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Single-crystal Pd nanowires with typically 100 nm diameters and lengths from several micrometers to tens of micrometers were grown on Al 2 O 3 substrates in a furnace with Ar atmosphere. Integral field emission measurements of such samples after Pd coating (~10 nm) were performed in a diode configuration with a 50 μm mica spacer in a vacuum chamber at pressures of about 10 -9 mbar. The IV measurement of the sample shows an integral emission current up to 2 μA at a voltage of 500 V (10 MV/m) and an onset voltage for a current of 1 nA of about 275 V. The corresponding Fowler-Nordheim plot show a linear behavior, like expected for a metal needle.
Transition metal dichalcogenides such as MoS2 and WS2 are low-dimensional semiconductor materials. MoS2 and WS2 nanotubes and flakes were grown by a chemical transport reaction under a temperature gradient. I2 was used as a transport agent for previously synthesized MoS2 and WS2, respectively. These multilayered nanotubes are indirect bandgap semiconductors with a bandgap depending on their diameter. WS2 flakes were prepared by the sulfurization of thin WOx flakes. To increase the field enhancement of such low-dimensional structures by a higher aspect ratio, two approaches were examined: (a) the MoS2 and WS2 nanotubes were attached individually by a focused ion beam with Pt on dry etched n-type Si pillars and (b) the WS2 flakes were grown directly on the surface of the (n-type and p-type) Si pillars. Integral field emission measurements were performed in a diode configuration with a 50 μm mica spacer in a vacuum chamber at pressures of about 10−9 mbar. At a voltage of 900 V (18 MV/m), the integral emission current from the nanotubes is up to 11 μA for the lateral mounted MoS2 and about 1.3 μA (1.0 μA) for the upright mounted WS2 (MoS2). The onset voltage for a current of 1 nA is about 550 V for MoS2 and 500 V for WS2, respectively. The voltage conversion factor is in the range of 6 × 104–8 × 104 cm−1 for the nanotubes. The mounted MoS2 flakes show a field emission current of about 6 μA at 18 MV/m in contrast to the directly grown WS2 flakes, which show a pronounced saturation regime and, therefore, a lower emission current of about 0.5 μA is reached at 1500 V (25 MV/m). The WS2 flakes show a two times higher (1 × 105 cm−1) voltage conversion factor in comparison to the MoS2 flakes (5 × 104 cm−1). The extracted characteristics of the current-limiting part show a difference in the behavior of the extracted current-limiting characteristics between the lateral (linear) and upright mounted (exponential) nanotubes and the MoS2 flakes. In contrast, the WS2 flakes show charge carrier depletion effects.
A cathode with individually addressable Si tips allows the observation of the activation procedure and emission behaviour of each field emission emitter at any time of the measurement. The cathode consists of an array of 2x2 conically shaped emitter structures, which were fabricated by laser micromachining and wet etching of a Si substrate bonded on a glass carrier. Using the same process, a Si extractions grid was fabricated and mounted onto the emitter. Integral field emission measurements were performed in a diode configuration in a vacuum chamber at pressures of about 10- 9 mbar. The emitters show an onset voltage between 200 V and 300 V. The emission current for each emitter on the cathode was regulated to a given value (1.0 μA, 2.5μA, 5.0μA) by an external regulating circuit and was recorded individually during the measurement. With such approach, the relation between the emission behaviour and the geometry of emitters can be studied in detail. In addition, the current stabilization of each emitters of an array can be investigated, which led to a current stability of better than 0.5%.
Ästhetisches Sorgen
(2020)
Ästhetik reflektiert Kunst, kaum aber deren konkrete Verwendungsformen. Um zu verstehen, was Kunst ist, muss sie jedoch als spezifische Situationen konstituierende besondere Praxis untersucht werden. Kunst ist kein Erkennen oder Erfahren, sondern strategisches Tun: Als (feierliches) ästhetisches Sorgen kultiviert sie in öffentlichen wie privaten Kontexten eine Praxis existenziellen kultischen Sorgens. Christian Zürner hinterfragt ästhetische Topoi wie Autonomie und (Zweck-)Freiheit angesichts solch immanenter Notwendigkeit ebenso wie normative philosophische Zuschreibungen. Kunst bedeutet keinen souveränen Überschuss, sondern lebt vom Drang, menschliche Existenz in einer unheimlichen Welt überhaupt erst einzurichten.
