Energie und Mobilität
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This work aims at investigating the reduction/oxidation (redox) reaction kinetics on iron oxide pellets under different operating conditions of thermochemical hydrogen storage. In order to reduce the iron oxide pellets (90% Fe2O3, 10% stabilizing cement), hydrogen (H2) is applied in different concentrations with nitrogen (N2), as a carrier gas, at temperatures between between 700 ∘C and 900 ∘C, thus simulating the charging phase. The discharge phase is triggered by the flow of a mixture out of steam (H2O) and N2 at different concentrations in the same temperature range, resulting in the oxidizing of the previously reduced pellets. All investigations were carried out in a thermo-gravimetric analyzer (TGA) with a flow rate of 250mL/min. To describe the obtained kinetic results, a simplified analytical model, based on the linear driving force model, was developed. The investigated iron oxide pellets showed a stable redox performance of 23.8% weight reduction/gain, which corresponds to a volumetric storage density of 2.8kWh/(L bulk), also after the 29 performed redox cycles. Recalling that there is no H2 stored during the storage phase but iron, the introduced hydrogen storage technology is deemed very promising for applications in urban areas as day-night or seasonal storage for green hydrogen.
he hydrogen gas-to-liquid mass transfer is the limiting factor in biological methanation. In a trickle-bed reactor, mass transfer can be increased by high flow velocities in the liquid phase, by adding a packing material with high liquid hold-up, or by choosing methanogenic archaea with a high methane productivity. This study analyzed various packings and methanogenic strains from a hydrodynamic and microbial perspective. By analyzing twelve pure cultures of thermophilic methanogens for their ability to produce high quality methane and to form biofilms on different packings, strains of Methanothermobacter were found to perform better than thus of the genus Methanothermococcus. Best methane production and adherence was observed on DuraTop®, Bioflow 9, and filter foam. DuraTop® and Bioflow 9 had also a high dynamic liquid hold-up, but the maximum hold-up was determined for expanded clay. The ideal combination for use in the ORBIT-trickle-bed reactor was identified as Methanothermobacter thermoautotrophicus IM5 and DuraTop®.
The use of alternative fuels in high-power non-road mobile machinery (NRMM) combustion engines is a possible way to substitute fossil fuel. By using pure vegetable oil fuels, like rapeseed oil fuel (DIN 51605), the greenhouse gases can be reduced effectively. Due to the differences in physical and chemical properties, a modification of the engine control unit calibration is necessary to adapt the working process on the fuel. Without modifications, the engine power output with rapeseed oil fuel is lower than with diesel fuel because of the smaller energy content. By adapting the engine settings, like the injection fuel mass, the power loss can be compensated but it accompanies with a higher fuel consumption. The engine emissions at part load conditions show, that there are benefits in particle emissions by using rapeseed oil at similar NOx emissions. Therefore, a design of experiment setup was initiated on a selected engine operation point to determine the effects of further parameters, like rail pressure, manifold pressure and injection pattern, on the process and to see the potential of an optimized calibration.
Assuming that future connected cars with automated driving functions will require even more computing power and communication bandwidth, the current network infrastructure as well as the existing individualized control units are not a profitable option for such vehicles. In addition, changing user expectations demand flexible architectural patterns and upgradeability of software components without the need to visit the workshop. However, the current statically developed and configured ECU architecture does not offer any practicable possibilities for this. For these reasons, the research for a new dynamic and flexible architecture is necessary. This new type of system architecture is expected to meet future requirements in terms of space, cost, performance, energy efficiency and number of required computing units in the vehicle, which will arise as a result of the implementation/inclusion of new automated driving functionalities, and due to the changes in user expectations.
Solutions to this issue can be found in the field of enterprise
IT (cluster computing), in which technologies such as Ethernet,
container-based virtualization and flexible software architectures have proven themselves to be very efficient for years.
Relevant infrastructures, for example from cloud computing providers, have commonly been used in high-performance or high-availability applications. Thus, in the research project A 3F has been investigated which of these concepts and methods can be applied to modern vehicle system architectures. One of the main goals is to assess the synergy potential of the two sectors, information technology and automotive industry, which to date have very different orientations. However, this synergy is expected to grow strongly in the course of the developments mentioned above.
In the following pages, the necessary changes related to hardware and software will be discussed briefly und will be compared to concepts and possible solutions from the IT world.
Die Verschärfung der Abgasgesetzgebung sowie die politischen und gesellschaftlichen Forderungen an eine nachhaltige Mobilität zwingen die Automobilindustrie zur Entwicklung komplexer, hochpräziser mechatronischer Antriebssysteme. Die zunehmende Präzision der mechatronischen Komponenten führt dabei in der Regel zu einer
Zunahme der Strukturanregung und damit zu einer Erhöhung der Störgeräusche. Das so genannte Tickern des Kraftstoffeinspritzsystems hat im Vergleich zum Restmotorgeräusch einen niedrigeren Schalldruckpegel. Dennoch führt der impulshaltige und hochfrequente Geräuschcharakter zu einem Mangel in der Komfort- und Qualitäts-
32 wahrnehmung. Um die Geräuschqualität von raftstoffeinspritzsystemen als Frontloading-Maßnahme zu identifizieren, wurde ein Systemprüfstand entwickelt, der die Körper- und Luftschallabstrahlung des Einspritzsystems in seriennaher Konfiguration abbildet.
