7.4 Baustofftechnologie
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- Structural build-up (5)
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- Accelerated testing (2)
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- Bingham fluid (2)
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- Papierasche (1)
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- Potato starch (1)
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Organisationseinheit der BAM
- 7 Bauwerkssicherheit (29)
- 7.4 Baustofftechnologie (29)
- 3 Gefahrgutumschließungen; Energiespeicher (2)
- 3.1 Sicherheit von Gefahrgutverpackungen und Batterien (2)
- 4 Material und Umwelt (2)
- 4.4 Thermochemische Reststoffbehandlung und Wertstoffrückgewinnung (2)
- 7.1 Baustoffe (2)
- 7.7 Modellierung und Simulation (2)
- 8 Zerstörungsfreie Prüfung (2)
- 8.2 Zerstörungsfreie Prüfmethoden für das Bauwesen (2)
Paper des Monats
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Eingeladener Vortrag
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Alkali-silica reaction (ASR) is a chemical reaction within concrete which can lead over time to cracking and spalling. Due to the complexity of the problem, it still causes damage to concrete constructions worldwide.
The publication aims to illustrate the interdisciplinary research of the German Federal Institute for Materials Research and Testing (BAM) within the last 20 years, considering all aspects of ASR topics from the macro to the micro level. First, methods for characterization and assessment of ASR risks and reaction products used at BAM are explained and classified in the international context. Subsequently the added value of the research approach by combining different, preferably nondestructive, methods across all scales is explained using specific examples from a variety of research projects. Aspects covered range from the development of new test-setups to assess aggregate reactivity, to analysis of microstructure and reaction products using microscopical, spectroscopical and X-ray methods, to the development of a testing methodology for existing concrete pavements including in-depth analysis of the visual damage indicator and the de-icing salt input using innovative testing techniques. Finally, research regarding a novel avoidance strategy that makes use of internal hydrophobization of the concrete mix is presented.
Cementitious materials are frequently applied in environments in which they are exposed to acid attack, e.g., in sewer systems, biogas plants, and agricultural/food-related industries. Alkali-activated materials (AAMs) have repeatedly been shown to exhibit a remarkably high resistance against attack by organic and inorganic acids and, thus, are promising candidates for the construction and the repair of acid-exposed structures. However, the reaction mechanisms and processes affecting the acid resistance of AAMs have just recently begun to be understood in more detail. The present contribution synthesises these advances and outlines potentially fruitful avenues of research. The interaction between AAMs and acids proceeds in a multistep process wherein different aspects of deterioration extend to different depths, complicating the overall determination of acid resistance. Partly due to this indistinct definition of the ‘depth of corrosion’, the effects of the composition of AAMs on their acid resistance cannot be unambiguously identified to date. Important parallels exist between the deterioration of low-Ca AAMs and the weathering/corrosion of minerals and glasses (dissolution-reprecipitation mechanism). Additional research requirements relate to the deterioration mechanism of high-Ca AAMs; how the character of the corroded layer influences the rate of deterioration; the effects of shrinkage and the bond between AAMs and substrates.
The current understanding of the carbonation and the prediction of the carbonation rate of alkali-activated concretes is complicated inter alia by the wide range of binder chemistries used and testing conditions adopted. To overcome some of the limitations of individual studies and to identify general correlations between mix design parameters and carbonation resistance, the RILEM TC 281-CCC ‘Carbonation of Concrete with Supplementary Cementitious Materials’ Working Group 6 compiled and analysed carbonation data for alkali-activated concretes and mortars from the literature. For comparison purposes, data for blended Portland cement-based concretes with a high percentage of SCMs (≥ 66% of the binder) were also included in the database. The analysis indicates that water/CaO ratio and water/binder ratio exert an influence on the carbonation resistance of alkali-activated concretes; however, these parameters are not good indicators of the carbonation resistance when considered individually. A better indicator of the carbonation resistance of alkali-activated concretes under conditions approximating natural carbonation appears to be their water/(CaO + MgOeq + Na2Oeq + K2Oeq) ratio, where the subscript ‘eq’ indicates an equivalent amount based on molar masses. Nevertheless, this ratio can serve as approximate indicator at best, as other parameters also affect the carbonation resistance of alkali-activated concretes. In addition, the analysis of the database points to peculiarities of accelerated tests using elevated CO2 concentrations for low-Ca alkali-activated concretes, indicating that even at the relatively modest concentration of 1% CO2, accelerated testing may lead to inaccurate predictions of the carbonation resistance under natural exposure conditions.
