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- Fakultät für Holztechnik und Bau (19) (remove)
Circular hollow sections of beech-laminated veneer lumber (LVL) for the use as temporary geotechnical soil nailing systems are currently being developed. Due to their permanent subsoil cement embedment, investigations of the bond line quality of the timber sections are essential. This paper presents the bonding properties of flat and curved beech LVL after cyclic conditioning in a water–cement grout solution aimed at inducing short- and long-term alkaline attack of the timber. In total, 409 and 69 samples were tested in tensile shear tests after short-term and long-term conditioning, respectively.
Three different adhesive systems, a one-component polyurethane adhesive, a melamine–urea–formaldehyde adhesive and a melamine–urea–formaldehyde adhesive modified by means of (polyvinyl)-acetate adhesive were investigated and compared. Short-term conditioning by submersion in boiling cement suspension was found to be a reliable method for testing the bonding performance rather than long-term conditioning. In the case of tensile shear tests of samples subjected to long-term treatment, wood material strength was the decisive criterion. Generally, tensile shear test samples of all investigated adhesives achieved reliable bonding for a pressing force up to 1.0 MPa. No relationship was recognised between the determined bonding failure and the wood properties tensile shear strength, wood failure percentage, fracture pattern and bulk density of veneers adjacent to the bond line.
For the determination of the bond line integrity of curved veneer poles, it was necessary to test bonding quality in a combined test using curved and flat samples and to compare tensile shear strength with data determined on reference samples in the same veneer population without bond line.
Innovative circular, hollow, laminated veneer lumber (LVL) beech sections for use as temporary geotechnical soil reinforcement members are currently being developed. Appropriate surface gluing quality between the veneers is fundamental to this subsoil application of the permanently cement-embedded, engineered timber product. The circular cross-section geometry and the permanently high-alkaline environment of the structural member is not covered by presently standardized testing and conditioning methods for examining LVL surface bond line quality. The sample conditioning and tensile shear test method compliant with EN 302-1 (Adhesives for load-bearing timber structures—test methods—part 1: determination of longitudinal tensile shear strength, European Committee for Standardization, Brussels, 2013) was modified to determine bonding parameters for circular, hollow LVL sections. Bond line curvature, groove cutting depth and sample geometry were found to greatly influence stress distribution, percentage of wood failure and tensile shear strength.
Short-term alkaline treatment of test samples did not significantly influence the bonding performance, wood failure percentage, tensile shear strength and fracture patterns. To improve tensile shear strength, adhesives with different material rigidities were used and compared. An orthotropic, elastic numerical analysis revealed a greater influence of adherent elasticity than adhesive elasticity on the stress distribution within the bond line. With regard to determining the bond line integrity of curved veneer poles, a sample geometry compliant with EN 302-1 (2013) was developed and numerically evaluated.
Environmental scanning electron microscopy (ESEM) and complementary methods were employed to study the time dependent film formation of a latex dispersion in water and cement pore solution. First, a model carboxylated styrene/n-butyl acrylate latex dispersion possessing a minimum film forming temperature (MFFT) of 18 °C was synthesized in aqueous media via emulsion polymerization. Its film forming property was at a temperature of 40 °C, studied under an ESEM. The analysis revealed that upon removal of water, film formation occurs as a result of particle packing, particle deformation and finally particle coalescence. Film formation is significantly retarded when the latex dispersion is present in cement pore solution. This effect can be ascribed to adsorption of Ca2+ ions onto the surface of the anionic latex particles and to interfacial secondary phases. This layer of adsorbed Ca2+ ions hinders interdiffusion of the macromolecules and subsequent film formation of the latex polymer.
Both the subthreshold slope and the threshold voltage in inverted-staggered amorphous silicon thin-film transistors (a-Si:H TFTs) are vulnerable to metastable changes in the density of states (DOS) due to Fermi level displacement. In previous work, we have used passivated and unpassivated TFTs to distinguish between the effects of bulk states and interface states at the top passivating nitride interface. Here we report the results of experimental measurements and two-dimensional (2-D) simulations on unpassivated TFTs. Since there are no top interface states, all the observed changes are due solely to the bulk DOS. The subthreshold current activation energies in a-Si:H TFTs are compared for n-channel nonpassivated TFTs before and after bias stress. The experimental results agree well with the 2-D simulations, confirming that the dependence of subthreshold current activation energy on gate bias reveals the distribution of the DOS in energy but cannot resolve the magnitude of features in the DOS. This type of analysis is not accurate for TFTs with a top passivating nitride, since the activation energies in such devices are affected by the interfere states.