In diesem Beitrag werden Maßnahmen zur akustischen Optimierung von Einspritzsystemen und deren Auswirkungen auf die Robustheit im Systembetrieb diskutiert. Der Fokus liegt dabei auf dem Motorleerlauf, da an diesem Betriebspunkt das Tickern der Injektoren und der Hochdruckpumpe durch den geringen Maskierungseffekt anderer Geräusche am deutlichsten wahrzunehmen ist. Dazu wurden die Einspritzparameter im Vollmotorbetrieb erfasst und auf den Systemprüfstand transferiert. Durch ein spezielles Entwicklungssteuergerät war es möglich, die Parameter zu modifizieren, deren Einfluss auf das akustische Verhalten zu quantifizieren und darauf aufbauend NVHoptimierte
Ansteuerstrategien zu definieren. Zur Robustheitsbewertung der NVHoptimierten Ansteuerstrategien wurden Schlüsselfunktionen des Einspritzsystems unter variierenden Randbedingungen im Systembetrieb analysiert.
Beim Kauf eines Pkw wird der akustische Qualitätseindruck eines Fahrzeugantriebstrangs stetig relevanter. Die wahrgenommene Geräuschqualität des Motoraggregates nimmt hierbei eine Schlüsselrolle ein. Aufgrund der Ausprägung einzelner Störgeräusche wird jene Geräuschqualität negativ beeinflusst. Diese als unangenehm empfundenen Geräuschkomponenten gilt es im Rahmen der Fahrzeugentwicklung
weiter zu reduzieren, wobei die Identifikation und Bewertung störender Geräuschanteile am Motorgesamtgeräusch Voraussetzungen für eine effektive Akustikoptimierung sind. Vor allem das impulshafte Tickergeräusch wird bei Otto-DI-Motoren als besonders lästig eingestuft, weswegen dieser Beitrag darauf abzielt, die tickernden Geräuschanteile aus dem Gesamtgeräusch zu analysieren und zu bewerten. Hierzu wurde eine empirische Formel entwickelt, welche die tickernden Geräuschanteile in ihrer Intensität in Grenzen einstufen kann. Diese ist rein empfindungsbasiert und besteht aus der Impulshaftigkeit, der Lautheit sowie der Schärfe des Motorgesamtgeräusches.
Wie auch bei anderen psychoakustischen Bewertungsskalen wurde die Benotung von 1 (sehr tickernd) bis 10 (nicht tickernd) vorgenommen. Anhand von Hörversuchen mithilfe einer Expertenjury konnte die Tickergeräuschbewertungsformel anschließend verifiziert werden. Hiernach kann präzise ausgesagt werden, in welchen Motorkennfeldbereichen das Tickergeräusch die Angenehmheit des Motorgesamtgeräusches untergräbt.
The key for decentralized battery systems is a robust and communication-less control strategy for autonomous power sharing of parallel-connected DC-DC converters. Battery systems improve the reliability and quality of power supply in renewable energy systems and enable power supply for off-grid, mobile applications, including islanded grids, home storage, and electric vehicles. In many cases, components with different electrical properties require different voltage levels. An adaptation is consequently essential and is normally implemented in DC grids for the batteries via bidirectional DC-DC converters. The power flow in both directions can thus be ensured. To achieve a power distribution in parallel connected DC-DC converters, a droop control in the form of a virtual internal resistor can be used. This paper presents a novel approach of a DC-DC converter with a digitally parameterizable droop resistor, whose voltage regulation is based on an analog operational amplifier circuit to ensure low delays and robustness. The droop resistor is adjusted with a microcontroller, which offers the possibility to apply a higher-level control for load sharing via an interface. Mathematical correlations are used to clearly define the parameters of the control. Furthermore, the circuit was completely simulated and tested in the hardware setup. The shown results verify the functionality and indicate only minor deviations. Therefore, this circuit is important for future use in distributed battery systems.
DC- DC converters control the power flow and thus the power distribution between the components on different voltage levels. They are essential for (dis)charging batteries and influence the safety and stability of the entire battery management system (BMS). Therefore, testing the functionality and the reliability of DC-DC converters is crucial. This is especially true for decentralized battery management systems (DBMS), where multiple nodes communicate to collectively control the system. The used DC-DC converters are modified to parameterize them during operation via microcontroller interfaces. Integrating the communication into the control loop requires an analysis of the control behavior due to additional delays. Therefore, this paper proposes a framework to test DC-DC converters considering the control and communication perspectives. The response time, the control accuracy and stability of these DC-DC converters, e.g., under continuous and abrupt load changes, are measured in automated tests. The dedicated software framework simulates the DBMS and stimulates the hardware components (e.g. electronic loads, data acquisition) via respective interfaces (CAN, RS232). This allows the test of various DC-DC converters with flexibly adaptable load and power generation profiles. An initial application validates the test framework by verifying the aforementioned aspects and thus the applicability of a DC-DC converter within the DBMS.
With an increasing number of sold electric vehicles (EVs), a large number of used batteries will be at disposal. How to deal with these resources is one of the major challenges in reducing the environmental impact of batteries throughout their entire life cycle. Heterogeneous cell parameters due to the different usage histories are a challenge for second-life use. The effort and cost of remanufacturing required to test and assemble a new battery pack is a further concern. Systems that combine battery packs/modules without full reassembly offer advantages such as cost and reusability. A decentralized battery management system (DBMS) provides a suitable architecture for such systems involving different types of batteries. In this paper, an architecture for a decentralized, battery state-dependent control is shown. The proposed DBMS supports various types of batteries, is scalable and flexibly adaptable for a wide range of applications. Despite the significant advantages, there are increased requirements to meet for the hardware implementation and the applied control strategies. Therefore, the necessary hardware components and their requirements are described and the hardware implementations are provided.
Quantization and Sampling Effects in Fast Digitally Controlled Switch-Mode DC/DC Buck Converters
(2021)
Software-defined control of DC/DC switch mode power converters features unequaled flexibility compared to analog control. For fast switching converters as recently used for low power applications, digital control may cause steady-state oscillations known as limit cycles. This effect based on a quantized duty cycle is compared to other aberrations such as output ripple voltage, which is inherent to any pulse-width modulator. A distinction is made between DC and AC errors. The latter are divided into synchronous and asynchronous output voltage disturbances. Synchronous AC errors are composed of the switching frequency and its harmonics.