The structural build-up of fresh cement paste is often considered as a purely thixotropic phenomenon in literature even though cementitious materials undergo a non-reversible hydration process that can have an influence on the structuration process. In the current paper a method is proposed to validate the impact of the non-reversible structural build-up. It is shown that fresh cement paste samples lose their structural gain almost completely due to thixotropy while the structural build-up due to hydration can be observed but occurs in a significantly lower order of magnitude over the course of the first hours of hydration. In addition, it is shown, that the chemical component of the structural build-up accelerates with the onset of the acceleration period of hydration, while its contribution in the entire structural build-up remains constant.
The 87Sr/86Sr isotope ratio can, in principle, be used for provenancing of cement. However, while commercial cements consist of multiple components, no detailed investigation into their individual 87Sr/86Sr isotope ratios or their influence on the integral 87Sr/86Sr isotope ratio of the resulting cement was conducted previously. Therefore, the present study aimed at determining and comparing the conventional 87Sr/86Sr isotope ratios of a diverse set of Portland cements and their corresponding Portland clinkers, the major component of these cements. Two approaches to remove the additives from the cements, i.e. to measure the conventional 87Sr/86Sr isotopic fingerprint of the clinker only, were tested, namely, treatment with a potassium hydroxide/sucrose solution and sieving on a 11-µm sieve. Dissolution in concentrated hydrochloric acid/nitric acid and in diluted nitric acid was employed to determine the 87Sr/86Sr isotope ratios of the cements and the individual clinkers. The aim was to find the most appropriate sample preparation procedure for cement provenancing, and the selection was realised by comparing the 87Sr/86Sr isotope ratios of differently treated cements with those of the corresponding clinkers. None of the methods to separate the clinkers from the cements proved to be satisfactory. However, it was found that the 87Sr/86Sr isotope ratios of clinker and cement generally corresponded, meaning that the latter can be used as a proxy for the clinker 87Sr/86Sr isotope ratio. Finally, the concentrated hydrochloric acid/nitric acid dissolution method was found to be the most suitable sample preparation method for the cements; it is thus recommended for 87Sr/86Sr isotope analyses for cement provenancing.
Für die flächige Instandsetzung von Stahlbetonkonstruktionen kommen nahezu ausschließlich zementgebundene Systeme mit hohem Zementgehalt zum Einsatz (1). Bereits 2008 war die Zementproduktion für 5% des weltweiten, anthropogenen CO2-Ausstoßes verantwortlich (2). Um die prozessbedingten CO2-Emissionen zu senken, wird der Zement bereits durch gewisse Mengen an Sekundärrohstoffen wie Flugasche, Silicastaub oder Hüttensandmehl (Hochofenschlacke) substituiert. Das Potenzial für weitere Modifikationen ist inzwischen begrenzt (3). Zudem ist eine hohe Lebensdauer der Konstruktionen in vielen Anwendungsbereichen nur bedingt realisierbar. Spätestens mit Erreichen der geplanten Nutzungsdauer müssen Stahlbetonkonstruktionen mit zementgebundenen Systemen instandgesetzt werden, was im ökonomischen und ökologischen Sinne keine nachhaltige Lösung darstellt. Die Verwendung neuer Baustoffe wie alkalisch aktivierte Mörtel hält sich bisher in Grenzen (4), sodass die Akzeptanz durch praxisnahe Forschung adressiert werden muss.
Vorangegangene Forschungsergebnisse zeigen, dass alkalisch aktivierte Bindemittel vielversprechende technische Eigenschaften besitzen. So zeigen sich im Vergleich zu herkömmlichem Portlandzement ein ausgesprochen wirkungsvoller Verbund zu Stahl und Zementmörtel (5), (6), eine hohe chemische Beständigkeit sowie ein Erfolg versprechendes Abwitterungsverhalten bei Frost-Tau-Wechseln (7). Mit diesen Eigenschaften können alkalisch aktivierte Mörtel einen erheblichen Beitrag zur dauerhaften Betoninstandsetzung leisten und somit durch die verringerten CO2-Emmissionen dem Prinzip des nachhaltigen Bauens gerecht werden. Wichtig für die Produktion im größeren Maßstab ist die Verfügbarkeit der möglichen Reststoffe, um eine CO2-positivere Bilanz abzubilden.
