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An overview of test standards and regulations relevant to the fire testing of pressure vessels
(2021)
Fire exposure of storage and transportation vessels of hazardous materials (including pressure liquefied gases) can result in BLEVEs and other high-consequence incidents with large societal and economic impacts. To reduce risk most countries have numerous regulations, codes of practice and guidance notes covering the design, operation and maintenance of vessels and thermal protection systems. Yet despite such regulations there remains no internationally accepted fire test procedure for pressure vessel and accompanying thermal protection systems that is capable of meeting a range of regulatory requirements. This paper considers some of the regulations in place in the western world and considers the origin of these based on large and medium-scale testing conducted to date. It examines conditions found in these tests to propose a set of recommendations on which to base a standard method of test. These recommendations are proposed as being representative of a credible large pool fire scenario that may occur.
In 1976, a pressure vessel of a tank wagon burst during gravity shunting. The pressure vessel was filled with cold fluid carbon dioxide and failed by cleavage fracture explosively. Big parts of the vessel were flung up to 300 m, a building was destroyed, and rails as well as the superstructure of the gravity shunting yard were damaged.
The initiation sites of the fracture and the orientations of crack propagation were determined by means of the patterns on the fracture surfaces of the broken parts. The initiation sites were located in the heat-affected zone (HAZ) of welds, close to transitions of cross-sections and the starting and end points, respectively, of the welds. The primary initiation of crack propagation was almost certainly on the left side, close to the weld of the fixed bearing connecting the vessel with the carriage.
The results of metallographic investigations indicated the development of cold weld cracks during welding. Mechanical behavior assessments on specimens extracted from the failed vessel indicated sufficient strength and ductility in tensile loading. The values of the notched-bar impact energy or toughness were within the limits according to industry rules and standards, except for one metal sheet of the vessel that was welded to the left fixed bearing.
During shunting, two tank wagons were inappropriately braked, and began to roll too quickly. One rail brake used for deceleration of the wagons caused impulsive noises and vibrations, resulting in high impulsive loading of the first wagon. The cold weld cracks in the heat-affected zones near the fixed bearing of the pressure vessel were initiation points for unstable crack growth. As the result of very low notched-bar impact toughness, crack propagation was not arrested and unstable cleavage fracture occurred.
Due to a second similar accident, happened one year before, a program was started to assess characteristic values of pressure vessel materials and the influence of weld parameters by the manufacturer, the inspecting authority, and BAM. The scientific findings led to modifications of industry rules and standards with regard to using ISO-V specimens and to higher required values for notched-bar impact energy for fine grain structural steels.
Die Vorhersage der Beanspruchung bei plastischem Versagen von zylindrischen Druckbehältern wird häufig mittels Finite Elemente Berechnungen durchgeführt. Die Berechnung der zulässigen Beanspruchung erfordert ein elastisch-plastisches Werkstoffmodell und die Berücksichtigung von nichtlinearen geometrischen Effekten. Das plastische Versagen verursacht eine gesamte Strukturinstabilität und kann nicht direkt aus der Finite Elemente Analyse bestimmt werden. In dem vorliegenden Beitrag wird die Beanspruchung für plastisches Versagen eines zylindrischen Druckbehälters mittels eines analytischen Verfahrens basierend auf einem linear elastischen ideal-plastischen Materialmodell bestimmt. Wenn Plastizität auftritt, wird zum einen der Werkstoff als inkompressibel und zum anderen der Tensor der plastischen Dehnungen als parallel zum Spannungsabweichungstensor angenommen. In diesem Fall kann die Spannungs-Dehnungs-Beziehung von Henkel angewendet werden, um den Druck zu berechnen, bei dem plastisches Fließen und Versagen eintritt. Die analytischen Ergebnisse werden von den Finite Elemente Berechnungen vollkommen bestätigt.
At Juelich Research Center the prototype of an alkaline 120-bar electrolyser has been developed and built. Constructive and process-engineering measures must be taken to ensure the safe operation of such facilities. Potential hazards occur due to the high operating pressure in conjunction with the reactivity of the product gases and the electrolyte. First of all, the operating mode and technical features of the Juelich high-pressure electrolyser will be dealt with. Within the framework of a parametric study, the potential for weight reduction of the prototype while observing the rules for pressure vessel design will be shown. The Federal Institute for Materials Research and Testing in Berlin has performed measurements concerning the explosion limits of H2/O2 mixtures at different temperatures and pressures up to 200 bars. At an electrolysis test rig of IWV-3, which can also be operated up to 200 bars, investigations were carried out concerning the gas composition on the H2 and O2 path under different operating conditions. These measurement series were compared to the explosion limits determined and evaluated to derive safety measures required for the operation of high-pressure electrolysers.