The contribution presents a methodological procedure for the management and planning of interventions after earthquake events in small historic centres. Reference is made to the case study of Castelluccio di Norcia, a village in the Apennine Mountains affected by the seismic sequence that hit Central Italy in 2016. The earthquake risk of the area and the damaging events of 2016 are critically reviewed. The implementation of cognitive analysis and the application of advanced survey techniques involving the use of nmanned Aerial Vehicles (UAVs) for the purposes of emergency management and monitoring of damaged areas are analysed. The outcomes, combined with the direct involvement of the local population, represent a complete and integrated approach allowing the definition of a) possible intervention strategies, b) related decision criteria and c) practical recommendations for the reconstruction and regeneration of Castelluccio, and, in general, of small historic centres damaged by catastrophic events.
Als fairer Beitrag Deutschlands zur Einhaltung der globalen 1,5-Grad-Grenze werden 16 Orientierungspunkte für eine klimaverträgliche Energieversorgung vorgestellt. Es wird davon ausgegangen, dass hierfür die deutschen energiebedingten CO2-Emissionen in etwa 15 Jahren weitgehend auf Null sinken müssen. Energieeinsparung hilft, den notwendigen Ausbau von regenerativen Erzeugungskapazitäten zu verringern. Der Verkehrssektor kann ebenso wie die Bereiche Prozess- und Gebäudewärme hierzu wesentlich beitragen. Die Kernenergie ist mit großen Risiken belastet und kann nicht hinreichend schnell aufgebaut werden. Biomasse in Form von Energiepflanzen zu nutzen, ist ineffizient und steht im Konflikt mit anderen Arten der Landnutzung. Importe klimaneutral erzeugter Energieträger in sehr großem Umfang erfordern extrem große Investitionen im Ausland. Sie sind eine ungesicherte Option auf die Zukunft.
Entscheidend ist daher der ausreichend schnelle Ausbau von Photovoltaik (PV) und Windkraft in Deutschland. Schätzungsweise kann der Elektrizitätsbedarf im Jahr 2030 z.B. durch den Ausbau auf ca. 350 GW PV und ca. 150 GW Windkraft nahezu vollständig regenerativ gedeckt werden. Damit ließe sich eine zum großen Teil elektrifizierte Mobilität und Wärmeversorgung betreiben und ein Teil des benötigten "grünen" Wasserstoffs in Deutschland bereitstellen. Hierfür ist ein jährlicher Zubau von durchschnittlich ca. 30 GW PV und ca. 9 GW Windkraft nötig. Dies ist ca. sechs- (PV) bzw. dreimal (Wind) so hoch wie bisher vorgesehen und verlangt eine gesellschaftliche Kraftanstrengung. Ein weiter verzögerter Ausbau müsste mit noch deutlich größeren gesellschaftlichen Anstrengungen für drastische Energieeinsparungen oder Importe erneuerbarer Energie ausgeglichen werden. Insgesamt könnte dies noch deutlich schwieriger zu realisieren sein, als ein ambitionierter Ausbau. Da der Aufbau der Kapazitäten mehrere Jahre erfordert, ist es möglich nachzusteuern, z. B. wenn erkennbar wird, dass sich ein ausreichend großer globaler Markt für Importe entwickelt. Bis dahin ist es aus Verantwortung gegenüber der Zukunft und im Sinne des Pariser Vertrages empfehlenswert, die hier genannten Ausbauziele zu verfolgen.
Grüner, also aus erneuerbaren Energien hergestellter Wasserstoff und daraus abgeleitete Syntheseprodukte sind für die Dekarbonisierung von Industrieprozessen, den Flug- und Schiffsverkehr sowie für die Absicherung der Energieversorgung bei Dunkelflauten nötig. Ohne die genannten Ausbauziele für Wind und Solar noch drastisch weiter zu erhöhen, stehen diese Produkte für Straßenverkehr und Wärmeversorgung jedoch nicht in ausreichenden Mengen zur Verfügung. Techniken zum Ausgleich zwischen Elektrizitätsangebot und -nachfrage sind verfügbar und sollten rechtzeitig auf- bzw. ausgebaut werden. Hierzu gehören: Stromaustausch mit den Nachbarländern, Flexibilisierung des Verbrauchs und Energiespeicherung. Für deren Integration sowie den Ausbau der Netze sollten zügig verbesserte rechtliche Rahmenbedingungen geschaffen werden.
Die Kosten eines klimaverträglichen Energiesystems sind mittel- bis langfristig nicht höher als im derzeitigen System. Gleichzeitig entstehen Arbeitsplätze und Exportchancen durch Aufbau, Betrieb und Wartung einer regenerativen Energieversorgung in Deutschland und die energetische Gebäudesanierung. Die politischen Rahmenbedingungen entscheiden, ob eine klimaverträgliche Energieversorgung Deutschlands gelingt.
This paper presents different options to provide reactive power in electricity grid systems. Since conventional power plants are being phased out and the reactive power demand tends to increase, alternative technologies are needed to cover it. reactive power sources are being defined and specified in this submission. A technical evaluation and an economic analysis of selected reactive power sources are carried out, based on interviews with manufacturers and operators. As well a multifactorial techno-economic comparison of the evaluated reactive power sources is presented. The technical analysis addresses reactive power control-ranges, stochastic parameters, lifespans, electrical losses and dynamics of re-active power sources. It states that power electronics allow faster setpoint changes than mechanical technologies can achieve, but at the same time this is associated with the highest electrical losses of the reactive power sources considered here. Considering the economic analysis, relative investment costs per reactive power of conventional compensation systems turn out to be the most cost-efficient. With regard to the multifactorial techno-economic comparison, it is im-portant not only to standardize on reactive power that can be provided, but also to include the additional system-relevant properties of technologies in the evaluation as well as the costs in operation.
