Refine
Document Type
Language
- English (2)
Has Fulltext
- no (2)
Is part of the Bibliography
- no (2)
Keywords
Institute
Emission properties of [Os(phen)2(dppene)]2+ were investigated from 1.4 to 300 K in ethanol, PMMA, and PVK, a matrix which is frequently applied in OLEDs. These data provide the zero-field splitting values of the emitting T1 state and the individual decay times of its substates. The T1 state is assigned to be largely of MLCT character. The splittings change only moderately due to variation of the matrix, whereas the individual decay times are substantially affected. Further, energy transfer from the triplet state of PVK to [Os(phen)2(dppene)]2+ was studied by applying time-resolved emission spectroscopy and is assigned to be dominantly of Dexter type.
Strong oxygen quenching following a Stern−Volmer behavior of Ir(ppy-NPh2)3 demonstrates the high technological potential for oxygen sensing applications. This compound exhibits a phosphorescence quantum yield of 70% and an emission decay time of 4.3 μs in deaerated solution. The electronic structure of the emitting triplet, being responsible for these properties, is investigated.