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  <doc>
    <id>2005</id>
    <completedYear>2013</completedYear>
    <publishedYear/>
    <thesisYearAccepted/>
    <language>eng</language>
    <pageFirst>2058</pageFirst>
    <pageLast>2065</pageLast>
    <pageNumber/>
    <edition/>
    <issue>12</issue>
    <volume>11</volume>
    <type>article</type>
    <publisherName>Versita</publisherName>
    <publisherPlace/>
    <creatingCorporation/>
    <contributingCorporation/>
    <belongsToBibliography>1</belongsToBibliography>
    <completedDate>--</completedDate>
    <publishedDate>--</publishedDate>
    <thesisDateAccepted>--</thesisDateAccepted>
    <title language="eng">Shape memory polyurethanes based on recycled polyvinyl butyral. I. Synthesis and morphology</title>
    <abstract language="eng">Shape memory polyurethanes (SMPUs) were synthesized by 4,4′-diphenylmethane diisocyanate (MDI), hexane-1,6-diol (HD), polypropylene glycol (PPG), and recycled polyvinyl butyral (PVB). Dynamic mechanical analysis, differential scanning calorimetry and Fourier transformation infrared attenuated total reflection spectroscopy was used to characterize the poly (vinylbutyral-urethanes). Micro-phase domain separation of hard and soft segments and phase inversion were investigated. Increasing the hard segment content, i.e., average hard segment molecular weight, leads to an increase in the degree of micro-phase separation, hard domain order and crystallinity. The crystalline hard segment structures combined with the elastic nature of soft segment matrix provide enough physical and chemical crosslinks to have shape memory effect.</abstract>
    <parentTitle language="eng">Central European Journal of Chemistry</parentTitle>
    <identifier type="urn">urn:nbn:de:kobv:526-opus4-20052</identifier>
    <enrichment key="opus.import.date">2025-02-20T06:27:24+00:00</enrichment>
    <enrichment key="opus.source">sword</enrichment>
    <enrichment key="opus.import.user">sword</enrichment>
    <enrichment key="opus.import.file">attachment; filename=deposit.zip</enrichment>
    <enrichment key="opus.import.checksum">3c75809f2623a11115fc1bafa8a8b5d4</enrichment>
    <enrichment key="DOI_VoR">https://doi.org/10.2478/s11532-013-0331-3</enrichment>
    <enrichment key="SourceTitle">Tsonev, T., Herzog, M., &amp; Nenkova, S. (2013). Shape memory polyurethanes based on recycled polyvinyl butyral. I. Synthesis and morphology. Central European Journal of Chemistry, 11(12), 2058–2065. doi:10.2478/s11532-013-0331-3</enrichment>
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    <licence>Creative Commons - CC BY-NC-ND 3.0 - Namensnennung - Nicht-kommerziell - Keine Bearbeitung 3.0 Unported</licence>
    <author>Tsvetomir Tsonev</author>
    <author>Michael Herzog</author>
    <author>Sanchi Nenkova</author>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>polyvinyl butyral</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>shape memory</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>polyurethane</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>thermal analysis</value>
    </subject>
    <subject>
      <language>eng</language>
      <type>uncontrolled</type>
      <value>IR spectroscopy</value>
    </subject>
    <collection role="ddc" number="620">Ingenieurwissenschaften und zugeordnete Tätigkeiten</collection>
    <collection role="ddc" number="668">Technik anderer organischer Produkte</collection>
    <collection role="institutes" number="">Fachbereich Ingenieurwesen / Wirtschaftsingenieurwesen (bis 8/2014)</collection>
    <collection role="open_access" number="">open_access</collection>
    <collection role="Import" number="import">Import</collection>
    <thesisPublisher>Technische Hochschule Wildau</thesisPublisher>
    <file>https://opus4.kobv.de/opus4-th-wildau/files/2005/10.2478_s11532-013-0331-3.pdf</file>
  </doc>
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