Ingenieurwissenschaften und zugeordnete Tätigkeiten
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- 2017 (2) (entfernen)
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- Englisch (2)
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- Photocatalysis (2) (entfernen)
This paper presents the development of ultra-high performance concrete (UHPC) for façade elements with self-cleaning properties. For creating self-cleaning surfaces two different approaches are proposed. One approach is based on the photocatalytic activation of the external UHPC shell by incorporation of TiO2 particles. The second approach consists of the modification of the UHPC surface by micro structuring in combination with the application of hydrophobic agents to create durable super hydrophobicity. In the framework of the H-HOUSE Project funded by the European Commission the experimental investigations were performed with UHPC based on Dyckerhoff Nanodur® technology. The special properties of this material enable the precise reproduction of any micro structure without flaws. The current results obtained from laboratory and outdoor weathering tests are promising and demonstrate the feasibility of the approaches.
Photocatalysis is a promising technique to reduce volatile organic compounds indoors. Titanium dioxide (TiO2) is a frequently-used UV active photocatalyst. Because of the lack of UV light indoors, TiO2 has to be modified to get its working range shifted into the visible light spectrum. In this study, the photocatalytic degradation of toluene, butyl acetate and limonene was investigated under UV LED light and blue LED light in emission test chambers with catalysts either made of pure TiO2 or TiO2 modified with graphene oxide (GO). TiO2 coated with different GO amounts (0.75%–14%) were investigated to find an optimum ratio for the photocatalytic degradation of VOC in real indoor air concentrations. Most experiments were performed at a relative humidity of 0% in 20 L emission test chambers. Experiments at 40% relative humidity were done in a 1 m³ emission test chamber to determine potential byproducts. Degradation under UV LED light could be achieved for all three compounds with almost all tested catalyst samples up to more than 95%. Limonene had the highest degradation of the three selected volatile organic compounds under blue LED light with all investigated catalyst samples.