Im Zuge des Forschungsvorhabens sollen Rezepturen für Instandsetzungsprodukte entworfen werden, die auf alkalisch aktivierte industrielle Reststoffe zurückgreifen und die Anforderungen an konventionelle Instandsetzungsprodukte erfüllen. Hierzu wurden potenzielle Ausgangs-stoffe mit Natriumcarbonat aktiviert und die Verarbeitbarkeit der Leime sowie die Druckfestigkeiten nach sieben Tagen verglichen. Hüttensandmehl reagiert ausreichend mit diesem Aktivator, was sich mit Ergebnissen von (8) und (9) deckt. Es werden 〖CO〗_3^(2-)-Ionen in das System eingebaut, was zu einer anfänglichen Erstarrung des Gefüges durch die Bildung von Carbonaten (Calcit und Hydrotalcit) führt. Nach einer längeren dormanten Phase bilden sich zusätzlich Hydratphasen, die die Festigkeit weiter erhöhen. Weiterhin ist die chemische Zusammensetzung der Schlacken für die Erhärtung und die späteren Eigenschaften von großer Bedeutung (10), (11), was mit einer Parameterstudie im laufenden Jahr an natriumcarbonataktivierten Schlacken näher betrachtet werden soll. Erkenntnisse aus vergleichenden Versuchen durch (12) bestätigen die Einflussnahme der chemischen Zusammensetzung. Die übrigen Reststoffe konnten mit anderen Aktivatoren (z. B. Natriumsilicat und -hydroxid) zu einer Reaktion angeregt werden. Im Hinblick auf die Akzeptanz der alkalisch aktivierten Bindemittel stellen diese Aktivatoren jedoch bei der Herstellung höhere technische Anforderungen an das Personal und die verwendeten Geräte im Vergleich zur konventionellen Beton- und Mörteltechnik. Die Aktivierung mittels Alkalicarbonaten ermöglicht die Herstellung von Beton bzw. Mörtel nach dem üblichen „just add water“-Prinzip (13).
Aktuell wird unter Einbindung einer studentischen Abschlussarbeit eine Rezeptur mit Hüttensandmehl hinsichtlich der Frisch- und Festeigenschaften charakterisiert und einer Referenzmischung – basierend auf Portlandzement – gegenübergestellt. Hieraus resultierende Ergebnisse sollen neben den Erkenntnissen aus den Vorversuchen zur Konferenz vorgestellt und ein Ausblick auf die weitere Forschungsarbeit gegeben werden.
Die Zementindustrie erzeugt etwa 6-7% der globalen CO2-Emissionen und steht damit als Industriezweig vor dem Hintergrund einer anvisierten Klimaneutralität vor gewaltigen Herausforderungen. Der Prozess der Klinkerherstellung wurde über die vergangenen Jahrzehnte bereits kontinuierlich optimiert. Seit 1990 ist es der deutschen Zementindustrie gelungen, die spezifischen CO2-Emissionen der Zementproduktion u. a. durch den Einsatz alternativer, nicht fossiler Brennstoffe und durch Absenkung des Klinkergehalts im Zement um 20 % zu senken. Weitere konventionelle Minderungsstrategien versprechen jedoch nur noch wenig zusätzliche Reduktion. Im Falle des Portlandklinkers besteht die Schwierigkeit darin, dass zwei Drittel der CO2-Emissionen rohstoffbedingt durch die Entsäuerung des Kalksteins (CaCO3) anfallen, die durch die beschriebenen Maßnahmen nicht weiter abgesenkt werden können. Vielmehr wird es erforderlich sein, noch zu entwickelnde oder zu optimierende Technologien anzuwenden und ggf. alle relevanten Ebenen wie Produktion, Weiterverarbeitung und Anwendung von Zement und Beton neu zu denken. Neben technologischen Ansätzen zur CO2-Abscheidung mit nachfolgender langfristiger Speicherung (Carbon Capture and Storage – CCS) oder Verwertung (Carbon Capture and Utilisation – CCU) werden auch alternative Rohstoffe für die Zementproduktion und alternative Bindemittel in Betracht zu ziehen sein.
