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Ammonia is increasingly considered a promising hydrogen carrier due to its high hydrogen density and well-established infrastructure. Monitoring ammonia cracking efficiency requires robust, continuous gas analysis across a wide concentration range, with resistance to corrosive gases. Conventional methods such as gas chromatography or mass spectrometry meet these requirements, but are costly and operationally complex. To address this gap, a Thermal Conductivity Analyzer (TCA) was developed based on an OEM module and validated for continuous in situ monitoring of ammonia cracking. The system includes a pump-driven bypass extraction line and a three-stage calibration procedure: zero-point correction, look-up table generation, and span calibration. Measurement stability was assessed using binary H2/N2 mixtures and a quasi-binary surrogate of the ammonia cracking product gas, mixed via mass flow controllers (MFCs). The analyzer was then applied to characterize a monolithic ammonia cracking catalyst from 200– 650∘C. With daily zero-point and span calibration, all measured H2 concentrations fell within the mixing uncertainty of the MFCs across 0– 100vol.%. For the synthetic cracking gas, maximum conversion ratio deviations of +0.317 and −0.224 percentage points were achieved. These results demonstrate that the TCA offers a simple, ammonia-resistant alternative for monitoring NH3 cracking processes, with uncertainties competitive with MFC repeatability.
We measured the cubic nonlinear susceptibility tensor elements ( χ(3)) for polarization along the primary crystallographic axis in titanium-indiffused lithium niobate waveguides, assessed through self-phase modulation using picosecond-duration pulses at telecommunication wavelengths. A dominant, highly temperature- and wavelength-dependent contribution from a cascaded second-order nonlinearity is observed. Through careful extraction of the cascaded effect, we quantify the intrinsic third-order susceptibility tensor elements as χ(3) zzzz(ω; ω, ω, −ω) = (5.2 ± 1.3) × 10−21 m2 V2 and χ(3) xxxx(ω; ω, ω, −ω) = χ(3) yyyy(ω; ω, ω, −ω) = (3.6 ± 0.8) × 10−21 m2 V2 .
These measurements underscore the substantial impact of the cascaded nonlinearity in enhancing the effective cubic nonlinearity in lithium niobate and offer precise values essential for the design of nonlinear photonic devices.
Additive manufacturing (AM), particularly laser powder bed fusion (L-PBF), provides unmatched design flexibility for creating intricate steel structures with minimal post-processing. However, adopting L-PBF for high-performance applications is difficult due to the challenge of predicting microstructure evolution. This is because the process is sensitive to many parameters and has a complex thermal history. Thin-walled geometries present an added challenge because their dimensions often approach the scale of individual grains. Thus, microstructure becomes a critical factor in the overall integrity of the component. This study focuses on applying cellular automata (CA) modeling to establish robust and efficient process–structure relationships in L-PBF of 316L stainless steel. The CA framework simulates solidification-driven grain evolution and texture development across various processing conditions. Model predictions are evaluated against experimental electron backscatter diffraction (EBSD) data, with additional quantitative comparisons based on texture and morphology metrics. The results demonstrate that CA simulations calibrated with relevant process parameters can effectively reproduce key microstructural features, including grain size distributions, aspect ratios, and texture components, observed in thin-walled L-PBF structures. This work highlights the strengths and limitations of CA-based modeling and supports its role in reliably designing and optimizing complex L-PBF components.
This paper extends prior work on low-code by explaining when adoption archetypes occur and how to use them. Motivated by information technology (IT) talent shortages and uneven low-code development platform (LCDP) outcomes, the paper seeks practical guidance for post-adoption choices in work systems. Using a multiple mini case study of 36 cases in large German organizations, this study analyzes interviews and context questionnaires with within-/cross-case coding and pattern matching against a 13-factor model. This analysis identifies situations that trigger three adoption archetypes—application development democratizers, synergy realizers, and IT resource shortage mitigators—and one non-adoption archetype, intricacy adversaries. The analysis also maps advantages and disadvantages and distills 12 good practices. Across adoption cases, efficiency is the dominant goal, whereas non-adoption stems from high application sophistication. The results give actionable guidance: align goals to an archetype, stick to LCDP standards, involve IT and foster an open culture, invest in skilling, reuse platform components, and reserve LCDPs for less-complex apps while planning architecture early.
Between 51% and 72% of a bituminous roofing membrane used for structural water-proofing consists of organic material, predominantly bitumen - a derivative of crude oil refining - highlighting the strong dependence of this product on fossil resources. Considering that several tonnes of these membranes must be replaced every 30 to 50 years, substantial potential exists for emission reduction through the establishment of circular material systems. This study investigates this potential by analysing 26 Environmental Product Declarations (EPDs) and life cycle datasets from across Europe covering the period from 2007 to 2023. To ensure comparability, all data were normalised to a declared unit of 1 kg of roofing membrane. The reinforcement layers were categorised into glass and polyester & glass composites, and their differences were examined using Welch’s t-tests.
Correlative analyses and linear as well as multiple regression models were then applied to explore relationships between environmental indicators and the shares of organic and mineral mass fractions. The findings reveal that renewable energy sources, although currently representing only a small share of total production energy, provide a major lever for
reducing nearly all environmental impact categories. The type of reinforcement layer was also found to influence the demand for fossil resources, both materially and energetically.
