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Electronic spectra of organic molecules doped into superfluid helium nanodroplets show characteristic features induced by the helium environment. Besides a solvent induced shift of the electronic transition frequency, in many cases, a spectral fine structure can be resolved for electronic and vibronic transitions which goes beyond the expected feature of a zero phonon line accompanied by a phonon wing as known from matrix isolation spectroscopy. The spectral shape of the zero phonon line and the helium induced phonon wing depends strongly on the dopant species. Phonon wings, for example, are reported ranging from single or multiple sharp transitions to broad (Δν > 100 cm−1) diffuse signals.
Despite the large number of example spectra in the literature, a quantitative understanding of the helium induced fine structure of the zero phonon line and the phonon wing is missing. Our approach is a systematic investigation of related molecular compounds, which may help to shed light on this key feature of microsolvation in superfluid helium droplets. This paper is part of a comparative study of the helium induced fine structure observed in electronic spectra of anthracene derivatives with particular emphasis on a spectrally sharp multiplet splitting at the electronic origin. In addition to previously discussed species, 9-cyanoanthracene and 9-chloroanthracene will be presented in this study for the first time.
We show experimentally that field-free one-dimensional (1D) alignment of 1,4-diiodobenzene molecules embedded in helium nanodroplets, induced by a single, linearly polarized 200-fs laser pulse, can be significantly enhanced by using two or four optimally synchronized laser pulses. The strongest degree of 1D alignment is obtained with four pulses and gives ⟨cos2θ⟩>0.60. Besides the immediate implications for molecular frame studies, our results pave the way for more general manipulation of rotational motion of molecules in He droplets.
The purpose of this paper is to show how trust as an organizational value contributes to employee competence utilization in the case of innovation capability. Thus, it is the objective of this paper to analyze the positive impacts, but also potential limits of trust in business management. The research paper uses two different quantitative empirical studies drawn from German and Austrian midsized companies to empirically test this interrelation.
As a result, the paper determines particular aspects of trust such as accountability, shared norms and the ability to take responsibility to be interrelated with the usage of employee competences and underlines a positive connection between product innovation performance and trust. However, the trust concept needs enriching elements to be balanced towards a feeling of mutual reliance and support creativity instead; inclusions of bridging social capital, elements of distrust and a pioneering spirit are to be mentioned here.
Der Wärmeschutz der äußeren Gebäudehülle ist wegen der zukünftig erforderlichen Energieeinsparungen stark in der öffentlichen Diskussion präsent und wird vom Gesetzgeber über Novellierungen der Energieeinsparverordnung flankiert.
Ein großes Potenzial hinsichtlich der Energieeinsparung steckt dabei in der Sanierung von Altbauten. Hier wird zur Verbesserung des Wärmeschutzes oftmals mit Wärmedämmverbundsystemen (WDVS) oder vorgehängten gedämmten Fassadenverkleidungen gearbeitet. Durch Aufbringen dieser Dämmsysteme wird auch die Schalldämmung der Außenwand beeinflusst.
In einem im Rahmen der Forschungsinitiative Zukunft Bau geförderten und beim ift Rosenheim durchgeführten Forschungsvorhaben [1] wurden Untersuchungen der Schalldämmung speziell an Dämmsystemen aus nachwachsenden Rohstoffen auf schweren, mittelschweren und leichten Massivwänden durchgeführt (Bild 1). Die akustische Wirksamkeit dieser Dämmsysteme wurde analysiert und mit Prognosemodellen verglichen. Ergebnisse aus diesem Forschungsprojekt werden in diesem Beitrag vorgestellt.