To ensure safety when transporting dangerous goods, it is important to specify the flow properties of the respective solid filling substance of the packagings. For this purpose, the angle of repose is currently used for the UN approvals in Germany. Measurements were carried out on 12 powdery or granular substances applying the angle of repose measuring methods customary in the test centres. The results of the methods differ significantly from each other. In addition, some of the techniques cannot be applied for very cohesive or coarse-grained materials. The results for the angle of repose show a strong scatter for some constellations (coefficient of variation more than 20 %). Safety during transport of dangerous goods cannot be guaranteed with this currently practiced system of measuring the angle of repose. As a consequence, an alternative parameter to characterize the flow properties of bulk materials should be used in the recognized test centers for dangerous goods packagings, such as the Hausner ratio. This approach leads to more precise test results for the substances examined (maximum coefficient of variation 2.8 %). It also has advantages in terms of applicability and occupational safety.
Since the flow properties are safety-relevant, both in terms of mechanical safety and safety against the release of dangerous substances, the testing practice in the recognized test labs should be improved and standardized.
To ensure safety when transporting dangerous goods, it is important to specify the flow properties of the respective solid filling substance of the packagings. For this purpose, the angle of repose is currently used for the UN approvals in Germany. Measurements were carried out on 12 powdery or granular substances applying the angle of repose measuring methods customary in the test centres. The results of the methods differ significantly from each other. In addition, some of the techniques cannot be applied for very cohesive or coarse-grained materials. The results for the angle of repose show a strong scatter for some constellations (coefficient of variation more than 20 %). Safety during transport of dangerous goods cannot be guaranteed with this currently practiced system of measuring the angle of repose. As a consequence, an alternative parameter to characterize the flow properties of bulk materials should be used in the recognized test centers for dangerous goods packagings, such as the Hausner ratio. This approach leads to more precise test results for the substances examined (maximum coefficient of variation 2.8 %). It also has advantages in terms of applicability and occupational safety.
Since the flow properties are safety-relevant, both in terms of mechanical safety and safety against the release of dangerous substances, the testing practice in the recognized test labs should be improved and standardized.
Basic oxygen furnace slag (BOFS) is a by-product of steelmaking of which about 10.4 Mt are produced annually in the EU. BOFS is mostly used in road construction, earthwork and hydraulic engineering. However, in this use, the iron bound in BOFS is lost and the opportunity to produce higher value products from BOFS is forgone.
In recent decades, many researchers have investigated a thermochemical process to reduce iron oxides to metallic iron in molten BOFS. The metallic iron formed separates from the reduced slag due to its higher density and can be recovered. An advantage of this process is that simultaneously the chemical composition of the reduced slag is adapted to that of the Portland cement clinker and the hydraulic reactive mineral alite is formed.
In this study, BOFS was reduced in a small-scale electric arc furnace using petrol coke as reducing agent, and the hydraulic properties of the reduced, low-iron BOFS were investigated. Despite a chemical and mineralogical composition similar to that of Portland cement clinker, the reduced BOFS produced less heat of hydration, and its reaction was delayed compared to Portland cement. However, the addition of gypsum, as is also done in cement production from Portland cement clinker, has been found to accelerate the hydration rate of reduced BOFS.
Further research to improve the hydraulic properties of the reduced slag is essential. If successful, the production of a hydraulic binder and crude iron from BOFS could have economic and ecological benefits for both the cement and steel industry.
In general, pH-sensitive colorants such as phenolphthalein are applied on freshly split surfaces of building structures to determine the state of carbonation. For years, it has been known that the aerosols of phenolphthalein are suspected of being carcinogenic. Hence, more work has currently being done on alternative indicators for the use in research and the use on construction sites. Over the past years, mainly pH indicators from other research areas and natural dyes were investigated for their usability to cementitious systems. This paper presents the experimental results of using phenolphthalein solution bound in agar-agar gel. This gel-bound indicator allows the future use of the already known phenolphthalein dye without the health hazards for the user. To demonstrate the flexibility of the gel-bound colorant, different application forms of the indicator were carried out and assessed. In addition, the results obtained by the different methods were statistically evaluated to ensure validity.
