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The electronic structure of gas-phase H2O and D2O molecules has been investigated using resonant
inelastic soft x-ray scattering (RIXS). We observe spectator shifts for all valence orbitals when
exciting into the lowest three absorption resonances. Strong changes of the relative valence orbital
emission intensities are found when exciting into the different absorption resonances, which can be
related to the angular anisotropy of the RIXS process. Furthermore, excitation into the 4a1 resonance
leads to nuclear dynamics on the time scale of the RIXS process; we find evidence for vibrational
coupling and molecular dissociation in both, the spectator and the participant emission.
The surface properties of CuInS 2 (CIS) thin-fi lm solar cell absorbers are
investigated by a combination of electron and soft X-ray spectroscopies.
Spatially separated regions of varying colors are observed and identifi ed to
be dominated by either CuS or Cu 2 S surface phases. After their removal by
KCN etching, the samples cannot be distinguished by eye and the CIS surface
is found to be Cu-defi cient in both regions. However, a signifi cantly more
pronounced off-stoichiometry in the region initially covered by Cu 2 S can be
identifi ed. In this region, the resulting surface band gap is also signifi cantly
larger than the E g Surf of the initially CuS-terminated region. Such variations
may represent a hidden parameter which, if overlooked, induces irreproducibility
and thus prevents systematic optimization efforts.
Rapid urbanisation and climate change-induced watershed hydrologic alteration have increased urban flooding risks. As a strategy for urban flood control, low impact development (LID) practices focus on promoting the infiltration and detention of stormwater runoff. A modelling-based study was conducted to analyse LID performance in urban flooding reduction. Two-dimensional simulations were conducted to visualise the flood risk under different precipitation scenarios and LID schemes. An integrated evaluation system based on life-cycle cost analysis, the analytic hierarchy process, and regret decision theory were applied to assess the LID performance in multiple aspects. The results indicated that the LID practices achieved runoff control and flood mitigation to some extent, especially under mild rainfall events. According to the integrated evaluation, urban flooding risk could be sufficiently reduced with the LID combination of bioretention, infiltration trenches, and rain barrels in the given area.