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Milling reactions often result in 100% yields of single products, making purifying procedures obsolete. Mech-anochemistry is also a sustainable and eco-friendly method. The ever increasing interest in this method is contrasted by a lack in mechanistic understanding of the mechanochemical reactivity and selectivity. Recent in situ investigations provided direct insight into formation pathways. However, the currently available theories do not predict temperature T as an influential factor. Here, we report the first determination of an activation energy for a mechanochemical reaction. In a temperature-dependent in situ study the cocrystallisation of ibuprofen and nicotinamide was investigated as a model system. These experiments provide a pivotal step towards a comprehensive understanding of milling reaction mechanisms.
Right from the beginning of applying SHM to bridge structures it was obvious that environmental based perturbations on the measurement significantly influence the ability to identify structural damage.
Strategies are needed to classify such effects and consider them appropriately in SHM. Various methods have been developed and analyzed to separate environmental based effects from damage induced changes in the measures. Generally, two main approaches have emerged from research activity in this fields: (a) statistics based tools analyzing patterns in the data or in computed parameters and (b) methods, utilizing the structural model of the bridge taking into account environmental as well as damage based changes of stiffness values.
With the back-ground of increasing affordability of sensing and computing technology, effort should be made to increase sensitivity, reliability and robustness of procedures, separating environmental from damage caused changes in SHM measures. The contribution describes both general strategies and points out their Advantages and drawbacks. As basis, a review on relevant methods was conducted. The aim of the study is to classify approaches for separating damage describing information from environmental based perturbations in dependency of the SHM objective. And such, it is intended to describe a best practice in designing concepts for Monitoring infrastructure, naturally effected by environmental influences.
We present the synthesis and characterization of a family of regioisomerically pure pH-sensitive rosamine fluorophores consisting of xanthene fluorophore cores, which determine the dyes’ photophysical properties such as excitation/emission wavelength, fluorescence quantum yield, and fluorescence lifetime, and differently substituted phenol moieties. The hydroxyl substituent of the phenol moiety introduces a pH sensitivity of the dyes’ fluorescence exploiting a photoinduced electron transfer (PET), that leads to a protonation-induced switching ON of the rosamine emission. Rational tuning of the pKa value of the rosamine fluorescence between 4 to 9 is achieved by altering the substitution pattern and degree of bromination of the phenolic subunits. Additionally, a temperature sensitivity of the fluorescence quantum yield is introduced or suppressed based upon the degree of rigidity of the xanthene scaffold.