The accuracy of the results was confirmed by thermogravimetric analysis and IR spectroscopic studies as reference methods. It has also succeeded to demonstrate the comparability of the results achieved by the gel-bound colorant with the results of the common sprayed application method. As an additional gain in knowledge, comparative results of indicator tests, TGA analysis, and FTIR investigation are shown.
Ziel des Projekts HYTEGRA ist die Herstellung leichter Gesteinskörnungen durch hydrothermale Behandlung quarz- und kalkreicher Reststoffe. Als Ausgangsstoffe dienen heterogener Mauerwerkbruch aus Bau- und Abbruchabfällen als SiO2-Träger und Papierasche aus dem Altpapierrecycling als CaO-Träger. Für beide Reststoffe besteht derzeit ein Verwertungsdefizit. Das Verfahren beruht auf der Idee des rohstofflichen Recyclings, d. h. die chemisch-mineralogischen Stoffeigenschaften werden für die hydrothermale Stoffumwandlung genutzt. Bei der Härtung der Hydrothermalgranulate bilden sich Calciumsilicathydrat-Phasen (CSH) aus der Reaktion zwischen Quarzpartikeln und Kalk im Autoklav bei 200 °C und 16 bar Sattdampf.
Calcined clays as supplementary cementitious materials (SCMs) have been identified and credited to be a viable solution in mitigating the CO2 emissions related to cement production and consumption. Calcined clays range from a variety of different clay types based on an assortment of varying minerals and compositions. While extensive data is available on kaolinitic clays (based on the 1:1 clay type), other clays such as brick clays (based on the 2:1 clay type) are currently understudied, although such clays are largely more available than the kaolinitic clays.
The aim of this thesis is to draw attention to the varying compositions present in two selected brick clays in Germany and elaborate on how such compositions affect their suitability to be used as SCMs in blended cement systems. The novelty of this thesis explains the relationship between the reactivity of the bricks to their varying compositions and their suitability for their employment as SCMs. This was based on their chemical and physical transformations in the calcination temperature range 650–900 or 950 °C, and the performance of the calcined brick clays in blended cement systems measured by their heat evolution, strength development and durability-related properties. The results of their performance were compared to two kaolinitic clays with varying compositions. While the kaolinitic clays generally exhibited the best performance as SCMs, the brick clay with a lower Fe2O3 content showed promising results similar to the kaolinitic clays when an optimum calcination temperature is applied and when substituted at a moderate cement substitution rate. Thus, this finding promoted further efforts made to improve the reactivity of the brick clay by producing a mixed clay composed of 50 % brick clay (with lower Fe2O3 content) and 50 % kaolinitic clay. The mixed clay was compared to the two individual brick clays and one kaolinitic clay, whereby optimum calcination conditions were performed in large-scale simulating an industrial-scale production of SCMs. All calcined clays exhibited pozzolanic reactivity, with the performance of the brick clays inferior to the kaolinitic clay, however, the mixed clay performed very similar to the kaolinitic clay.
At a similar degree of hydration compared to plain Portland cement, the good performance of the mixed clays was especially evident in the strength development and improved chloride penetration resistance, which was caused by a refinement in the pore structure in the cementitious systems. Moreover, it was deduced that not only the high surface area, but also, the solubility of Si and Al ions in the resulting calcinate of the mixed clays plays a significant role when calcined at ~600–700 °C, which points to viable options for optimal employment of brick clays in cementitious systems.
Aim of this study is to provide information about moisture dependent material behaviour of unstabilised loadbearing earth blocks and mortars. Compressive strength and Young’s modulus were investigated after conditioning in varying relative humidity reaching from 40 % up to 95 %. The material composition and physical properties were investigated to understand the influence of relative humidity onto the mechanical properties. A normalisation of strength and stiffness by the values obtained at 23 ◦C and 50 % relative humidity reveals a linear dependence of compressive strength and Young’s modulus that is regardless of the material composition.
Thus, it is possible to describe the influence of relative humidity onto the load-bearing behaviour of unstabilised earth masonry materials in a generally valid formulation.
