TY - JOUR A1 - Hungenberg, Klaus-Dieter A1 - Schwede, Christian A1 - Wulkow, Michael A1 - Wulkow, Niklas T1 - Determination of reactivity ratios for acrylic acid and its dimer from classical parameter estimation and Bayesian approach JF - Canadian Journal of Chemical Engineering N2 - The reactivity ratios of acrylic acid (AA, M1) and its dimer beta-acroyloxypropionic acid (diAA, M2) are determined from cumulative copolymerization data by two different methods: classical parameter estimation (PE) by minimizing the objective function and a Bayesian analysis. Classical PE gives r1 =0.74 and r2 = 1.23 at the minimum of the residual. From the Bayesian analysis, the probability distribution of the parameter sets is obtained, revealing the existence of parameter sets with rather the same probability. The influence of the number of data and the size of the measurement error are discussed. Y1 - 2021 U6 - https://doi.org/https://doi.org/10.1002/cjce.24330 SP - 1 EP - 10 ER -