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- Fakultät für Holztechnik und Bau (19) (remove)
This paper presents a method which allows to assess the wettability of thermomechanical pulp (TMP) with thermoplastic. The method is based on the usage of laboratory sheets made of TMP and plastic granules which form drops under heat. The contact angle of the drops after re-solidification on the surface of the laboratory sheets serves as the wetting characteristic. This method enables a direct and evaluable testing of wood fiber thermoplastic combinations. The exemplary results indicate that wood species, pulping temperature and mercerization influence the wettability of TMP with thermoplastic.
We describe physically based analytical models for n‐channel amorphous silicon thin film transistors and for n‐ and p‐channel polysilicon thin film transistors. The models cover all regimes of transistor operation: leakage, subthreshold, above‐threshold conduction, and the kink regime in polysilicon thin film transistors. The models contain a minimum number of parameters which are easily extracted and can be readily related to the structural and material properties of the thin film transistors. The models have been verified for a large number of devices to scale properly with device geometry.
We describe a new physics based, analytical DC model accounting for short channel effects for hydrogenated amorphous silicon (a-Si:H) thin film transistors (TFT's). This model is based on the long channel device model. Two important short-channel phenomena, self-heating and kink effects, are analyzed in detail. For the self-heating effect, a thermal kinetic analysis is carried out and a physical model and an equivalent circuit are used to estimate the thermal resistance of the device. In deriving the analytical model for self-heating effect, a first order approximation and self-consistency are used to give an iteration-free model accurate for a temperature rise of up to 100/spl deg/C. In the modeling of the kink effects, a semi-empirical approach is used based on the physics involved. The combined model accurately reproduces the DC characteristics of a-Si:H TFT's with a gate length of the 4 /spl mu/m. Predictions for a-Si:H TFT's scaled down to 1 /spl mu/m are also provided. The model is suitable for use in device and circuit simulators.
Driving forest machines on wet soils causes irreversible soil compaction, often associated with intensive rut formation and inaccessibility of wheeled forest machines for future forest operations. The German forestry equipment manufacturer FHS, Forsttechnik Handel & Service GmbH, engineered a forwarder, the Trac 81/11, equipped with conventional, well-proved bogie-axles embraced by a closed rubber track. At the center of the bogie-axle, four additional supportive rollers are placed to increase the load-carrying section between the tires of the bogie-axle. The study aimed to characterize the principle concept and the trafficability of the forwarder by analyzing the footprint area, the contact pressure, the rut formation on forest sites and the slippage during driving. Therefore, the effective contact area was measured on steel plates and rut formation was analyzed on a case study basis. Results showed that the supportive rollers increase the contact surface area by about 1/3. By this, a decrease of peak loads below the wheels and a more homogenous load distribution were observed. However, the contact surface area is still clearly divided into three parts; the area between the supportive rollers and the wheels does not take any load. Results of the rut formation were diverse: After 20 passes with 26,700 kg total mass, rut depth varied between 12.6 and 212.5 mm. Overall, the new undercarriage concept of FHS demonstrated a generally positive performance. The engineered forwarder contributes to reduce the environmental impact associated with log extraction.
Driving forest machines on wet soils causes irreversible soil compaction, often associated with intensive rut formation and inaccessibility of wheeled forest machines for future forest operations. The German forestry equipment manufacturer FHS, Forsttechnik Handel & Service GmbH, engineered a forwarder, the Trac 81/11, equipped with conventional, well-proved bogie-axles embraced by a closed rubber track. At the center of the bogie-axle, four additional supportive rollers are placed to increase the load-carrying section between the tires of the bogie-axle. The study aimed to characterize the principle concept and the trafficability of the forwarder by analyzing the footprint area, the contact pressure, the rut formation on forest sites and the slippage during driving. Therefore, the effective contact area was measured on steel plates and rut formation was analyzed on a case study basis. Results showed that the supportive rollers increase the contact surface area by about 1/3. By this, a decrease of peak loads below the wheels and a more homogenous load distribution were observed. However, the contact surface area is still clearly divided into three parts; the area between the supportive rollers and the wheels does not take any load. Results of the rut formation were diverse: After 20 passes with 26,700 kg total mass, rut depth varied between 12.6 and 212.5 mm. Overall, the new undercarriage concept of FHS demonstrated a generally positive performance. The engineered forwarder contributes to reduce the environmental impact associated with log extraction.