Influence of the hydroxypropylation of starch on its performance as viscosity modifying agent
(2022)
Synopsis: Starch is a commonly used viscosity modifying agent (VMA). The performance of starch as VMA depends on its origin (e.g. potato, corn, cassava, etc.) and corresponding molecular properties, such as molecular weight, ratio between amylose and amylopectin etc. Depending upon the application, the efficiency of starch can be enhanced by hydroxypropylation. The maximum degree of substitution (DoS) cannot be greater than 3.0, which is the number of hydroxy groups per glucose monomer in the polymer. In the current research three potato starches exhibiting the DoS of 0.4, 0.6 and 0.8 were utilised. The influence of the modified starch on the rheological properties and hydration of cement paste, as well as the viscosity of the pore solution were investigated. Our findings show that the starch with the highest DoS increases the dynamic yield stress the most, while the plastic viscosity is less dependent on the DoS. Additionally, starch with the highest DoS retards hydration to lower degree than other starches.
Organic admixtures are an indispensable component of modern concrete. Thus, their purposeful application is not only technically and economically viable but in addition an inevitable tool to make concrete more environmentally friendly. In this context, the use of polysaccharides has increasingly gained interest in the built environment as sustainable resource for performance enhancement. However, due to its origin, biopolymers possess a vast variety of molecular structures which can result in incompatibilities with other polymers present in concrete, such as superplasticizers. The present study highlights effects of the joint application of different types of starches and polycarboxylates with respect to their influence on cement hydration and structural build-up of cement pastes.
Introduction of a monitoring system for Bingham fluids in additive manufacturing with concrete
(2022)
Freeform additive manufacturing of concrete structures is a rising technology in civil engineering with several fascinating advantages. Nonetheless, to ensure reliability and structural integrity, standards and quality control are required in the future to bring this technology into the market. As the concrete is manufactured continuously, continuous quality control of the printing process is also required, i.e. comprehensive process monitoring. At BAM, a test rig will be installed, enabling the printing of concrete structures with a maximum size of 2 m x 1 m x 1 m (l x w x h). Here, process monitoring is the focus of the test rig. In this study, we show the results of the first pump tests, including the measurement of several parameters such as temperature and pressure along the supply system, i.e. from the concrete pump to the printer head.
Introduction of a monitoring system for Bingham fluids in additive manufacturing with concrete
(2022)
Freeform additive manufacturing of concrete structures is a rising technology in civil engineering with several fascinating advantages. Nonetheless, to ensure reliability and structural integrity, standards and quality control are required in the future to bring this technology into the market. As the concrete is manufactured continuously, continuous quality control of the printing process is also required, i.e. comprehensive process monitoring. At BAM, a test rig will be installed, enabling the printing of concrete structures with a maximum size of 2 m x 1 m x 1 m (l x w x h). Here, process monitoring is the focus of the test rig. In this study, we show the results of the first pump tests, including the measurement of several parameters such as temperature and pressure along the supply system, i.e. from the concrete pump to the printer head.
The oxidation of sulfur in aqueous solutions is an important process in several geochemical and industrial contexts. In concrete technology, it is particularly relevant for the protection of steel reinforcement in slag cement-based concretes, as the presence of sulfides affects the passivation of the steel and corrosion initiation in the presence of chlorides. However, the knowledge about the kinetics of sulfide oxidation in alkaline solutions, such as concrete pore solutions, is incomplete. To address this issue, we prepared solutions with 0.80 M NaOH, and nominally 10, 100 and 350 mM HS−, respectively, and followed the evolution of the sulfur species during bubbling with oxygen-containing gas (concentration 100% or 22%) using X-ray absorption near-edge structure (XANES) spectroscopy at the sulfur K-edge. Polysulfide, thiosulfate, sulfite and sulfate were identified and quantified via linear combination fitting of the spectra, using previously measured standards. A preliminary analysis of the results shows that the initial rate constant of sulfide oxidation depends strongly on the HS− concentration, while it less strongly depending on the oxygen concentration, in line with previous results for lower pH values. Approaches to fit the data to obtain the rate constants of all relevant reactions will be discussed.
