concerning the perception of comfort and sound quality. In order to identify the sound quality of fuel injection systems as a frontloading measure, a system test bench has been developed which represents the structure-borne and airborne sound radiation of the stand-alone injection system in a close to series configuration. In this paper, measures for the acoustic optimization of injection systems and their effects on the robustness of the system are discussed. The focus is on engine idling, since at this operating point the ticking of the injectors and high-pressure pump can be perceived most clearly due to the low masking effects of other noise sources. For this purpose, the injection parameters were measured during full engine operation and transferred to the system test bench. By using a special development control unit, it was possible to modify the parameters, quantify their influence on the acoustic behavior and, based on this, define NVH optimized control strategies. For the robustness evaluation of the NVH optimized control strategies, key functions of the injection system were analyzed under varying boundary conditions in system operation on an injection rate test bench.
To identify the sound quality of fuel injection systems as a frontloading measure, a system test bench has been developed that simulates the structure and airborne noise emission. The setup of the system test bench includes an assembly of the acoustical relevant engine parts and an encapsulated drive for the high-pressure pump. A specific control unit enables a high variability for the operation strategy of the injection system.
The focus of this study is on the development of a methodology to analyze and optimize the sound quality of gasoline direct injectors in critical operation points by suitable active means. For this, the injection parameters in engine idle have been identified and subsequently transferred to the system test bench. Additionally, the injection parameters have been optimized acoustically and the impacts on the key functions regarding injection rating and shot-to-shot scattering of the injected fuel mass are discussed.
Pure rapeseed oil fuel (R100) according to standard DIN 51605 is a greenhouse gas saving option for the mobility sector. With its high energy density close to diesel fuel, R100 is suitable to operate non-road mobile machinery with a high power demand and long operating time, where electric drives reach their limits. Advantages are indicated for its use in environmentally sensitive areas like agriculture since R100 is highly biodegradable and non-toxic. However, R100 is characterised by differing physical and chemical properties compared to diesel. The objective of the research is to investigate the differences in the ignition and combustion behaviour of R100 compared to diesel fuel (DF). For this purpose, a constant volume combustion chamber is used, which is equipped with a modern solenoid injector for engines of non-road mobile machinery. The researched injector shows a different hydraulic behaviour when using R100 compared to DF in that the injected fuel mass is lower with R100 than with DF. In combination with the 14 % by mass lower calorific value, less energy output is determined with R100. When varying the injection pressure, the impact on the ignition delay and combustion behaviour is much higher for R100 than for DF. Specifically, an increase of the injection pressure supports mixture preparation and thus partially compensates the differing physical properties of R100.
The results of ignition delay measurements and net heat release analysis are as follows: At low load conditions with low injection pressure as well as a low combustion chamber temperature and pressure, R100 ignites later and shows a further delayed combustion compared to diesel. The opposite is observed for medium and high load conditions, where R100 ignites faster and without delayed combustion in comparison to DF. Thus, an adjustment of the heat release of R100 at the same level as for DF is possible by modifying the injection strategy.
The research shows that for an optimised combustion of R100 the injection settings must be adjusted for every operation point separately. The results indicate how the injection parameters should be adjusted for different load conditions to realise a high-quality engine calibration for R100.
A new biofuel concept is developed, enabling the usage of vegetable oils and glycerol derivatives in mixtures with biodiesel. This concept significantly enhances the biodiesel production's profitability and thus strongly contributes to the sustainability of future biofuels. After simple addition reactions with building block chemicals, less hydrophilic glycerol derivatives are obtained, which are compatible with biofuels. Even more, the products of the reactions of glycerol with acetone or butyric acid, referred to as solketal and tributyrin, respectively, lead to promising biofuels in mixtures with rapeseed oil and its biodiesel. Due to their low freezing points, they act as cloud and freezing point depressants, when added to vegetable oil/biodiesel blends. Further, since their viscosity is close to common biodiesel, biofuels containing high amounts of vegetable oil and even more glycerol derivatives than they arise during the biodiesel production can be obtained. Thus, this new class of biofuels enables adaptable compositions depending on the application and also the usage as drop-in fuel without any or just few percent of further additives. After optimising the formulations, ignition delay, exhaust gas recirculation, fuel consumption and combustion process measurements were performed in an unmodified upto-date diesel engine. The experiments showed that the properties of the formulated biofuels are either similar to or even better than diesel. The hydrotropy of the glycerol derivatives in these mixtures enables the potential to implement water into biofuels, so-called hydrofuels, reducing nitrogen oxide emissions and leading to further optimised dropin fuels.
