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A novel deign of test equipment has been commissioned to investigate thermal stratification and boiling during fire exposure of pressure vessels. Extensive temperature measurements and video of the internal conditions during fire exposure are possible, and the equipment has been designed for future compatibility with laser-based velocity measurement techniques. It is expected to generate data large quantities of data that will be of use in validation of two- and three-dimensional CFD models for the prediction of pressure vessel behaviour in fire. Future work will seek to characterize the boundary layer conditions in detail for a range of test fluids, fill levels and fire-induced thermal boundary conditions.
Initial tests undertaken during commissioning may indicate that fire exposure of the vessel wall just above the liquid level can have a notable influence on the pressurization rate, by increasing the degree of superheat. Further experimental and modelling work is required to confirm and quantify this effect, or to rebut this conclusion.
The vessel wall response shows a good agreement between the numerical predictions of and experimental data using the limit load approach. Further work is continuing to understand the thermohydraulic response and the boundary conditions for material modelling. As shown in figure 2 there was one BLEVE of a bare tank containing a PRV, highlighting the risk of serious consequences if models are inaccurate. The behavior of partly coated tanks were similar to the bare tank.
The results are based on data1. Figure 3 displays temperatures of the tank wall and of the gas phase over testing time. It can be seen that a complete coating strongly delayed the heating of tank wall and gas phase, whereas the partly coated tanks only had a minor influence on temperature development. There was no significant difference between a half coated and a thirdly coated tank measurable. Figure 4 shows the internal pressure of tanks over testing time. Only the fully coated tank enabled a low pressure over 90 min testing time. Hence, a complete coating is necessary to guarantee the fire safety of hazmat tanks and a partly coating is not sufficient.
It was possible to achieve an error as 9% or even 0% at certain time steps, as shown in the graph above, the usage of UDF code has major importance in achieving the pressure Profile required, and it heat transfer between the bottle itself and the surroundings was taken into consideration which of course had a high influence on how the temperature of the air flask changes.
A simplified model, based upon physical principles, is proposed the simulate the effect of sloshing on the pressure developed in the tanker chambers. The model has been validated in good extent, with experimental data from full scale testing. The characteristic that mostly affects the pressure developed with the chambers of the tanker is the length of the chamber. While a reduction in this property could decrease the pressure developed within a given chamber, the analysis should take into account an overall approach, as a shortening of the individual chambers would influence the number of chambers necessary to carry a certain amount of product. Consequently, the resulting model could be used to study different effects of the sloshing cargo on the carrying vehicles, including the length and position of the chambers along the tanker body.
A dynamic simulation model for a tanker ship along the Rhine River has been proposed, based on a simplified computational scheme, involving a two-degree-of-freedom roll plane multibody system, subjected to lateral accelerations estimated on the basis of measured data. The resulting equations of motion are solved through the transition matrix approach. The results suggest that many contributing factors were involved in the capsizing of the ship, including the relatively high speed of the river water and the meandering path of the infrastructure, further affected by dynamic effects derived from the behavior of the payload and from the steering maneuvers performed.