Ein zentrales Fundament moderner Gesellschaften ist eine intakte Abwasserinfrastruktur. Schäden infolge biogener Schwefelsäurekorrosion von konventionellen Betonen haben jedoch zu einem erheblichen Sanierungsbedarf geführt. Alkaliaktivierte Mörtel besitzen aufgrund eines hohen Säurewiderstands das Potential, einen Beitrag zur langfristigen Lösung dieses Problems zu leisten. Dazu müssen jedoch zunächst die Faktoren, die den Haftverbund zwischen diesen Mörteln und dem Betonsubstrat bestimmen, besser verstanden werden, um die Eigenschaften der Beschichtungssysteme gezielt anpassen und verbessern zu können. Die vorliegende Arbeit liefert hierzu einen Beitrag und zeigt dadurch Wege zu einer technisch machbaren und nachhaltigen Sanierung von Abwasserbauwerken auf.
The current paper develops a novel accelerated corrosion test method based on Faraday’s law to investigate the performance of different inhibitors in reinforced concrete elements under electrical voltage. Using the proposed method two commercially available and three lab-made inhibitors were tested. Lab-made inhibitors based on potassium fluorosilicate and amine carboxylate showed the best performance over others. Furthermore, it is found that under an electrical potential environment beyond 3.6 V, the higher the concrete strength, the more efficient is the corrosion inhibition. Based on experimental results, a novel model describing the corrosion evolution in reinforced concrete was proposed.
The retardation mechanism of cement hydration as imparted by the addition of polyphosphate comb superplasticizer to model cement containing C3S, C3A and calcium sulfate hemihydrate is studied using XRD, ss NMR and calorimetry. Our findings show the retardation effect caused by the direct addition of polyphosphate comb superplasticizer differs significantly to that of conventional polycarboxylate superplasticizers. Conversely to polycarboxylates, polyphosphates, at a low dosage, inhibits the silicate reaction without affecting the aluminate reaction and formation of ettringite. Yet, at high doses, both reactions are hampered, and the induction period extended, followed by accelerated aluminate and silicate reactions.
Hydrous lithium aluminosilicate (L–A–S–H) and lithium aluminate (L–A–H) gels are candidate precursors for glass-ceramics and ceramics with potential advantages over conventional processing routes. However, their structure before calcination remained largely unknown, despite the importance of precursor structure on the properties of the resulting materials. In the present study, it is demonstrated that L–A–S–H and L–A–H gels with Li/Al ≤ 1 can be produced via an organic steric entrapment route, while higher Li/Al ratios lead to crystallization of gibbsite or nordstrandite. The composition and the structure of the gels was studied by thermogravimetric analysis, X-ray diffraction, 27Al and 29Si magic-angle spinning nuclear magnetic resonance, and Raman spectroscopy. Aluminium was found to be almost exclusively in six-fold coordination in both the L–A–H and the L–A–S–H gels. Silicon in the L–A–S–H gels was mainly in Q4 sites and to a lesser extent in Q3 sites (four-fold coordination with no Si–O–Al bonds). The results thus indicate that silica-rich and aluminium-rich domains formed in these gels.
With increasing focus on industrialized processing, investigating, understanding, and modelling the structural build-up of cementitious materials becomes more important. The structural build-up governs the key property of fresh printable materials -- buildability -- and it influences the mechanical properties after the deposition. The structural build-up rate can be adjusted by optimization of the mixture composition and the use of concrete admixtures. Additionally, it is known, that the environmental conditions, i.e. humidity and temperature have a significant impact on the kinetic of cement hydration and the resulting hardened properties, such as shrinkage, cracking resistance etc. In this study, small amplitude oscillatory shear (SAOS) tests are applied to examine the structural build-up rate of cement paste subject to different temperatures under controlled humidity. The results indicate significant influences of the ambient temperature on the intensity of the re-flocculation (Rthix) rate, while the structuration rate (Athix) is almost not affected. A bi-linear thixotropy model extended by temperature dependent parameters coupled with a linear viscoelastic material model is proposed to simulate the mechanical behaviour considering the structural build-up during the SAOS test.
