TY - CHAP A1 - Grytsenko, Kostyantyn A1 - Slominskii, Yu L. A1 - Tolmachev, O. I. A1 - Resel, R. A1 - Ksensov, S. A1 - Schrader, Sigurd T1 - Enigma of the second harmonic generation in oriented film of symmetric squaraine N2 - Second harmonic generation (SHG) in the oriented film of symmetric squaraine (Sq) was studied. Oriented Sq film on aligned polytetrafluoroethylyne (PTFE) sublayer prepared by vacuum deposition with subsequent rubbing using a cloth has been obtained. However, the mechanisms of orientation and SHG are still not clear. Methyl and ethyl substituted hydroxyl-Sq (OHSq) compounds formed oriented films with dichroic ratio of 8 on PTFE layer but with dichroic ratio of 1,5 on Teflon AF. Second layer deposition of Me-OHSq on Et-OHSq or of Et-OHSq on Me-OHSq led to an increase of the film dichroic ratio. Only the film, where Me-OHSq was first layer, exhibits an increase of SHG signal after deposition of second layer. Small differences in bi-layered OHSq films structure was detected by X-Ray diffraction (XRD) spectra. KW - dye KW - solid KW - film KW - squaraine KW - optical spectra KW - deposition KW - second harmonic generation Y1 - 2008 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:526-opus4-15183 SP - 324 EP - 331 PB - Society of Photo-Optical Instrumentation Engineers (SPIE) ER - TY - CHAP A1 - Grytsenko, Kostyantyn A1 - Doroshenko, T. A1 - Kolomzarov, Yurii A1 - Prokopets, Vadym M. A1 - Fedoriak, O. A1 - Zelinski, R. A1 - Lytvyn, Oksana A1 - Prescher, Dietrich A1 - Grimm, Bernd A1 - Ksianzou, Viachaslau A1 - Schrader, Sigurd A1 - Tolmachev, O. I. A1 - Slominskii, Yu L. A1 - Kurdiukov, V. A1 - Smirnova, G. T1 - Research on the growth of dye film in vacuum in situ N2 - Organic film deposition in vacuum is fast developing scientific and industrial domain. We developed installation for deposition of organic films equipped with optical spectrometer for measurements in situ. We are developing new dyes aimed for application in waveguide sensor, nonlinear optics and studying film organisation during deposition. Fluorinated azo-dyes and azomethine dyes were synthesized at University of Applied Sciences Wildau and at the Institute of Organic Chemistry, Kyiv. Compounds were evaporated at a pressure of 10-3 Pa using resistive heated crucible. Glass and glass covered with polytetrafluoroethylene (PTFE) film are used as substrates. The films were studied with Polytec and StellarNet spectrometers and an atomic force microscope. Optical spectra of the dye films revealed, that some compounds were decomposed during evaporation. Several kinds of dyes were evaporated and deposited without decomposition. Some deposited films formed H-aggregates and other types of aggregates. AFM images of dye films showed that their morphology depends on the chemical structure of the compounds and on the nature of the substrate on which the film was grown. KW - dye KW - solid KW - film KW - in situ KW - optical spectra KW - vacuum deposition Y1 - 2008 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:526-opus4-15206 SP - 318 EP - 323 PB - Society of Photo-Optical Instrumentation Engineers (SPIE) ER -