Analytical Models for Amorphous Silicon and Polysilicon TFTs for High Definition Display Technology
(1996)
We report temperature measurements of inverted staggered amorphous silicon thin film transistor subthreshold conductance for devices with and without a top silicon nitride passivating layer. Subthreshold conductance activation energies clearly show the different conductance paths in the active layer of these devices. Transistors with no top nitride layer conduct in the bulk amorphous silicon, whereas the devices with a top nitride layer conduct at the interface between the amorphous silicon and the top nitride (a ‘‘back’’ channel). Gate bias stressing and light soaking experiments uphold the existence of the back channel. We also present two‐dimensional simulations that support our interpretation of the experimental data.
Several methods were employed to study the time dependent film formation of a self synthesized anionic latex dispersion in water and cement pore solution. First, a model carboxylated styrene/n-butyl acrylate latex dispersion possessing a minimum film forming temperature (MFFT) of 18 °C and a glass transition temperature (Tg) of 30 °C was synthesized via emulsion polymerization. Next, its film forming behaviour was studied at 40 °C, using an ESEM instrument. The analysis revealed that upon removal of water, film formation occurs as a result of particle packing, particle deformation and finally particle coalescence. Film formation is significantly hindered in synthetic cement pore solution. This effect can be ascribed to adsorption of Ca2+ ions onto the surface of the anionic latex particles and to interfacial secondary phases. This layer of adsorbed Ca2+ ions hinders interdiffusion of the macromolecules and subsequent film formation of the latex polymer.
Novel hybrid admixtures for construction applications were prepared by layer-by-layer deposition technique. Colloidal core templates consisting of styrene/acrylate latex particles were coated with multilayers of polycondensate-based dispersants commonly used in concrete. This way, core–shell particles possessing both dispersing and film-forming properties were achieved. Incorporation of the latex@dispersant hybrid additive into a cement paste results in a slow release of the dispersant which instigates prolonged plastification of the cement slurry. Following disintegration of the shell, the latex core particles are released into the pore solution and coalesce into a polymer film which improves the mechanical properties of the hardened cement. Characterization of the templates and novel additives plus tracking of the layer-by-layer polyelectrolyte adsorption was performed by means of zeta potential measurement, dynamic light scattering and electron microscopy. Our method allows to synthesize multifunctional additives with time-controlled release effect.
This paper investigates the long-term tensile properties of laminated veneer lumber (LVL) beech sections coated with cement and exposed to fungal decay. A set of LVL coupon (dog-bone) samples was stored in compost, tested in tension after 6 and 12 months and compared to reference samples stored at 20 °C and 65% relative humidity. Results showed that after 26 weeks of compost exposure, a fungus of the Ascomycota genus was identified in cement-coated samples using a molecular biology polymerase chain reaction (PCR) technique, which analyses the internal transcribed spacer (ITS) region of the ribosomal DNA. However, no visual deterioration was noticed.
Still in cement-covered samples and after 12 months of exposure, a common white rot fungus was determined by DNA chip technology, but no fungal wood decay was visible in areas where the applied coating had a thickness of at least 5 mm. Decay in uncoated LVL samples was significant with the samples having an average residual strength equal to 7%. This compares to the tensile strength of coated samples, which only decreased by 65% relative to the reference samples. Strength and stiffness of coated samples did not differ significantly between 6 and 12 months of exposure. Preliminary investigations tend to show that the strength reduction in cement-coated samples is due to an alkaline degradation of the wood. The observed influence of the coating thickness on the visual fungal decay can probably be ascribed to the protection mechanism due to a physical fungal barrier with a high pH.
Investigations on the interaction of cationic and anionic latex particles with Portland cement
(2008)
The interaction between organic latex polymers and the surface of hydrating cement was investigated by measuring the zeta potential and adsorbed amount of polymer on cement. First, differently charged model latex particles were synthesized in aqueous media by well-known emulsion polymerization technique. The latex polymers were characterized by differential scanning calorimetry (DSC), dynamic light scattering (DLS) and environmental scanning electron microscopy (ESEM). Electrokinetic latex surface properties were investigated by means of streaming potential measurements using a particle charge detector (PCD). It is shown that the anionic latexes adsorb a considerable amount of Ca2+ from the cement pore solution. Next, adsorption of the latex polymers on the surface of hydrating cement was confirmed by zeta potential measurements using the electroacoustic method. A water to cement ratio in the cement paste as low as 0.5 was studied, representing actual conditions in mortar and concrete. Additionally, adsorption isotherms were determined in a sedimentation test using the depletion method. For all latex polymers, Langmuir type adsorption isotherms were found. The latex dosages required to achieve saturated adsorption on the cement surface obtained from zeta potential measurements correspond well with those determined in the sedimentation test. Electron microscopy photographs confirm that the charged latex polymers adsorb selectively on surface areas of hydrating cement showing opposite charge. This way, domains of organic latex polymers exist on the cement surface. They provide adhesion between the inorganic cement matrix and the organic polymer film formed later on by particle coalescence as a result of cement hydration and drying.