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- Emission (2)
- Emission test chamber (2)
- Volatile organic compounds (2)
- 3D printer (1)
- AgBB scheme (1)
- CO2 assisted impregnation (1)
- Emissions testing (1)
- Emitting reference material (1)
- FEM model (1)
- Glasmalerei (1)
Organisationseinheit der BAM
There has been an increasing use of oriented strand boards (OSBs) for the construction of floors, ceilings and walls of buildings. In Germany and other European countries, OSBs are mainly produced from pine wood (Pinus sylvestris). In response to complaints about the odour and irritation of mucous membranes in connection with the use of OSBs, samples of OSBs were bought from do-it-yourself stores to test their volatile organic compound (VOC) emissions by using emission test chambers. The boards emitted predominantly monoterpenes, aldehydes, acids and acetone. Aldehydes are generated during the production process by the oxidation of unsaturated fatty acids such as linoleic acid. Pine wood, compared with other wood species, contains more unsaturated fatty acids. Of the six acquired OSBs, four boards from three manufacturers would not meet the requirements of the German AgBB (Ausschuss zur gesundheitlichen Bewertung von Bauprodukten, Committee for Health Evaluation of Building Products), mainly because of the emissions of unsaturated aldehydes. These compounds have low LCI values (lowest concentration of interest) and are therefore problematic substances based on a health-related evaluation of building products according to the AgBB scheme.
3D-printing or additive manufacturing has many promising and unique advantages. Especially low cost molten polymer Deposition Printers are increasingly populär in the private and educational sector.
Their environmental friendliness can be questioned due to recently reported ultrafine particle and suspected VOC emissions, To further investigate 3D-printing as a potential indoor air pollution source we characterized fine and ultrafine particle emissions from a molten polymer deposition printer producing a 3D object with ten marketable polymer filament materials under controlled conditions in a test chamber. VOC emissions from the filaments have also been compared. Using a straightforward emission model time dependent and averaged particle emission rates were determined. The results indicate that under comparable conditions some filament materials produce mainly ultrafine particles up to an average rate of 1013 per minute. This value is in the upper ränge of typical indoor ultrafine particle sources (e.g. Smoking, frying, candle light, laser printer). The observed material-specific rates differ by five Orders of magnitude. Filament-specific gaseous emissions of organic compounds such as bisphenol A, styrene and others were also detected.
Our results suggest a detailed evaluation of related risks and considering protective measures such as housing and filtering.
Vor dem Hintergrund der notwendigen Revision der Kriterien zur Vergabe des Gütezeichens "Blauer Engel" für Laserdrucker, Kopierer und Multifunktionsgeräte mussten auch die Prüfmethoden angepasst werden, da die alten Verfahren nicht mehr die heutigen Anforderungen der Emissionsmessung erfüllen. In diesem Zusammenhang wurde auch das unterschiedliche Emissionsverhalten von Hardcopy-Geräten auf Grund der verschiedenen und nicht miteinander vergleichbaren Prüfverfahren heftig diskutiert. Aus diesen Gründen wurde ein neues Prüfverfahren entwickelt, mit dem eine verlässliche und reproduzierbare Prüfung der Emissionsraten von Staub, Ozon und flüchtiger organischer Verbindungen auf der Basis des ECMA (European Computer Manufacturer Association) Standards 328 möglich ist. Dazu wurden neun verschiedene Geräte unter verschiedenen Bedingungen untersucht. Als ein Ergebnis dieser Studie wurden neue Kriterien zur Vergabe des "Blauen Engels" für Kopierer, Drucker und Multifunktionsgeräte festgelegt.
Historische Glasmalereien können durch anorganische und organische Luftverunreinigungen geschädigt werden. Chemische Reaktionen der empfindlichen Materialien eines Glasgemäldes (Glas, Malschicht, Blei) mit Luftfeuchtigkeit und den Schadstoffen der Umgebung führen zu Veränderungen der oberflächennahen Schichten des Glases, der Malschichten und schädigen die Bleie. Die Wirkung von Luftschadstoffen, die aus Industrieabgasen und Feuchtigkeit bestehen und als saurer Regen auf die Verglasung von Kirchen und Kathedralen einwirken ist weitgehend bekannt. Emissionen aus Materialien, die zur Verpackung, zum Transport und zur Lagerung von Kunstgegenständen aus Glas eingesetzt werden, können auch Schäden auf den empfindlichen Materialien verursachen. Als flüchtige organische Bestandteile (Volatile Organic Compounds VOC) wurden neben anderen auch organische Säuren analysiert. Das Schädigungspotenzial von Essigsäure, Propansäure, Hexansäure und Oktansäure wurde an Modellproben unter zeitraffenden Bedingungen im Klimaschrank untersucht. Nach einer Versuchsdauer von 12 Wochen waren die Oberflächen der empfindlichsten Modellproben bereits deutlich geschädigt. Hieraus ergibt sich die Schlussfolgerung, dass Materialien mit hohen Emissionsraten an organischen Säuren auch an mittelalterlichen Gläsern unter ungünstigen Bedingungen (geringe Luftwechsel in Depoträumen) Schäden verursachen können.
Volatile Organic Compounds (VOC) are ubiquitous in the indoor air since they are emitted from materials used indoors. Investigations of these materials are mostly carried out in emission test chambers under controlled climatic conditions. Reference materials are an important tool for quality assurance/Quality control of emission test chamber measurements but so far they are not commercially available. In this study, a new approach was tested to develop an appropriate reference material with homogenous and reproducible emission of the VOC with well measurable air concentrations in emission test Chambers larger than 20 L at air change rates of 0.5 - 1 /h.
Thermoplastic Polyurethane (TPU) was selected as Matrix material which was impregnated with 2,2,4- trimethyl-1,3-pentanediol monoisobutyrate (texanol) as test VOC using compressed carbon dioxide. An optimization of the impregnation parameters such as temperature, pressure, time, VOC injection volume and TPU sample size was performed until the targeted area specific Emission rate (SERa) value was reached. Further aspects like process control, storage effects and correlation of the sample size to the emission rate were investigated. It was found that the SERa immediately after sample preparation were not reproducible between the batches but became unified 10 days after loading into the test chamber indicating the necessity of aging before use. SERa between 13,000 and 18,000 mg m-2 h-1 were obtained, and the impregnated materials could be well stored in aluminum-coated polyethylene foil for at least seven weeks without significant losses. Furthermore, the impregnation of styrene and the SVOC 2,6-diisopropylnaphthalene was tested.
Recent research into emissions of (semi-)volatile organic compounds [(S)VOC] from solid materials has focused on the development of suitable reference materials for quality assurance/quality control of emission test chamber measurements, which fulfill requirements such as homogenous and reproducible (S)VOC release. The approach of this study was to find a method for preparation of a material with predictable (S)VOC emission rates. AVOC (styrene) and an SVOC (2,6-diisopropylnaphthalene, DIPN), loaded into either vacuum grease or a 1:1 mixture of paraffin/squalane, have been tested. For the prediction of the emission rates, a model using the finite element method (FEM) was created to simulate the (S)VOC emission profiles. Theoretical and experimental results obtained in a Micro-Chamber/Thermal Extractor (μ-CTE™) and in 24 L emission test chamber measurements were in good agreement. Further properties were investigated concerning the material applicability, such as shelf life and inter-laboratory comparability. The maximum relative standard deviation in the inter-laboratory study was found to be 20%.