Ingenieurwissenschaften und zugeordnete Tätigkeiten
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- 2024 (1) (entfernen)
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- C-F bond activation (1)
- Heterogeneous catalysis (1)
- ZrF4 (1)
Organisationseinheit der BAM
- 6.3 Strukturanalytik (1) (entfernen)
Kemnitz et al. developed a fluorolytic route to access metal fluorides 2 such as AlF3 3 and MgF2 4 which possess a high surface area. In aluminium-based systems, the synthetic approach led to amorphous xerogels that can be further converted into Lewis superacids.3 Still, despite zirconium oxide being described as a stronger Lewis acid than other metal oxides 4 zirconium fluoride-based materials have only recently been reported or investigated. 6 In this work we extend the class of amorphous Lewis acidic heterogeneous catalysts to an amorphous ZrF4 that is active in C-F bond activation.