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. Hard coated steel components are used in a wide application range, mostly for protective, wear resistant and decorative purposes. Despite of these coatings being regarded as relatively dense, there is always a high risk of localized corrosion when a coated low alloyed steel component encounters a surrounding high humidity atmosphere or even an aqueous medium. An approach to enhance the corrosion properties is the addition of magnesium to physical vapor deposited hard coatings, like TiN. It has been found that there is a remarkable increase in corrosion resistance in dependence of magnesium content of the TiMgN coating and its surface properties. In this work the authors will explain the underlying corrosion protection mechanisms by means of electrochemical and analytical studies. The positive impact of magnesium in the coating relates on its preferred dissolution vs. steel. This causes the potential to shift to more negative direction with respect to the steel substrate and additionally leads to a temporarily passivation of the steel due to alkalization of the surrounding electrolyte by formation of magnesium hydroxide.
Magnesium (Mg) alloys have attracted much attention due to their merits of meeting requirements of lightweight, energy-efficient and environmental friendly engineering. In this study, a modified refill friction stir spot welding (refill-FSSW) method is proposed to weid AMSO Mg alloy, in which pin and sleeve rotate at different states. Effects of process parameters on the microstructure, material flow, and mechanical properties of welds were studied. Results showed that, the modified refill-FSSW technology could enhance the intennixing of material by changing the flow state. Lap shear strength of welds could be significantly improved with changed failure modes. The modified refill FSSW technology is a competitive welding method for Mg alloy.