Lean-burn engines, such as diesel engines, are widely used in mobile and stationary applications. Operation of lean-burn engines leads to formation of distinct amounts of nitrogen oxides (NO and NO2). Efficient aftertreatment is mandatory to meet legal requirements, especially at low exhaust temperatures, as for the future a decline of the exhaust temperature level can be predicted due to improved engine efficiencies. Within this review, potential technical solutions to enhance the DeNO(x)-aftertreatment efficiency at low exhaust temperatures are presented.
To investigate the combustion and emission behavior of straight vegetable oils (SVO), jatropha oil, soybean oil, and diesel fuel were tested. For this research, a 2.2L common-rail engine with a two-stage turbocharging concept was equipped with a cylinder pressure indication system, an exhaust-gas analyzer, an AVL Micro Soot sensor and a Scanning Mobility Particle Sizer 3936 (SMPS) device to detect the particle-size-distribution (PSD). At a low and mid-load engine-operating point (EOP), the thermodynamic and emissions were investigated under various exhaust gas recirculation (EGR) rates with respect to the PSD. Moreover, the injection behavior of the three test fuels was analyzed separately using an injection rate analyzer. This procedure facilitates the thermodynamic investigations of the engine process and allows the calculation of the hydraulic delay (HD) as well as the ignition delay (ID). The ID of the SVO fuels compared to diesel fuel was found to be lower at all engine-operating modes, while jatropha oil always showed the shortest ID. In the particulate-nitrogen oxide (NOX) trade-off, the SVO fuels showed higher particulate matter (PM) emissions at the low-load EOP, whereas the PM emissions of diesel fuel overtop the SVO fuels at a higher engine load. With increased EGR-rates, a rise in the particle size was observed for all fuels. At the low-load EOP, the SVO fuels showed larger particles for high EGR-rates. This effect also changed by increasing the engine-load to the mid-load EOP, wherein the particle size of the diesel fuel emissions is higher by applying elevated EGR-rates.
The hydrocarbons present in the diesel exhaust gas are analyzed. A mass spectrometer is used for the measurements, and it operates on the basis of an ion-molecule reaction. This method is especially suitable because it is selective, is as free of fragments as possible, and is highly sensitive to the species that need to be measured. The study shows that numerous hydrocarbons in diesel exhaust gas can be identified. In particular, three molecules, ethyne, ethene and propene, were analyzed online in-depth on an engine test bench under different engine operating conditions.
To reduce particulate emissions, the use of particulate filters in diesel engines is meanwhile state of the art, while the integration of such systems in gasoline engines is now also necessary in order to comply with today's regulations. Over its lifetime, a gasoline particulate filter (GPF) collects ash components of fuel, lubrication oil, and materials originating from the catalytic coating and from engine abrasion. In the development and application process, synthetic ashing from GPFs is challenging. The ash of the lubrication oil can be increased in various ways, like oil-doped fuel, a separate oil burner, or changes in the piston-cylinder system of the engine. However, these methods show major disadvantages. For this reason, an improved approach is presented in this study, which allows a quick response to changes in combustion (e.g., engine knocking) and producing ash, which is more realistic due to its primary particle size and the density of ash plugs, in a shorter time. Therefore, an approach to accelerate ash loading by active oil injection using a multi-point injection (MPI) system is introduced. With the help of this methodology, an ashing capacity of 1.21 g/h is implemented, which is a high rate compared to other investigations. The primary particle size (evaluated by means of a transmission electron microscope), is in the same size range as those detected at the full-load curve during regular operation. A computer tomographic (CT) analysis of the incinerated particulate filter also shows that a very high density of ash plugs can be realized, which has also been found in the literature for real applications. In addition, with the help of a mass spectrometer (MS) and an intermediate weighing of the particulate filter, the current ash loading of the GPF could be determined with an accuracy of 1%.
