Analytische Chemie
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At the core of luminescence color and lifetime Tuning of rare earth doped upconverting nanoparticles (UCNPs), is the understanding of the Impact of the particle architecture for commonly used sensitizer (S) and activator (A) Ions. In this respect, a series of core@Shell NaYF4 UCNPs doped with Yb3+ and Ho3+ ions are presented here, where the same dopant concentrations are distributed in different particle architectures following the scheme: YbHo core and YbHo@..., ...@YbHo, Yb@Ho, Ho@Yb, YbHo@Yb, and Yb@YbHo core-Shell NPs. As refealed by quantitative steady-state and time-resolved luminescence studies, the relative spatial Distribution of the A and S ions in the UCNPs and their protection from surface quenching has a critical Impact on ther luminescence characteristics. Although the increased amount of Yb3+ Ions boosts UCNP Performance by amplifying the Absorption, the Yb3+ ions can also efficiently dissipate the energy stored in the material through energy Migration to the surface, thereby reducing the Overall energy Transfer Efficiency to the activator ions. The results provide yet another proof that UC Phosphor chemistry combined with materials Engineering through intentional core@shell structures may help to fine-tune the luminescence Features of UCNPs for their specific future applications in biosensing, bioimaging, photovoltaics, and Display technologies.
The propagation of ultrasonic waves in concrete is affected by its micro- and macro-structure, geometry and properties as well as external influences as stress, temperature or moisture. In addition, age and degradation have a strong influence. Therefore, Ultrasound has been used to monitor concrete samples and structures since decades. However, early applications using conventional techniques as time-of flight or changes in amplitudes have been limited to detect changes in a late stage close to serviceability or ultimate load states.
Around 2000, several new, more sensitive techniques adopted from geophysics or other field of material sciences have been introduced to research in ultrasonic monitoring of concrete. The most discussed methodologies are coda wave interferometry, a technique which allows to detect very subtle changes from repeated ultrasonic measurements. Nonlinear acoustic techniques help to identify e. g. cracks even in an inhomogeneous background. Both techniques can be combined.
This paper reviews methods and results achieved so far on the laboratory scale and with full scale models the directions for future research and application is given as well.
The propagation of ultrasonic waves in concrete is affected by its micro- and macro-structure, geometry and properties as well as external influences as stress, temperature or moisture. In addition, age and degradation have a strong influence. Therefore, Ultrasound has been used to monitor concrete samples and structures since decades. However, early applications using conventional techniques as time-of flight or changes in amplitudes have been limited to detect changes in a late stage close to serviceability or ultimate load states.
Around 2000, several new, more sensitive techniques adopted from geophysics or other field of material sciences have been introduced to research in ultrasonic monitoring of concrete. The most discussed methodologies are coda wave interferometry, a technique which allows to detect very subtle changes from repeated ultrasonic measurements. Nonlinear acoustic techniques help to identify e. g. cracks even in an inhomogeneous background. Both techniques can be combined.
This paper reviews methods and results achieved so far on the laboratory scale and with full scale models the directions for future research and application is given as well.