Labor Additive and Intelligent Manufacturing for Sustainability (AIMS)
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- additive manufacturing (14)
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- peer-reviewed (19)
In former works, the optical material properties of different polymer powders used for Laser Beam Melting (LBM) at room temperature have been analyzed. With a measurement setup using two integration spheres, it was shown that the optical material properties of polymer powders differ significantly due to multiple reflections within the powder compared to solid bodies of the same material. Additionally, the absorption behavior of the single particles shows an important influence on the overall optical material properties, especially the reflectance of the powder bed. Now the setup is modified to allow measurements at higher temperatures. Because crystalline areas of semi-crystalline thermoplastics are mainly responsible for the absorption of the laser radiation, the influence of the temperature increase on the overall optical material properties is analyzed. As material, conventional polyamide 12 and polypropylene as new polymer powder material, is used. By comparing results at room temperature and at higher temperatures towards the melting point, the temperature-dependent optical material properties and their influence on the beam-matter interaction during the process are discussed. It is shown that the phase transition during melting leads to significant changes of the optical material properties of the analyzed powders.
In this report, the delivery of polyamide 12 (PA 12) powder and powder layer preparation by vibrating steel nozzles is investigated and discussed with respect to its application for laser beam melting. Therefore, a setup was realized which includes a steel nozzle attached to a piezo actor as well as a positioning system. In order t o investigate the mass flow characteristics in dependency on the applied vibration state, a weighing cell is used enabling time-resolved mass flow measurements. Moreover, single-layer patterns consisting of colored and uncolored polyamide 12 were created and characterized regarding surface homogeneity and selectivity before as well as after the melting of the powder layers by a hot plate.
By Laser Beam Melting of polymers (LBM), parts with almost any geometry can be built directly out of CAD files without the need for additional tools. Thus, prototypes or parts in small series production can be generated within short times. Up to now, no multi-material parts have been built by LBM, which is a major limitation of the technology. To realize multi-material parts, new mechanisms for depositing different polymer powders as well as a new irradiation strategy are needed, by which polymers with different melting temperatures can be warmed to their specific preheating temperatures and be molten simultaneously. This is achieved by simultaneous laser beam melting (SLBM). In the process, two different materials are deposited next to each other and preheated a few degrees below their melting temperatures by infrared emitters and laser radiation (λ = 10.60 µm), before in the last step the two preheated powders are molten simultaneously by an additional laser (λ = 1.94 µm). So far, multi-material tensile bars have been realized and analyzed regarding their boundary zone between both materials. The experiments showed that the temperature gradients in the boundary zone and along the building direction seem to be of great importance for the process stability and the resulting part properties. Therefore, a detailed analysis of the occurring temperature gradients during the process is needed to identify adequate process adjustments regarding the temperature controlling. To analyze the temperature gradients, thermocouples positioned inside the powder bed are used. By varying the temperature of the building platform, the influence of different temperature gradients on the resulting part properties is shown.
The generation of multi-material components using Laser beam melting (LBM) is a challenge which requires the invention of new coating devices for the preparation of arbitrary powder patterns. One solution is the usage of vibration-controlled nozzles for selective deposition of polymer powders. Powder flow can be initiated by vibration even when using powders with low flowability. In this report, the selective deposition of polymer powder by vibrating nozzles is investigated with respect to their application in LBM machines. Therefore, a steel nozzle attached to a piezo actor is applied, whereas the nozzle itself features internal channels which allow the precise control of the powder temperature using heat transfer oil. The setup is used to study the influence of temperature on the powder mass flow. The results show that, next to the vibration mode, the temperature strongly influences the powder mass flow which is done by affecting the moisture and thus the particle-particle adhesion forces. This shows that a precise control of the powder temperature inside the nozzle is required in order to achieve a constant mass flow and thus a successful application of vibrating nozzles inside LBM machines.
Im Rahmen dieses Beitrags wird das Schmelzeemulgieren als Verfahren zur Herstel-lung von Polymermikropartikeln vorgestellt. In diesem Prozess wird zunächst ein Polymergranulat in einer kontinuierlichen Phase in Gegenwart geeigneter Additive in einem Rührbehälter aufgeschmolzen, die Rohemulsion in einer Rotor-Stator-Einheit feinemulgiert und anschließend zu einer Suspension abgekühlt. Der Einfluss von Prozessparametern und Systemzusam-mensetzung auf das Emulgierergebnis wird diskutiert und die Anwendbarkeit des Verfahrens für polymere Mikropartikeln anhand von Polypropylen (PP) und Polyethylen (PE-HD) dargestellt. Die erhaltenen Suspensionen werden zur Überführung in Pulverform sprühgetrocknet und die Fließeigenschaften des Pulvers analysiert. Durch trockenes Beschichten mit pyrogener Kieselsäure kann die Fließfähigkeit der erhaltenen Partikeln weiter verbessert werden. Das Verfahren bietet somit einen neuen Zugang zur Herstellung neuer Ausgangsmaterialien für die Additive Fertigung.
