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Photovoltaics, a mature technology, is set to play a vital role in
achieving a carbon-free energy system. This article examines the
pivotal role of optics in advancing photovoltaics. We identify key
scientific research areas where the optics community can make
significant contributions. We are guided by the central question: How
can optics facilitate the large-scale deployment of photovoltaics
necessary for decarbonizing our societies?