In this paper a multiphysics development method is used for designing a novel wound field synchronous machine of the future generation of high voltage traction drives. This method covers the domains of electromagnetics, the mechanical strength, thermal behavior and the magnetic noise. It is shown that the proposed novel asymmetric design with a circular flux barrier in combination with an asymmetric pole offset is fulfilling the requirements according to performance and torque ripple. A fatigue strength rotor mechanic concept is included. A hybrid cooling concept consisting of a water jacket cooled stator and air cooled rotor ensures the needed continuous power. Unacceptable noise levels are excluded by investigating the equivalent radiated power (ERP) level due to radial forces in the air gap. Finally, the multi-physical workflow resulted in a fully developed component with a high degree of maturity.
This paper shows how magnetic noises can be reduced with a wound field synchronous machine (WFSM) with magnetic
asymmetry compared to a permanent magnet synchronous machine (PSM), operating at base speed range and full load. In order to reproduce a real noise behavior, the two rotor types are operated in a complete electric drive unit (EDU) consisting of an electric motor, gearbox, inverter and overall housing. In the concept study, the noise characteristics of the two electric machines is evaluated and compared via mechanical finite element method (FEM) simulations using the equivalent radiated power (ERP) level and Campbell diagrams. Furthermore, it is shown that critical frequency orders can already be identified by the analysis of the magnetic force density from the electromagnetic design without computationally intensive ERP calculations. In this context, the ERP investigations have shown that the unique feature of the magnetically asymmetric WFSM is the reduction of the slot harmonics. At the current state of the art, the slot harmonics can only be reduced with a rotor skewing. The disadvantage of this is a reduction in performance and a more expensive production. It is also remarkable that the magnetic asymmetry reduces the slot harmonics more than the rotor skewing in the PSM. In addition, both machines are still considered with a short-pitched stator winding to optimize the overall noise level by reducing the 24th frequency order.
A prototype of a thermal insulation system to offer high selectivity of the solar gain regarding the solar incidence angle (SATIS) was applied to a typical solid brick masonry for existing buildings in Germany. Light conducting elements (LCEs) inclined at 19 ° were incorporated in SATIS, which equals the average solar noon angle in southern Germany during winter. The entire wall construction was experimentally investigated in a differential climatic chamber test bench at four different irradiation angles according to a dynamic test procedure. In addition, a conventional wall construction (CWC) has been measured. At SATIS’ design angle of 19 °, the SATIS wall construction shows a solar gain (SG) of 394.5 Wh/m², while the SG of the CWC amounts to only 25.4 Wh/m². The validated transient model of the SATIS wall construction showed that, at the end of the irradiation period of the dynamic test procedure (8 h), the solar heat penetrates to a depth of 253 mm and 111 mm inside the 385 mm thick brick wall masonry at the irradiation angles of 19 ° and 50 °, respectively. During the same time, the stored solar energy at 50 ° amounts to only 24.4 % of that stored at 19 °.
Das übergeordnete Ziel des Vorhabens war die Entwicklung neuer technologischer Möglichkeiten für den biologischen Methanisierungsprozess mit Archaeen1 in Power-to-Gas-Anwendungen. Im Gegensatz zur technisch ausgereiften chemisch-katalytischen Methanisierung sind hier noch Potenziale zur Optimierung verfahrenstechnischer und biologischer Prozesse für das Speicherkonzept Power-to-Gas [7] vorhanden.
Dabei sollte zum einen ein Rieselbett-Bioreaktor optimiert, simuliert und für die Hochskalierung vorbereitet werden. Zum anderen sollte eine Kombination optimal geeigneter Mikroorganismen und Packungsmaterialien selektiert und deren Verhalten und Eignung im Reaktor analysiert werden. Das Verhalten des entwickelten Systems sollte zunächst im Labor- und Technikumsmaßstab und anschließend im Feldtest an einer bestehenden Power-to-Gas-Anlage untersucht werden. Hauptziel während des Feldtests war die Produktion von einspeisefähigem Methan sowie dessen Einspeisung ins Gasnetz.
Ein Hauptziel des Projektes war es, die Normung und Standardisierung notwendiger Systemparameter und Semantik zur Beschreibung und Einbindung biologischer Methanisierungseinheiten in Power-to-Gas-Anlagen voranzutreiben. Dies sollte zum einen die Vergleichbarkeit der wissenschaftlichen Erkenntnisse verbessern und zum anderen unterstützend bei der Kommerzialisierung der Technologie wirken. Aus dem Projekt heraus wurde so die neue Normungsreihe VDI 4635 Power-to-X beim Verein Deutscher Ingenieure angestoßen.
Electric vehicles are one of the important components of the energy transition, which is necessary for the CO2 emission reduction. In order to estimate the influence of electromobility on electric grids at present day and in the future, the generation of realistic charge profiles is necessary. The main objective of this study is the development of an algorithm, which generates realistic charge time series of electric vehicles. The very huge and detailed input surveys enable to define different population groups, representing specific driving behaviour. These groups are then composed and scaled up, according to the statistical population structure of a chosen town or city in Germany, and show typical driving behaviour of all inhabitants. The charge profiles are calculated for several charge station types, based on daily electric vehicle user mobility, day type and household type. In addition, charge process occurrence is evaluated through a model, involving charge infrastructure presence, attractiveness of corresponding charge station type and charge process necessity.