Neue Prozessstrategien zur Herstellung von Multi- Material-Bauteilen und Gradientenwerkstoffen
(2012)
Das additive Fertigungsverfahren, dem gemeinhin die größten Potentiale zugesprochen werden, ist das Laserstrahlschmelzen im Pulverbett von Kunststoffen (LSS-K) und von Metallen (LSS-M). Wie bei anderen Techniken der additiven Fertigung werden Bauteile direkt aus CAD-Dateien ohne zusätzliche Werkzeuge bei enormer konstruktiver Freiheit gefertigt. Die resultierenden Werkstoffeigenschaften sind vergleichbar mit konventionelleren Prozessrouten wie etwa dem Spritzgießen thermoplastischer Polymere beziehungsweise auf der Seite der Metalle dem Schmieden oder Gießen. Derzeit wird der Einsatz des LSS zur Fertigung von Endprodukten in kleinen Stückzahlen erschwert von nicht ausreichender Prozessstabilität und, insbesondere bei Kunststoffen, von der eingeschränkten Werkstoffauswahl. Bisher werden für beide Werkstoffklassen Bauteile aus jeweils einem einzigen Ausgangsmaterial hergestellt. Näherungsweise erzeugt LSS also einheitliche Materialeigenschaften über das gesamte Bauteil hinweg. Ein Ansatz, der in den Teilprojekten A5 und B6 des Sonderforschungsbereichs 814 verfolgt wird, ist die Realisierung von Multi-Material-Bauteilen mittels LSS-K beziehungsweise LSS-M.
In the paper first results regarding the realisation of gradient and multi-material parts manufactured by Laser Beam Melting in powder bed of metals and polymers are published. Gradient properties of additively manufactured metal parts can be achieved by varying the composition of alloying components in the powder and adapting process strategies. As an alternative to atomizing pre-alloyed materials, mixtures of different powders are investigated. For realizing multi-material-parts from polymers, at first relevant material properties concerning compatibility have to be analysed. Therefore the paper shows the main requirements for compatibility between different materials and also first results regarding the compatibility of polymer powders and possible combinations for the manufacturing of multi-material components by laser beam melting of polymers.
Simultaneous laser beam melting (SLBM) allows the direct realization of multi-material components consisting of different polymer materials by a single Additive Manufacturing (AM) process. To achieve a high compound strength between different materials by adhesive bonding, a common boundary zone based on diffusion of the macromolecules is necessary and thus, both materials needs to be compatible regarding their specific adhesion compatibility. However, by SLBM also incompatible polymers can be processed to multi-material parts. If two incompatible polymers are processed, a positive locking between the different materials is necessary to achieve a connection between the materials. The positive locking results of a random mixture process of the different powder materials during the powder deposition process by a two chamber recoater system, which leads to the forming of undercuts of one material in the other during the melting and recrystallization. In this paper, thermoplastic elastomer (TPE) and polypropylene (PP) powders, which are incompatible, are processed to multi-material specimens. By qualifying basic material properties, their influence on the process and especially on the forming of undercuts in the boundary zone is analyzed. To also allow the analysis of the influence of both material and process parameters on the resulting part properties, tensile test specimens are built and their tensile strength is determined. Additionally, cross sections of the boundary zone are prepared and analyzed by microscope images.
Simultaneous Laser Beam Melting of polymers (SLBM) allows the generation of multi-material components,consisting of different thermoplastic polymers, within one additive building process. Besides the common advantagesof conventional Laser Beam Melting (LBM), multi-material components built by SLBM can fulfill different productrequirements like different chemical resistances or haptic material properties within a single part. To achieve suchparts, different powder materials are deposited next to each other and preheated a few degrees below their meltingtemperatures by infrared emitters and laser radiation (λ = 10.60 μm), before in the last step the preheated powdersare molten simultaneously by an additional laser source (λ = 1.94 μm). In this paper, different polymer powders likepolypropylene (PP) and polyamide 12 (PA12) are used for the generation of multi-material specimens. By varyingdifferent building parameters according to a specified design of experiments, their influence on the part properties isanalyzed. Important building parameters are the intensity and the irradiation time of the laser beam used for meltingthe preheated powders. Besides using tensile tests to determine the tensile strength and the elongation at break, theaverage part height in dependence of the energy input is analyzed. The overall aim is to specify the correlationbetween different building parameters regarding the energy deposition on the resulting part properties.
By simultaneous laser beam melting (SLBM), parts consisting of different polymer powders can be additively manufactured within one building process. Besides the advantages of conventional LBM, e.g., not needing additional tools and being able to realize parts with almost any geometry, different product requirements can be achieved within a single part. Product requirements may be different chemical resistances or haptic material properties. Therefore, SLBM enlarges the application field for additive manufacturing in general. In the process, two different materials are deposited on the building platform and preheated a few degrees below the melting temperature of the lower melting polymer by infrared emitters. Afterward, a CO2 laser (λ = 10.6 μm) provides the energy for the temperature difference between the preheating temperatures of both materials. Finally, a digital light processing chip is used to achieve simultaneous and flexible energy deposition for melting both preheated polymers. By illuminating the chip with a laser, parts of the beam can be flexibly guided onto the powder bed or into a beam trap. As laser, a single mode thulium laser (λ = 1.94 μm) is used. After melting the layer, a new layer is deposited and the process starts anew. In this paper, polypropylene and polyamide 12 are used as materials. After analyzing the material and melting behavior during the process by a high-resolution thermal imaging system, the parts are qualified regarding their material compatibility at the boundary zone and porosity by cross sections.