The purpose of this study was to investigate the characteristic of nanoparticles under consideration of sub-23-nm particles from a 1.8-l direct injection (DI) gasoline engine under stoichiometric air/fuel conditions in the exhaust gas system. For future CO2 challenges, the usage of DI-instead of port fuel injection (PFI)-gasoline engines is unavoidable. Therefore, a state of the art particle management program-particle number (PN) system, the Horiba SPCS (2100) with an integrated CPC (condensation particle counter), was recalibrated from a 50% cutoff (D-50%) at 23 nm down to a cutoff at 10 nm and the PCRF (particle concentration reduction factor) for sizes smaller than 23 nm was checked. Two different modal points, out of a representative Real Driving Emission (RDE) cycle, were investigated with both calibrations, D-50%=10 nm and D-50%=23 nm. For these different load points, the fuel pressure (FUP) and the start of injection (SOI) were varied, to represent the difference in the structure and the ratio conc((10 nm))/conc((23 nm)) of the nanoparticle emissions. The particle characterization includes the particle number (PN), the particle size distribution (PSD), and the particle mass (PM). The particle number was measured with Horiba SPCS (2100). The particle size distribution was analyzed with a Grimm differential mobility analyzer (DMA) in combination with a Faraday cup electrometer (FCE). Micro Soot and Pegasor were used to determine the PM, and an optical characterization was done with a 120-kV Phillips CM12 transmission electron microscope (TEM). The position of all particle measurement systems was downstream the three-way catalyst (TWC). The results of this investigation showed that a higher injection pressure decreases the PN (without consideration of sub-23-nm particles) in general. The ratio conc((10 nm))/conc((23 nm)) was therefore higher, because smaller particles, especially ash particles, were less reduced from the FUP. This means higher FUP tends to a higher ratio. For the SOI, the main reasons of the ratio differences were explained by an encroachment between the injection jet and the piston, the valve and the wall.
Tonal components can be regarded as one of the most relevant components for interior sound quality of electric vehicles, especially at low speeds. Sources for these tones are for example the vehicles' drivetrains but also other technical components. Depending on the driving conditions, due to the interaction of various dominant sources, audible tone complexes can occur. Similar to musical intervals, the different frequency ratios within these complexes can result in consonant or dissonant sensations. The strength of this sensation does not only depend on the frequency relation of the tones but also on their relative levels. In this study, different musical intervals were subjectively rated in terms of their specific consonant or dissonant character. Using an adaptive procedure, sound pairs, each consisting of a two-tone signal, where adjusted to equal dissonance by varying the level of the second tone of one of the two-tone signals. Using the same paradigm, also pairs of equal vehicle sound quality were obtained. With these results, it is possible to quantify dissonance, and theinfluence of dissonance on sound quality expressed in terms of level differences of two-tone signals. These results can help to make the concept of dissonance more useful for sound-engineering applications.
Gasoline particulate filters (GPFs) are an appropriate means to meet today's emission standards. As for diesel applications, GPFs can be monitored via differential pressure sensors or using a radio-frequency approach (RF sensor). Due to largely differing soot properties and engine operating modes of gasoline compared to diesel engines (e.g., the possibility of incomplete regenerations), the behavior of both sensor systems must be investigated in detail. For this purpose, extensive measurements on engine test benches are usually required. To simplify the sensor development, a simulation model was developed using COMSOL Multiphysics((R)) that not only allowed for calculating the loading and regeneration process of GPFs under different engine operating conditions but also determined the impact on both sensor systems. To simulate the regeneration behavior of gasoline soot accurately, an oxidation model was developed. To identify the influence of different engine operating points on the sensor behavior, various samples generated at an engine test bench were examined regarding their kinetic parameters using thermogravimetric analysis. Thus, this compared the accuracy of soot mass determination using the RF sensor with the differential pressure method. By simulating a typical driving condition with incomplete regenerations, the effects of the soot kinetics on sensor accuracy was demonstrated exemplarily. Thereby, the RF sensor showed an overall smaller mass determination error, as well as a lower dependence on the soot kinetics.
Ammonia-based selective catalytic reduction (SCR) systems are the most widely used technology for reduction of nitrogen oxide emissions from lean-burn engines such as diesel engines. However, at low exhaust temperatures, the SCR process is limited by difficulties in the decomposition of the ammonia precursor urea, which is carried on-board using an aqueous solution "AdBlue". In this study, the decomposition of AdBlue urea induced by electrical current and the resulting associated pH shifts were investigated in a divided cell configuration in the liquid phase. The decomposition was found to be favored in both electrochemical compartments, anodic and cathodic, at temperatures of 60-80 degrees C compared to a reference without electrochemical treatment. In addition to the determination of ammonia contents using an ammonia sensor, IC/HPLC analyses were carried out for each sample. Different side products such as biuret, nitrate, cyanuric acid, ammelide, and others were formed. In the anodic compartment, nitrate formation could be observed due to oxidation of ammonia at the electrode surface.
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Difficulties in decomposing AdBlue to ammonia limit the applicability of selective catalytic reduction systems at low exhaust temperatures. Investigations on the decomposition of AdBlue in the liquid phase under elevated pressure at temperatures up to 165 degrees C were carried out. Besides effects of inorganic catalysts, the impact of pH on urea decomposition was examined. After dissolution in aqueous phase, the compounds ZnO, WO3, and MoO3 were found to be effective in liquid-phase AdBlue decomposition. However, the efficiency was dropping significantly over few hours. Decomposition of AdBlue urea was also found to be favored for alkaline and acidic conditions.