The ORBIT-Project: Biological methanation in a trickle-bed reactor - key results and next steps
(2021)
The development of new technologies like advanced driver assistance systems or automated driving requires a flexible simulation environment of sufficient complexity. In general this flexibility is not provided by commercial software packages. This paper presents a three-dimensional and nonlinear hand-made model for heavy commercial vehicles including tractor and trailer as well as tractor and semitrailer combinations that can be used in different simulation environments, as well as in real-time applications. As typical for trucks, the torsional flexibility of the frame and a suspended driver's cabin are taken into account. The design kinematics makes it possible to handle different and quite complex axle suspensions very efficiently. Appropriate force elements are used to model various couplings between tractor and trailer or tractor and semitrailer, respectively. The virtual test truck environment (VTT) coded in ANSI C is extremely portable and can easily be embedded in commercial simulation packages like MATLAB/Simulink. It includes the TMeasy tyre model and offers flexible interfaces to third-party software tools.
Axles with leaf spring suspension systems are still a popular choice in many commercial vehicles. However, leaf springs are not in perfect conformity to standard multibody vehicle models because they combine guidance and suspension in one single element. Combining standard multibody vehicle models with sophisticated finite element leaf spring models results in rather complex and computing time-consuming solutions. Purely kinematic models, defined by lookup tables or the design kinematics approach, cover only some but not all features of the leaf spring suspension. As shown here, the five-link model, which incorporates a quasi-static solution of the leaf spring compliance, provides a very practical model. It is comparatively lean and provides results of sufficient accuracy in the whole application range.
The present work aims at the thermodynamic analysis of different working pairs in adsorption heat transformers (AdHT) for low-temperature waste heat upgrade in industrial processes. Two different AdHT configurations have been simulated, namely with and without heat recovery between the adsorbent beds. Ten working pairs, employing different adsorbent materials and four different refrigerants, have been compared at varying working boundary conditions. The effects of heat recovery and the presence of a temperature gradient for heat transfer between sinks/sources and the AdHT components have been analyzed. The achieved results demonstrate the possibility of increasing the overall performance when internal heat recovery is implemented. They also highlight the relevant role played by the existing temperature gradient between heat transfer fluids and components, that strongly affect the real operating cycle of the AdHT and thus its expected performance. Both extremely low, i.e., 40-50 degrees C, and low (i.e., 80 degrees C) waste heat source temperatures were investigated at variable ambient temperatures, evaluating the achievable COP and specific energy. The main results demonstrate that optimal performance can be achieved when 40-50 K of temperature difference between waste heat source and ambient temperature are guaranteed. Furthermore, composite sorbents demonstrated to be the most promising adsorbent materials for this application, given their high sorption capacity compared to pure adsorbents, which is reflected in much higher achievable specific energy.
In this study, a fully automated process converting hydrogen and carbon dioxide to methane in a high temperature trickle-bed reactor was developed from lab scale to field test level. The reactor design and system performance was optimized to yield high methane content in the product gas for direct feed-in to the gas grid. The reaction was catalyzed by a pure culture of Methanothermobacter thermoautotrophicus IM5, which formed a biofilm on ceramic packing elements.
During 600 h in continuous and semi-continuous operation in countercurrent flow, the 0.05 m3 reactor produced up to 95.3 % of methane at a methane production rate of 0.35 mCH43mR-3h-1. Adding nitrogen as carrier gas during startup, foam control and dosing of ammonium and sodium sulfide as nitrogen and sulfur source were important factors for process automation.
All known locomotion principles are limited respective to environmental conditions. Often, the occurrence of obstacles or gaps means the break-off for the operating motion systems. For such circumstances, a controllable jumping locomotion is required to cross these barriers. However, this locomotion demands sophisticated requirements to the actuation. The abrupt actuation is commonly realized by high dynamic actuators or complex mechanisms. In this work, a simple solution utilizing the multistability of a compliant tensegrity structure is described. Therefore, a two-dimensional tensegrity structure featuring four stable equilibria is considered. Based on bifurcation analyses a feasible actuation to control the current equilibrium configuration is derived. Changing between selected equilibrium states enables a great difference in potential energy, which yields a jumping motion of the structure. Based on numerical simulations a suitable actuation strategy is chosen to overcome obstacle and steps by jumping forward or backward, respectively. The theoretical approach is examined experimentally with a prototype of the multistable tensegrity structure.
(c) 2020 Elsevier Ltd. All rights reserved.
All known locomotion principles are limited respective to environmental conditions. Often, the occurrence of obstacles or gaps means the break-off for the operating motion systems. For such circumstances, a controllable jumping locomotion is required to cross these barriers. However, this locomotion demands sophisticated requirements to the actuation. The abrupt actuation is commonly realized by high dynamic actuators or complex mechanisms. In this work, a simple solution utilizing the multistability of a compliant tensegrity structure is described. Therefore, a two-dimensional tensegrity structure featuring four stable equilibria is considered. Based on bifurcation analyses a feasible actuation to control the current equilibrium configuration is derived. Changing between selected equilibrium states enables a great difference in potential energy, which yields a jumping motion of the structure. Based on numerical simulations a suitable actuation strategy is chosen to overcome obstacle and steps by jumping forward or backward, respectively. The theoretical approach is examined experimentally with a prototype of the multistable tensegrity structure.
The growing efforts for the development of clean and efficient energy systems require the use of a multi-disciplinary approach and the integration of multiple generation appliances. Among the fields that can be considered enabling technologies, adsorption systems for air conditioning and thermal energy storages, are constantly increasing their maturity. However, for a proper design and integration of such systems, there is the need for a simulation framework that is reliable and computationally convenient. In the present paper, the implementation of a dynamic model for adsorption systems is presented, which includes different components (adsorber, phase changer, sorption materials) and is structured as a library. Modelica language and the commercial software Dymola (R) are used for the analysis. Data for different heat exchangers and working pairs are calibrated using experimental results and the calibrated model is subsequently used for the design of an adsorber based on a plate heat exchanger for thermal energy storage applications. The results proved that the model is fast and can reproduce experimental results with good accuracy, thus being a useful tool for the design and optimization of the different components of sorption systems.
