Filtern
Erscheinungsjahr
- 2014 (7) (entfernen)
Dokumenttyp
Sprache
- Englisch (7) (entfernen)
Referierte Publikation
- ja (7)
Schlagworte
- Mechanical properties (7) (entfernen)
The challenge of how to adequately characterize the toughness behavior of ductile cast iron (DCI) materials had been solved through the development and application of fracture mechanics concepts. Outstanding examples are found in the design and safety assessment procedures of sophisticated DCI components for wind turbines or transport and storage casks for radioactive materials. An essential requirement for these procedures is to have adequate fracture mechanics toughness data available.
Because DCI materials may substantially change their deformation, damage and fracture behavior from ductile to brittle by increasing loading rate, decreasing temperature, increasing pearlite share and increasing stress triaxiality, the corresponding experimental measuring techniques and analysis concepts have to be chosen and adapted with deliberation. Long-time experience in this field is imperative to provide valuable data.
BAM has been dealing with mechanical and fracture mechanical characterization of DCI materials for more than 30 years. This paper demonstrates state-of-the-art fracture mechanics test methods for the determination of quasi-static and dynamic fracture toughness. Among others, it is exemplarily shown for a variety of DCI materials conforming to grade EN-GJS-400 how mechanical and fracture mechanical properties are influenced by temperature, loading rate and microstructure. A major lesson to be learned is that fracture toughness data of DCI should always be discussed, reported and used in correlation with microstructural parameters.
We review contact mechanics with emphasis on the rheological (time dependent) properties of polymers and their relations to surface roughness, material properties, and friction as well as wear behavior of rubbing polymer surfaces. The main concept of polymer mechanics related to tribology consists of three basic elements involved in friction: deformation resulting in the real area of contact of rough surfaces, contact adhesion, and shear and rupture of materials in the contact during the sliding friction. The results of classical work are included, which addresses the real contact area calculation and the description of adhesion interaction between rough surfaces. A brief review of experimental investigations concerning the surface characterization by means of bearing curves, the intermolecular force interaction using the adhesion parameter, the effect of temperature on the real contact area, the formation of transferred polymer film during friction, and tribological behavior of ultrathin polymer layers are presented and their implications discussed.
Thin polybutadiene/polystyrene blend films were deposited on glass substrates by spin-coating. The two polymers were chosen, as they are immiscible and differ strongly in their mechanical properties. The blend was characterized with Tapping Mode and force–distance curves. Several advantages of force–distance curves measurements compared to Tapping Mode are shown, most of all the capability of yielding quantitative information about several properties, such as Young's modulus and adhesion. Also the aging behaviour of the blend exposed to air could be observed, in particular the increase of the Young's modulus due to cross-linking and dewetting processes. Additionally, the sample was used to improve the resolution of force–distance curves up to 6 nm, which is to date the best resolution achieved with force–distance curves. Such an improvement resolves the major disadvantage of force–distance curves, compared to other scanning mode, i.e. its inferior resolution.
Design and safety assessment of advanced ductile cast iron (DCI) components like wind turbines or transport and storage casks for radioactive materials require appropriate material data in terms of strength and fracture toughness. Therefore, it is of vital importance to characterize and understand the deformation, damage and fracture behaviour of DCI which may substantially change from ductile to brittle by increasing loading rate, decreasing temperature and/or increasing stress triaxiality. This paper reports on recent BAM inverstigations on different qualities of the widely used DCI grade EN-GJS-400 with varying pearlite shares (none and 18% respectively). The focus was on the influences of microstructure, temperature (ambient and -40 °C) and loading rate (quasi-static to crash) on strength (YS, UTS, flow curve) and fracture mechanical properties (R-curve, crack initiation toughness, fracture toughness). Systematic metallographical and fractographical analyses were performed accompanying the whole test program and a systematics of specific damage behaviour and fracture mechanisms was derived from the results.
Structural electrolytes were prepared using a fully formulated commercially available high performance epoxy resin (MTM57) and an ionic liquid based electrolyte: lithium bis(trifluoromethylsulfonyl)imide (LiTFSI) dissolved in 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMIM-TFSI). Through a systematic study, the composition of the formulations was found to have a greater effect than the curing temperature on the morphology and properties of the resulting structural electrolytes. The presence of lithium salt is essential to form a structurally homogeneous electrolyte. Bicontinuous morphologies containing continuous (coarse) epoxy networks surrounded by connected spherical epoxy nodules were obtained with different length scales upon varying the lithium salt concentration. Increasing the LiTFSI concentration improved the miscibility of MTM57 with the electrolyte and decreased the characteristic length scale of the resulting bicontinuous microstructure. The properties of the structural electrolytes correlated with the morphology, showing increased Youngs modulus and decreased ionic conductivity with increasing lithium salt concentration. The miscibility of the epoxy system with the electrolyte was also improved by substitution of EMIM-TFSI with an equal weight of an aprotic organic solvent, propylene carbonate (PC); however, the window of PC concentrations which resulted in structural electrolytes with bicontinuous microstructures was very narrow; at PC concentrations above 1 wt %, gel-like polymers with no permanent mesoporosity were obtained.
Multifunctional composites which can fulfil more than one role within a system have attracted considerable interest. This work focusses on structural supercapacitors which simultaneously carry mechanical load whilst storing/delivering electrical energy. Critical mechanical properties (in-plane shear and in-plane compression performance) of two monofunctional and four multifunctional materials were characterised, which gave an insight into the relationships between these properties, the microstructures and fracture processes. The reinforcements included baseline T300 fabric, which was then either grafted or sized with carbon nanotubes, whilst the baseline matrix was MTM57, which was blended with ionic liquid and lithium salt (two concentrations) to imbue multifunctionality. The resulting composites exhibited a high degree of matrix heterogeneity, with the ionic liquid phase preferentially forming at the fibres, resulting in poor matrix-dominated properties. However, fibre-dominated properties were not depressed. Thus, it was demonstrated that these materials can now offer weight savings over conventional monofunctional systems when under modest loading.
The continuing increase of steam parameters of fossil fuelled high efficiency power plants and new combustion concepts for the capture and storage of carbon dioxide lead to harsher service conditions for the components and structural materials of such facilities. The present work introduces a test concept that allows testing of candidate materials under simultaneous mechanical and corrosive loading. The material's reaction can be directly investigated under simulated temperature, load and corrosion conditions of modern installations. First results obtained for different heat resistant steels suggest a strong influence of the environmental medium on the fatigue and creep behaviour. Such findings complement the data that is available from the classical qualification process of the materials and may support the material selection for new power plant installations.