For most environmental indicators, only multiple regression models can explain at least 30% of the variance based on the proportions of organic and mineral inputs. Overall, the study underscores the crucial importance of high-quality, transparently documented product data for accurately assessing the sustainability of building products. It further demonstrates that substituting fossil energy carriers with renewable sources and optimising material efficiency can substantially reduce environmental burdens, provided that methodological consistency and clarity of indicator definitions are maintained.
Intra-abdominal pressure is a significant physiological parameter influencing spinal stability and pelvic floor health. This study investigates the potential of a transformer encoder model to predict IAP using motion capture data and musculoskeletal modeling. Data from 211 subjects performing walking, fast walking, and running were used to train a transformer encoder. The model showed promising results with an overall Mean Absolute Percentage Error of 13.5% and a Pearson correlation coefficient of 0.85. Predictions for fast walking and running proved to be more challenging compared to walking, which was attributed to the greater variability and complexity of faster movements.
Boundary spanning—the actions and roles individuals or organizations undertake to bridge differences and facilitate communication, collaboration, and understanding across diverse cultural, organizational, or geographical divisions—is an essential element of international cooperation. Set against the backdrop of the Russia-Ukraine war, The purpose of this study is to explore the type of boundary spanning in this uncertain context, the linguistic characteristics of boundary spanners, the necessary skills and competencies required to navigate the complex socio-political landscape, and the role of boundary spanners in humanitarian assistance. This study employs a qualitative research approach, using semi-structured interviews with informants actively engaged in relief efforts and cross-cultural collaboration. The findings emphasized the significance of English as the primary language of communication, the importance of cultural sensitivity and awareness, and the need for intercultural competence in effective boundary spanning. The study concludes with insights from the ongoing Ukrainian experience of bridging geodemographic boundaries and the role of boundary spanners in this process, highlighting key aspects of boundary spanning. Overall, the study contributes to the theoretical background of boundary spanning and enhances the understanding of how linguistic and cultural boundary spanning can drive positive change and improve outcomes in humanitarian aid. The implications of this study suggest that underscore the critical need for collaboration with experienced boundary spanners in educational settings.
As global demand for green hydrogen rises, potential hydrogen exporters move into the spotlight. While exports can bring countries revenue, large-scale on-grid hydrogen electrolysis for export can profoundly impact domestic energy prices and energy-related emissions. Our investigation explores the interplay of hydrogen exports, domestic energy transition and temporal hydrogen regulation, employing a sector-coupled energy model in Morocco. We find substantial co-benefits of domestic carbon dioxide mitigation and hydrogen exports, whereby exports can reduce market-based costs for domestic electricity consumers while mitigation reduces costs for hydrogen exporters. However, increasing hydrogen exports in a fossil-dominated system can substantially raise market-based costs for domestic electricity consumers, but surprisingly, temporal matching of hydrogen production can lower these costs by up to 31% with minimal impact on exporters. Here, we show that this policy instrument can steer the welfare (re-)distribution between hydrogen exporting firms, hydrogen importers, and domestic electricity consumers and hereby increases acceptance among actors.
Purpose – The purpose of this study is to introduce surrogate elements for static and transient finite element simulations. These elements are designed to replace regions of several conventional solid elements with a single artificial element that possesses a reduced number of degrees of freedoms (dofs). A notable advantage of our surrogate elements is their seamless integration into standard finite element meshes.
Design/methodology/approach – The construction of the surrogate elements stiffness and mass matrices is achieved through an optimization process wherein displacements serve as the optimization objective. Moreover, the matrices are designed to possess properties analogous to those of standard finite elements. A particular focus is placed on ensuring that the artificial stiffness matrices are positive semi-definite. Furthermore, artificial degrees of freedom are introduced.
Findings – The efficacy of the proposed technique is demonstrated through its application to two different use cases. It is demonstrated that, despite being trained on examples comprising a single surrogate element, the surrogate elements can be employed multiple times within complex and practical models. The degree of accuracy achieved in these applications is noteworthy. Moreover, the proposed method is considerably faster than the fully discretized models.
Originality/value – The study expands the field of substructuring and model order reduction by incorporating artificial surrogate elements built by neural networks, which enables seamless integration with standard finite element analysis via positive semi-definite matrices. Furthermore, the introduction of artificial degrees of freedom, which are detached from the computational domain, is proposed. Once trained, the surrogate elements can be utilised in load and support independent scenarios.
INTRODUCTION
Sport psychology research has largely overlooked athletes with hearing impairments competing in Deaflympic sports, the designated elite sporting movement for this population. This study therefore explored Deaflympic athletes' and coaches' perspectives on mental training in the elite Deaf sports.
METHODS
A qualitative approach was used, involving six focus group interviews with 23 athletes (Mage = 33.09; 26.1% female) and four coaches from individual and team Deaf sports. Data were analyzed using reflexive thematic analysis.
RESULTS
Three themes emerged: sport psychology consultation, the influence of visual orientation on psychological skills and demands, and Deaf sport culture and communication. While participants expressed strong interest in sport psychology, engagement with professionals was limited by accessibility issues, lack of sign language-fluent consultants, and structural barriers. Deaf athletes reported adapting some techniques to match their visual-spatial orientation and both advantages and challenges of visual reliance in sports. Distinct communication dynamics between native signers and spoken-language users within Deaf teams were also revealed.
DISCUSSION
These findings highlight the importance of culturally sensitive sport psychology frameworks that support the needs and preferences of Deaflympic athletes and promote equitable access to effective mental training resources.