What commonalities are there in sustainable or unsustainable heating practices in five high-income, high-emitting western European countries? What preferences do a nationally representative sample of the public in these countries hold towards low-carbon options? It is imperative that climate policy researchers and practitioners grapple with the difficulty of decarbonizing heat, which remains the largest single end-use service worldwide and which accounts about half of total final energy consumption. Based on a comparative assessment of five representative national surveys in Germany (N = 2009), Italy (N = 2039), Spain (N = 2038), Sweden (N = 2023), and the United Kingdom (N = 2000), this study explores the demographics and geography of household heat decarbonisation in Europe. By analyzing our country level data as well as our combined sample of 10,109 respondents, it investigates how people conceive of the purposes of low-carbon heat, their preferences for particular forms of heat supply, and their (at times odd) practices of heat consumption and temperature settings. Grounded in its original data, the study organizes its findings inductively across the five themes of literacy (heating knowledge, awareness and control), sustainability (heating practices, dynamics and conflicts), temperature (heating satisfaction and preferences), desirability of change (low-carbon heating priorities, business models and trust), and culture (country and national variation). The study also explores intersections between these dimensions, using multivariate analysis, as well as how preferences differ according to varying types of actors as well as geography and space.
The objectives of this work include the analysis of electrical and magnetic properties of magneto-elastic hybrid materials with the intention of developing new techniques for sensor and actuator applications. This includes the investigation of dielectric properties at both low and high frequencies. The behaviour of capacitors whose dielectrics comprise magnetic hybrid materials is well known. Such interfacial magnetocapacitance can be varied according to magnetic content, magnetic flux density and the relative permittivity of the polymer matrix together with other dielectric content. The basic function of trapping electrical charges in polymers (electrets) is also established technology. However, the combination of magnetoactive polymers and electrets has led to the first electromagnetic device capable of adhering to almost any material, whether magnetically susceptible or not. During the course of this research, in addition to dielectrics, electrically conductive polymers based on (PDMS) matrices were developed in order to vary the electrical properties of the material in a targeted manner. In order to ensure repeatable results, this demanded new fabrication techniques hitherto unavailable. The 3D printing of silicones is far from being a mature technology and much pioneering work was necessary before extending the usual 3 d.o.f. to include orientation about and diffusion of particles in these three axes, thus leading to the concept of 6D printing. In 6D printing, the application of a magnetic field can be used during the curing process to control the particulate distribution and thus the spatial filler particle density as desired. Most of the devices (sensors and actuators) produced by such methods contain levels of carbonyl iron powder (CIP) embedded magnetic filler of up to 70 wt%. Contrary to this, a hitherto neglected research area, namely magnetoactive polymers (MAPs) having significantly lower magnetic particle concentrations (1 to 3 wt% CIP) were also investigated. With filler concentrations lower than 3 wt%, structures are formed which are completely absent at higher filler levels. CIP concentrations in the range of 1wt% demonstrate the formation of toroidal structures. Further development of coherent rings with a compact order results as filler concentrations increase towards 2 wt%. Above 3 wt% the structure eventually disintegrates to the usual random order found in traditional MAP with higher CIP content. Structured samples containing 1%–3 wt% CIP were investigated with the aid of X-ray tomography where solitary ring structures can be observed and eventually the formation of capillary doubles. Over wavelengths ranging from 1 to 25 µm, spectroscopic analysis of thin film MAP samples containing 2 wt% CIP revealed measurable magnetic-field-dependent changes in IR absorption at a wavenumber 2350 (λ = 4.255 µm). This was found to be due to the diamagnetic susceptibility of atmospheric carbon dioxide (CO2). Consequently, the first potential application for sparse matrix MAPs was found.
To reduce particulate emissions, the use of particulate filters in diesel engines is meanwhile state of the art, while the integration of such systems in gasoline engines is now also necessary in order to comply with today's regulations. Over its lifetime, a gasoline particulate filter (GPF) collects ash components of fuel, lubrication oil, and materials originating from the catalytic coating and from engine abrasion. In the development and application process, synthetic ashing from GPFs is challenging. The ash of the lubrication oil can be increased in various ways, like oil-doped fuel, a separate oil burner, or changes in the piston-cylinder system of the engine. However, these methods show major disadvantages. For this reason, an improved approach is presented in this study, which allows a quick response to changes in combustion (e.g., engine knocking) and producing ash, which is more realistic due to its primary particle size and the density of ash plugs, in a shorter time. Therefore, an approach to accelerate ash loading by active oil injection using a multi-point injection (MPI) system is introduced. With the help of this methodology, an ashing capacity of 1.21 g/h is implemented, which is a high rate compared to other investigations. The primary particle size (evaluated by means of a transmission electron microscope), is in the same size range as those detected at the full-load curve during regular operation. A computer tomographic (CT) analysis of the incinerated particulate filter also shows that a very high density of ash plugs can be realized, which has also been found in the literature for real applications. In addition, with the help of a mass spectrometer (MS) and an intermediate weighing of the particulate filter, the current ash loading of the GPF could be determined with an accuracy of 1%.