With increasing focus on industrialized processing, investigating, understanding, and modelling the structural build-up of cementitious materials becomes more important. The structural build-up governs the key property of fresh printable materials -- buildability -- and it influences the mechanical properties after the deposition. The structural build-up rate can be adjusted by optimization of the mixture composition and the use of concrete admixtures. Additionally, it is known, that the environmental conditions, i.e. humidity and temperature have a significant impact on the kinetic of cement hydration and the resulting hardened properties, such as shrinkage, cracking resistance etc. In this study, small amplitude oscillatory shear (SAOS) tests are applied to examine the structural build-up rate of cement paste subject to different temperatures under controlled humidity. The results indicate significant influences of the ambient temperature on the intensity of the re-flocculation (Rthix) rate, while the structuration rate (Athix) is almost not affected. A bi-linear thixotropy model extended by temperature dependent parameters coupled with a linear viscoelastic material model is proposed to simulate the mechanical behaviour considering the structural build-up during the SAOS test
Synopsis: Lately, there has been rising attention to superplasticizers (SP) based on polyphosphate esters. However, the influence of the molecular structure of the polyphosphate polymers on time-dependent properties such as structural build-up has not been examined yet intensively. To investigate this effect, three comb polyphosphate superplasticizers with different charge densities were synthesised by free radical polymerisation. Our findings indicate that SP with the lowest and medium charge densities extend the induction period more strongly than the SP with the highest charge density. The reduction of the structural build-up rate is linearly dependent on the dosage and concentration of the functional group of polyphosphate SP in the cementitious system. This study proposes a mathematical equation expressing the relationship between the structural build-up rate during the induction period and the molecular structure of the polyphosphate SP.
Hybrid cements are composites made of Portland cement or Portland clinker and one or more supplementary cementitious materials like slag, fly ash or metakaolin, activated with an alkali salt. To date, their hydration mechanism and the phase formation at various temperatures is insufficiently understood, partly due to the large variability of the raw materials used. In the present study, three hybrid cements based on ground granulated blast furnace slag, fly ash, Portland clinker and sodium sulfate, and an alkali-activated slag/fly ash blend were cured at 10 and 21.5°C, and subsequently analyzed by XRD, 27Al MAS NMR, and TGA. The compressive strength of the hybrid cements was higher by up to 27% after 91-day curing at 10°C, compared to curing at 21.5°C. The experimental results as well as thermodynamic modeling indicate that the differences in compressive strength were related to a different phase assemblage, mainly differing amounts of strätlingite and C-N-A-S-H, and the associated differences of the volume of hydration products. While the strätlingite was amorphous to X-rays, it could be identified by 27Al MAS NMR spectroscopy, TGA and thermodynamic modeling. The microstructural properties of the hybrid cements and the alkali-activated slag/fly ash blend as well as the compatibility between thermodynamic modeling results and experimental data as a function of curing temperature and time are discussed.
Synopsis: The paper presents the results of a study on the influence of agitation on the structural build-up of fresh cement pastes using a penetration test. It first presents results about the influence of the penetrating shape’s geometry on the influence on the cement paste specimen. Then, results are shown for the load-deflection curves depending upon time and agitation before testing. Based on the observation of the force required to penetrate the sample, conclusions on the structural build-up can be made. The observations were made over the course of time with samples that were left at rest and partly agitated before testing at different time steps. The setup allows to identify the contribution of the chemical reaction to the structural build-up process. The presence of superplasticizer obviously reduces the load that cement paste can withstand, while the loss of thixotropy is found notably lower than that of neat cement pates
Viscosity modifying agents: Key components of advanced cement-based materials with adapted rheology
(2022)
Viscosity modifying agents (VMAs) are essential ingredients for the production of flowable cement-based materials. This paper presents an overview of commonly used VMAs and attempts to shed some light on the underlying physics at the origin of their mechanisms of action. The main molecular parameters of VMA controlling the rheological properties of the cement pore solution are highlighted. As the mechanisms of action of VMAs in cement-based materials are closely related to their affinity with the surface of cement particles, the adsorption of the main VMA types is discussed. The effect of VMAs on flow properties and stability of cement-based materials is presented for VMAs added without any superplasticizer, and then in systems incorporating both VMAs and superplasticizers. Finally, the effect of VMAs in enhancing concrete properties to secure adequate performance of different construction applications, and perspectives for future developments of novel cement-based materials made with VMAs are showcased.