@article{DreyerMotocKoehleretal.2023, author = {Dreyer, Christian and Motoc, Dana Luca and Koehler, Mathias and Goldenberg, Leonid}, title = {UV LED Curable Perfluoropolyether (PFPE)-Urethane Methacrylate Transparent Coatings for Photonic Applications: Synthesis and Characterization}, series = {Polymers}, volume = {15}, journal = {Polymers}, number = {14}, publisher = {MDPI}, url = {http://nbn-resolving.de/urn:nbn:de:kobv:526-opus4-19139}, pages = {1}, year = {2023}, abstract = {The contribution aims to bring forth a novel synthesis route in developing transparent UV LED-curable coatings accounting for various exposure options. A selection of perfluoropolyether (PFPE)-urethane methacrylate and acrylate resins, free-radical photo-initiator Omnirad 2100, and two distinct silane-based crosslinking agents were blended under a weight ratio of 75:20:5 (without crosslinker) and 70:15:5:10, respectively. The coatings were cured under a UV LED 4 × 3 matrix light emitting source, in a chamber under a controlled atmosphere, by means of an in-house developed conveyor belt type platform, at different conveyor belt speeds (5, 50, 150, 250, and 500 mm/s). The morphologies of fabricated coatings were characterized by FTIR revealing high conversion rates (e.g., from 98 to 100\%) for increased exposure time as a result of the 5 or 50 mm/s values, on all combinations. Dynamic-mechanical and optical properties of UV LED-cured transparent coatings were also investigated. A negative shift of the glass transition temperature values with a decrease in exposure time, in all combinations, from about 60 °C to 30 °C, along with storage moduli lowering in the glassy plateau further favors higher exposure times for curing. The refractive indices of poly-mers were from 1.38 to 1.40, whereas the thermo-optic coefficients are showing minor changes around the value of 2.55∙10-4 K-1.}, language = {en} }