In order to function as soft actuators, depending on their field of use, magnetorheological elastomers (MREs) must fulfill certain criteria. To name just a few, these can include rapid response to external magnetic fields, mechanical durability, mechanical strength, and/or large deformation. Of particular interest are MREs which produce macroscopic deformation for small external magnetic field variations. This work demonstrates how this can be achieved by just a small change in magnetic field orientation. To achieve this, (super)paramagnetic nickel particles of size ≈ 160 μm were embedded in a non-magnetic polydimethylsiloxan (PDMS) (661–1301 Pa) and their displacement in a stepwise rotated magnetic field (170 mT) recorded using a video microscope. Changes in particle aggregation resulting from very small variations in magnetic field orientation led to the observation of a new strongly magneto-active effect. This configuration is characterized by an interparticle distance in relation to the angle difference between magnetic field and particle axis. This causes a strong matrix deformation which in turn demonstrates hysteresis on relaxation. It is shown that the occurrence strongly depends on the particle size, particle distance, and stiffness of the matrix. Choosing the correct parameter combination, the state can be suppressed and the particle-matrix system demonstrates no displacement or hysteresis. In addition, evidences of non-negligible higher order magnetization effects are experimentally ascertained which is qualitatively in agreement with similar, already theoretically described, particle systems. Even at larger particle geometries, the new strongly magneto-active configuration is preserved and could create macroscopic deformation changes.
Avoiding ice accumulation on aerodynamic components is of enormous importance to flight safety. Novel approaches utilizing surface dielectric barrier discharges (SDBDs) are expected to be more efficient and effective than conventional solutions for preventing ice accretion on aerodynamic components. In this work, the realization of SDBDs based on thin-film substrates by means of micro-electro-mechanical-systems (MEMS) technology is presented. The anti-icing performance of the MEMS SDBDs is presented and compared to SDBDs manufactured by printed circuit board (PCB) technology. It was observed that the 35 mu m thick electrodes of the PCB SDBDs favor surface icing with an initial accumulation of supercooled water droplets at the electrode impact edges. This effect was not observed for 0.3 mu m thick MEMS-fabricated electrodes indicating a clear advantage for MEMS-technology SDBDs for anti-icing applications. Titanium was identified as the most suitable material for MEMS electrodes. In addition, an optimization of the MEMS-SDBDs with respect to the dielectric materials as well as SDBD design is discussed.
Zünd- und Brennverhalten von Pflanzenölkraftstoff und Übertragung auf einen Motor der Abgasstufe V
(2020)
Durch den Ersatz von Dieselkraftstoff durch Rapsölkraftstoff (R100) können Treibhausgasemissionen reduziert werden. Für einen störungsfreien Betrieb eines Motors mit Rapsölkraftstoff sind jedoch Modifikationen an Motorkomponenten und Motorsteuergerät notwendig, um eine effiziente Verbrennung im Motor zu erreichen.
Ziel des Vorhabens ist die Erarbeitung von Grundlagen zur Auslegung der Motorsteuerung pflanzenöltauglicher Offroad-Motoren mit moderner Abgasnachbehandlung mit anschließender entsprechender Abstimmung der Motorapplikation am Prüfstand. Grundlegende Untersuchungen der physikalischen Prozessabläufe von R100 bei der Einspritzung werden an einem hydraulischen Druckanstiegsanalysator (HDA) und einer Hochdruck-Hochtemperatur-Kammer (HDHT-Kammer) durchgeführt. Unterschiede im Zünd- und Brennverhalten werden in einer Konstantvolumenbrennkammer untersucht. Abschließend werden die Erkenntnisse am Motorenprüfstand auf einen DEUTZ-Motor übertragen, dessen Einspritzsystem auch bei den grundlegenden Untersuchungen verwendet wurde.
Die Ergebnisse zeigen, dass das Einspritzverhalten von R100 eine höhere Sensitivität gegenüber Kraftstofftemperaturvariationen aufweist als Dieselkraftstoff. Bei niedrigen raftstofftemperaturen sind mit R100 ein längerer Öffnungsverzug und eine geringere Einspritzmenge festzustellen. Um diesen Einfluss bei der Einspritzstrategie zu kompensieren, ist die Kenntnis der Kraftstofftemperatur im Injektor notwendig. Eine weitere Herausforderung stellt die Gemischaufbereitung dar, hier führen unter anderem die höhere Viskosität und höhere Siedetemperaturen von R100 zu einem schmäleren Spritzwinkel und verzögerter Verdampfung im Vergleich zum Dieselkraftstoff. Eine Erhöhung des Einspritzdrucks und höhere Temperaturen und Drücke in der Brennkammer verbessern die Gemischaufbereitung.
Bei Bedingungen von mittlerer und hoher Last ist der Zündverzug von R100 kürzer und das Verbrennungsverhalten ähnlich zum Dieselkraftstoff. Eine geringere Wärmefreisetzung von R100 wird durch den geringeren Heizwert verursacht. Unter Bedingungen von niedriger Last und Motorstart ist ein längerer Zündverzug von R100 im Vergleich zum Dieselkraftstoff festzustellen. Eine Steigerung des Einspritzdrucks und höhere Brennkammerdrücke und -temperaturen führen bei beiden Kraftstoffen zu kürzeren Zündverzügen, der Einfluss dieser Parameter ist jedoch für R100 stärker als für Dieselkraftstoff. Voreinspritzungen führen bei beiden Kraftstoffen zu einer Verkürzung des Zündverzugs der Haupteinspritzung und zu einer geringeren Wärmefreisetzungsrate.
Am Motorprüfstand ist bei gleicher Motorapplikation mit R100 eine geringere Leistung als mit Dieselkraftstoff festzustellen. Nach Angleichung der Motorleistung durch Anhebung der Einspritzmenge von R100 sind im Rohabgas Stickstoffoxid (NOX)- und Kohlenstoffmonoxidemissionen auf gleichem Niveau zu Dieselkraftstoff zu beobachten sowie geringere Partikelemissionen. Unter Verwendung eines DoE Vorgehens kann der Partikel-NOX - trade-off von R100 optimiert und Einstellparameter gefunden werden, in denen sowohl niedrigere NOX als auch niedrigere Partikelemissionen im Vergleich zum Dieselkraftstoff resultieren.