Novel hybrid admixtures for construction applications were prepared by layer-by-layer deposition technique. Colloidal core templates consisting of styrene/n-butylacrylate latex particles were coated with multilayers of superplasticizers commonly used in concrete. This way, core-shell particles possessing both dispersing and film-forming properties were achieved. Incorporation of the latex@dispersant hybrid additive into a cement paste results in a slow release of the superplasticizer as a result of gradual shell disintegration which instigates prolonged plastification (long ”slump life”) of the cement slurry. Once the shell has been dissolved, latex particles are released into the pore solution and can coalesce into a polymer film which improves the mechanical properties of the hardened cement. Characterization of the templates and novel additives was performed by means of zeta potential measurement, dynamic light scattering and electron microscopy. Our method allows to synthesize multifunctional additives with time-controlled release effect.
Novel microcapsules were prepared from colloidal core–shell particles by acid dissolution of the organic core. Weakly crosslinked, monodisperse and spherical melamine-formaldehyde polycondensate particles (diameter ∼ 1 μm) were synthesized as core template and coated with multilayers of an anionic polyelectrolyte via layer-by-layer deposition technique. As polyelectrolytes, an anionic naphthalenesulfonate formaldehyde polycondensate that is a common concrete superplasticizer and thus industrially available, and cationic poly(allylamine hydrochloride) were used. Core removal was achieved by soaking the core–shell particles in aqueous hydrochloric acid at pH 1.6, resulting in hollow microcapsules consisting of the polyelectrolytes. Characterization of the template, the core–shell particles, and the microcapsules plus tracking of the layer-by-layer polyelectrolyte deposition was performed by means of zeta potential measurement and scanning electron microscopy. The microcapsules might be useful as microcontainers for cement additives.
Innovative beech laminated veneer lumber (LVL) circular hollow sections for the use as temporary geotechnical soil nailing systems are currently being developed. Due to the permanent subsoil cement embedment, combined with high water saturation and permanent loading, the timber sections will lose strength and stiffness over time to a degree currently unknown. This paper presents the tensile and bending material properties of flat and curved beech LVL under various periods of immersion in a water–cement grout solution aiming at inducing both water saturation and long-term alkaline attack of the timber.
In total, 824 and 279 samples were tested in tension and bending, respectively. Results show that samples manufactured from 3 mm thick veneers result in tensile strength and stiffness 17% and 24% higher, respectively, than samples manufactured from 2 mm thick veneers. A reduction in the initial bending and tensile strength of up to 70% was found after 90 days of water saturation and cement contact. Taking into account a duration of load factor for permanent loading of two years, it is recommended to reduce the short-term tensile and bending strength of beech circular hollow sections to be used as geotechnical anchors by 80%.
Due to the application of elastic interlayers for acoustic decoupling, wood screws to connect timber elements are stressed beneath axial and shear loads additionally by a bending moment. The equations to calculate the load carrying capacity of wood-wood-connections according to the Eurocode 5, lose their validity in case of application of interlayers with low shear resistance. Furthermore, the increasing flexibilities of the joints should be considered for a realistic static modelling.
Aim of the present work is to analyze the mechanical load bearing characteristics of wall-ceiling-connections of cross laminated timber with and without elastic interlayers. On the basis of experiments as well as analytical approaches, the load-deformation-behavior is discussed and contrasted to the current standards.
Investigations on the interaction of cationic and anionic latex particles with Portland cement
(2008)
The interaction between organic latex polymers and the surface of hydrating cement was investigated by measuring the zeta potential and adsorbed amount of polymer on cement. First, differently charged model latex particles were synthesized in aqueous media by well-known emulsion polymerization technique. The latex polymers were characterized by differential scanning calorimetry (DSC), dynamic light scattering (DLS) and environmental scanning electron microscopy (ESEM). Electrokinetic latex surface properties were investigated by means of streaming potential measurements using a particle charge detector (PCD). It is shown that the anionic latexes adsorb a considerable amount of Ca2+ from the cement pore solution. Next, adsorption of the latex polymers on the surface of hydrating cement was confirmed by zeta potential measurements using the electroacoustic method. A water to cement ratio in the cement paste as low as 0.5 was studied, representing actual conditions in mortar and concrete. Additionally, adsorption isotherms were determined in a sedimentation test using the depletion method. For all latex polymers, Langmuir type adsorption isotherms were found. The latex dosages required to achieve saturated adsorption on the cement surface obtained from zeta potential measurements correspond well with those determined in the sedimentation test. Electron microscopy photographs confirm that the charged latex polymers adsorb selectively on surface areas of hydrating cement showing opposite charge. This way, domains of organic latex polymers exist on the cement surface. They provide adhesion between the inorganic cement matrix and the organic polymer film formed later on by particle coalescence as a result of cement hydration and drying.