Filtern
Erscheinungsjahr
- 2023 (2) (entfernen)
Dokumenttyp
- Vortrag (1)
- Forschungsdatensatz (1)
Sprache
- Englisch (2)
Referierte Publikation
- nein (2)
Schlagworte
- Antimony (2) (entfernen)
Organisationseinheit der BAM
Eingeladener Vortrag
- nein (1)
Avoiding antimony – effect of Ca(H2PO2)2 on smoke emission and fire behaviour in brominated ABS
(2023)
The replacement of antimony trioxide (Sb2O3) in brominated flame-retardant ABS (ABS/FR) is of great interest. This study investigates the influence of calcium hypophosphite (CaP) in ABS/FR on flame retardancy and smoke emission. Different amounts of talc are added to ABS/FR/CaP to evaluate the influence of an inorganic barrier on smoke emission and flame retardancy. The cone calorimeter unveiled a reduction by 46% in PHRR for ABS/FR/CaP. Additional 8 wt.-% talc (ABS/FR/CaP/8Talc) reduced the PHRR by 61%. ABS/FR/CaP exhibited a more condensed phase action, which resulted in less smoke emission. The study investigates the influence of CaP in ABS/FR on the smoke toxicity, smoke density and the smoke particles distribution in the smoke density chamber (ISO 5659-2) coupled to a FTIR spectrometer and electrical low pressure cascade impactor (ELPI).
The chemical state of antimony and vanadium species in municipal solid waste incineration bottom ash
(2023)
Due to the large quantity as residual mineral waste, municipal solid waste incineration - bottom ash (MSWI-BA) is an interesting secondary raw material that can be utilized for road construction. However, leaching of chloride, sulfate and potentially hazardous heavy metals from MSWSI-BA into the environment may cause problems in utilization of it in civil engineering. In a previous study, we performed a long-term leaching test of MSWI-BA in a lysimeter for almost six years to investigate the efficiency of the treatment process on the release of hazardous substances. While concentrations of chloride, sulfate and the majority of the heavy metals started to decrease rapidly with progressive liquid-to-solid ratio (L/S), the ecotoxic hazardous elements antimony (Sb) and vanadium (V) behaved differently. To unravel these unusual release behaviors and the oxyanion-formation of Sb and V we will apply HERFD-XANES spectroscopy to analyze their chemical state.