Das installierte Abgasnachbehandlungssystem, bestehend aus einem Dieseloxidationskatalysator (DOC), Dieselpartikelfilter (DPF) und selektivem katalytischem Reduktionssystem (SCR), arbeitet für beide Kraftstoffe ähnlich und es scheint keine Anpassung der Dosierungsstrategie der wässrigen Harnstofflösung notwendig zu sein. Eine Regeneration des Partikelfilters mit R100 war nach Optimierung der Einstellparameter der Drosselklappe möglich.
Motorkaltstart und Leerlauf sind herausfordernde Betriebsphasen, die für R100 einer weiteren Optimierung bedürfen. Eine Temperierung von R100 im Injektor auf 50–60 °C sowie eine Kompensation der Einspritzmenge in Abhängigkeit von der Kraftstofftemperatur sind mögliche Verbesserungsmaßnahmen. Zudem kann durch einen früheren Einspritzbeginn von R100 das Verbrennungsverhalten angepasst werden. Die Motorprüfstandsuntersuchungen bestätigen qualitativ die Erkenntnisse die mit dem hydraulischen Druckanstiegsanalysator (HDA), der Hochdruck-Hochtemperatur-Kammer (HDHT-Kammer) und der Konstantvolumenbrennkammer gewonnen wurden.
Weitere Untersuchungen sind notwendig, um die Ergebnisse auf einen baugleichen, in einer mobilen Arbeitsmaschine eingebauten Motor zu transferieren, damit Informationen zur Dauerhaltbarkeit unter realen Bedingungen erhalten werden können. Weiterführende Forschungsarbeiten sind im Bereich der Betriebsphasen des Motorkaltstarts und Leerlaufs mit Rapsölkraftstoff nötig, um einen dauerhaft störungsfreien Betrieb in diesen Betriebsphasen zu erreichen. Die erzielten Erkenntnisse deuten darauf hin, dass hier noch viel Verbesserungspotenzial vorhanden ist.
Tonal components can be regarded as one of the most relevant components for interior sound quality of electric vehicles, especially at low speeds. Sources for these tones are for example the vehicles' drivetrains but also other technical components. Depending on the driving conditions, due to the interaction of various dominant sources, audible tone complexes can occur. Similar to musical intervals, the different frequency ratios within these complexes can result in consonant or dissonant sensations. The strength of this sensation does not only depend on the frequency relation of the tones but also on their relative levels. In this study, different musical intervals were subjectively rated in terms of their specific consonant or dissonant character. Using an adaptive procedure, sound pairs, each consisting of a two-tone signal, where adjusted to equal dissonance by varying the level of the second tone of one of the two-tone signals. Using the same paradigm, also pairs of equal vehicle sound quality were obtained. With these results, it is possible to quantify dissonance, and theinfluence of dissonance on sound quality expressed in terms of level differences of two-tone signals. These results can help to make the concept of dissonance more useful for sound-engineering applications.
In Folge der Verschärfung der gesetzlichen Abgasnormen wurden für direkt-einspritzende Benzinmotoren Partikelfilter notwendig. Zur Beladungsüberwachung können aufgrund stark unterschiedlicher Rahmenbedingungen die aus Dieselmotoren bekannten Systeme, wie dem Differenzdrucksensor, nur eingeschränkt übernommen werden. Ein hochfrequenzbasiertes Verfahren koppelt mittels Antennen elektromagnetische Wellen in das Filtergehäuse ein, deren Ausbreitungsverhalten durch die dielektrischen Eigenschaften des eingelagerten Rußes beeinflusst wird. Hierdurch kann bei Auswertung von Transmissionsdämpfung oder Resonanzfrequenzen die Rußbeladung direkt detektiert werden.
In order to comply with future emission regulations, the use of particulate filters in vehicles with direct injection gasoline engines is essential. The current amount of soot and ash in the filter is calculated by a soot load model in the electronic control unit in combination with a differential pressure sensor determining the pressure drop over the particulate filter. Active regeneration is initiated if the calculated amount of soot or the measured differential pressure is too high. This is associated with additional fuel consumption. An on-board diagnosis for the particulate filter is currently not part of the Euro 6d emission standard. For future exhaust emission standards, on-board diagnosis or active monitoring of the particulate filter is conceivable. One of the benefits of monitoring is the fact that unnecessary active regenerations can be avoided. As a result, there is no additional fuel consumption due to misinterpretations of the amount of soot in the filter. For active monitoring of the particulate filter, a radiofrequency (RF-) sensor, that detects the soot loading of the filter with electromagnetic waves directly, can be used. Such a system has the advantage that by utilizing the filter as a sensor more precise information about the current state of the filter, e.g. a possible damage, can be provided. Worst-case considerations of filter damages, tested at an engine test bench show the advantages which are entailed by a system like that. By means of partial regeneration of the particulate filter it is demonstrated how the remaining amount of soot in the filter can be detected in a better way in comparison to the differential pressure sensor by using the RF-sensor.
Die Richtlinie VDI 2500 „Faserseile“ hat 1990 erstmals zusammenfassend den Stand der Technik auf dem Gebiet der Faserseile dargestellt und wertvolle Infor-mationen über Aufbau, Auswahl, Konfek-tionierung und Überwachung von Faser-seilen gegeben. Die jetzt erscheinende zweite Auflage enthält eine Vielzahl wichtiger technischer Neuerungen für die Praxis. Zu nennen sind hier die hochfesten Fasern und deren Beschichtung sowie die erstmals systematisch aufgeführten Sei-lendverbindungen und ein Ausblick auf die zukünftig bedeutsamen sogenannten Hybridseile. Eine Checkliste hilft bei der richtigen Auswahl und Bemessung von Faserseilen. Bei den Normen wurde – soweit möglich – auf europäische Normen verwiesen.