Background:
Chronic obstructive pulmonary disease (COPD) has a functional definition. However, differences in clinical characteristics and systemic manifestations make COPD a heterogeneous disease and some manifestations have been associated with different risks of acute exacerbations, hospitalizations, and death.
Objective:
Therefore, the objective of the study was to evaluate possible clinical clusters in COPD at two study centers in Brazil and identify the associated exacerbation and mortality rate during 1 year of follow-up.
Methods:
We included patients with COPD and all underwent an evaluation composed of the Charlson Index, body mass index (BMI), current pharmacological treatment, smoking history (packs-year), history of exacerbations/hospitalizations in the last year, spirometry, six-minute walking test (6MWT), quality of life questionnaires, dyspnea, and hospital anxiety and depression scale. Blood samples were also collected for measurements of C-reactive protein (CRP), blood gases, laboratory analysis, and blood count. For the construction of the clusters, 13 continuous variables of clinical importance were considered: hematocrit, CRP, triglycerides, low density lipoprotein, absolute number of peripheral eosinophils, age, pulse oximetry, BMI, forced expiratory volume in the first second, dyspnea, 6MWD, total score of the Saint George Respiratory Questionnaire and packs-year of smoking. We used the Ward and K-means methods and determined the best silhouette value to identify similarities of individuals within the cluster (cohesion) in relation to the other clusters (separation). The number of clusters was determined by the heterogeneity values of the cluster, which in this case was determined as four clusters.
Results:
We evaluated 301 COPD patients and identified four different groups of COPD patients. The first cluster (203 patients) was characterized by fewer symptoms and lower functional severity of the disease, the second cluster by higher values of peripheral eosinophils, the third cluster by more systemic inflammation and the fourth cluster by greater obstructive severity and worse gas exchange. Cluster 2 had an average of 959 3 peripheral eosinophils, cluster 3 had a higher prevalence of nutritional depletion (46.1%), and cluster 4 had a higher BODE index. Regarding the associated comorbidities, we found that only obstructive sleep apnea syndrome and pulmonary thromboembolism were more prevalent in cluster 4. Almost 50% of all patients presented an exacerbation during 1 year of follow-up. However, it was higher in cluster 4, with 65% of all patients having at least one exacerbation. The mortality rate was statistically higher in cluster 4, with 26.9%, vs 9.6% in cluster 1.
Conclusion:
We could identify four clinical different clusters in these COPD populations, that were related to different clinical manifestations, comorbidities, exacerbation, and mortality rate. We also identified a specific cluster with higher values of peripheral eosinophils.
Algorithm selection (AS) tasks are dedicated to find the optimal algorithm for an unseen problem instance. With the knowledge of problem instances’ meta-features and algorithms’ landmark performances, Machine Learning (ML) approaches are applied to solve AS problems. However, the standard training process of benchmark ML approaches in AS either needs to train the models specifically for every algorithm or relies on the sparse one-hot encoding as the algorithms’ representation. To escape these intermediate steps and form the mapping function directly, we borrow the learning to rank framework from Recommender System (RS) and embed the bi-linear factorization to model the algorithms’ performances in AS. This Bi-linear Learning to Rank (BLR) has proven to work with competence in some AS scenarios and thus is also proposed as a benchmark approach. Thinking from the evaluation perspective in the modern AS challenges, precisely predicting the performance is usually the measuring goal. Though approaches’ inference time also needs to be counted for the running time cost calculation, it’s always overlooked in the evaluation process. The multi-objective evaluation metric Adjusted Ratio of Root Ratios (A3R) is therefore advocated in this paper to balance the trade-off between the accuracy and inference time in AS. Concerning A3R, BLR outperforms other benchmarks when expanding the candidates range to TOP3. The better effect of this candidates expansion results from the cumulative optimum performance during the AS process. We take the further step in the experimentation to represent the advantage of such TOPK expansion, and illustrate that such expansion can be considered as the supplement for the convention of TOP1 selection during the evaluation process.
A comprehensive experimental program is carried out to determine material parameters for fracture initiation and propagation in X100 pipeline steels. The quadratic Hill’48 yield function along with an isotropic hardening are used to describe plastic flow at large deformation and a phenomenological fracture criterion to predict fracture initiation. Fracture mechanics SENT specimens are used to calibrate post-initiation softening parameters necessary for ductile crack propagation in thick components. Once the material model parameters set is complete a final comparison is conducted with ring expansion test on same material.