Open Access

Sunnyvijay Yarram

• Concerns have been raised about the end-of-life management of bioplastics as their demand increasing as a sustainable alternative to conventional plastics. The fate of bioplastic waste, especially packaging waste, remains largely unexplored in existing waste management systems. Anaerobic digestion (AD) is considered as a viable end-of-life option for bioplastics, however, current research has been primarily limited to lab-scale studies. This study investigated the anaerobic digestion of film samples made from Bioplast 106, PBAT, PLA and Ecovio (PLA/PBAT blend) under mesophilic and thermophilic conditions in pilot-scale biodigesters. The results of 90-day thermophilic AD demonstrated that PLA and Ecovio exhibited significant biodegradation of 36% and 50% by dry mass loss, respectively, while Bioplast 106 exhibited moderate biodegradation of 22.22%. The collective methane yield from these three bioplastics was 322.86 mL CH4/g VS, indicating their potential for biogas production. SEM and FT-IR analyses confirmed structural degradation of Bioplast 106, PLA, and Ecovio, while no degradation was observed for PBAT. PBAT showed high resistance to AD in pure and blended form (Bioplast 106, Ecovio). Bioplast 106 exhibited diverse degradation patterns, influenced by feedstock type, digester temperature, and processing conditions. This study might serves as valuable reference for assessing the anaerobic biodegradability of Bioplast 106 in pilot-scale biodigesters. This study further highlights the necessity of optimization of pilot-scale AD conditions to enhance the anaerobic biodegradability of slow-degrading bioplastics.