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The successful market penetration of modern absorption heat pumps (AHP) today is critically dependent on their thermodynamic performance as well as other key factors like cost, reliability and inherent safety. Conventional AHPs have a proven record in the first two aspects but crucial shortcomings in the last two. For this reason it has been imperative to search for alternative working pairs that could potentially provide comparable performance while also satisfying the rest of the conditions to the best extent possible. As part of a systematic approach towards this direction, a detailed cycle analysis was performed, utilizing an idealized AHP system containing a real working pair, which enabled the identification of five dimensionless parameters and key thermophysical properties that influence the system's thermodynamic efficiency and the circulation ratio. In order to validate those findings, these parameters were calculated and compared between conventional and alternative AHP refrigerants. It turned out that low molecular weight ratios between absorbent and refrigerant have a beneficial effect on both coefficient of performance and the circulation ratio. Furthermore, both the refrigerant acentric factor and the absorbent vaporization enthalpy shall be minimized to obtain better performance. (C) 2016 Elsevier Ltd. All rights reserved.
The frequencies of ambient vibrations are often low (below 30 Hz). A broadband (3 dB bandwidth is larger than 10 Hz at an acceleration amplitude of 9.81 m s(-2)) vibration based energy harvester is proposed for transducing mechanical energy at such low frequencies into electrical energy. The mechanical setup converts low frequency mechanical vibrations into high frequency resonance oscillations of the transducer. This conversion is done by mechanical impacts on two mechanical stoppers. The originality of the presented design is that both low-frequency and high-frequency oscillators are permanently mechanically coupled. In the equivalent mechanical circuit, this coupling is achieved by connecting the ends of the stiff spring to both seismic masses, whereas one seismic mass (collison member) is also attached to the soft spring used as the constitutive element of a low-frequency oscillator. Further, both mechanical oscillators are not realized as conventional cantilever beams. In particular, the high frequency oscillator with the natural frequency of 340 Hz is a disc-shaped diaphragm with attached piezoelectric elements and a seismic mass. It is shown that it is possible to convert mechanical vibrations with acceleration amplitude of 9.81 m s(-2) in the region between approximately 7 and 25 Hz into electrical power larger than 0.1 mW with the maximum value of 0.8 mW. A simplified mathematical model based on piecewise linear coupled oscillators shows good agreement with experimental results. The ways to enhance the performance of the harvester and improve agreement with experiments are discussed.
In the present work, an experimental study on a lab-scale adsorption refrigerator, based on activated carbon/ethanol working pair is reported. An extensive testing campaign has been carried out at the CNR ITAE laboratory, with multiple aims. First, the performance has been evaluated in terms of both COP and Specific Cooling Power (SCP), under different boundary conditions, including both air conditioning and refrigeration applications. Attractive SCPs, up to 180 W/kg and 70 W/kg for air conditioning and refrigeration, respectively, were measured. Under the same conditions, COP between 0.17 and 0.08 were obtained. In addition, different management strategies, namely, heat recovery between adsorbers and re-allocation of phase durations, were evaluated to identify their influence on the system. Both strategies confirmed the possibility of increasing COP and SCP up to 40% and 25%, respectively. Moreover, a design analysis based on the experimental results has been carried out, to suggest possible improvements of the system. The obtained results demonstrated the possibility of employing a non-toxic refrigerant like ethanol reaching performance comparable with other harmful refrigerants like ammonia and methanol. (C) 2017 Elsevier Ltd. All rights reserved.
The flow of superfluid around a translationally oscillating sphere, levitating without mechanical support, can either be laminar or turbulent, depending on the velocity amplitude. Below a critical velocity that scales as and is temperature independent below 1 K, the flow is laminar (potential flow). Below 0.5 K, the linear drag force is caused by ballistic phonon scattering that vanishes as until background damping, measured in the empty cell, becomes dominant for K. Increasing the velocity amplitude above leads to a transition from potential flow to turbulence, where the large turbulent drag force varies as . In a small velocity interval % above , the flow is unstable below 0.5 K, switching intermittently between both patterns. From time series recorded at constant temperature and driving force, the lifetimes of both phases are analyzed statistically. We observe metastable states of potential flow which, after a mean lifetime of 25 min, ultimately break down due to vorticity created by natural background radioactivity. The lifetimes of the turbulent phases have an exponential distribution, and the mean increases exponentially with . We investigate the frequency at which the vortex rings are shed from the sphere. Our results are compared with recent data of other authors on vortex shedding by moving a laser beam through a Bose-Einstein condensate. Finally, we show that our observed transition to turbulence belongs to the class of "supertransient chaos" where lifetimes of the turbulent states increase faster than exponentially.
A huge upheaval emerges from the transition to autonomous vehicles in the domain of road vehicles, ongoing with a change in the vehicle architecture. Many sensors and Electronic Control Units are added to the current vehicle architecture and further safety requirements like reliability become even more necessary. In this paper we present a potential evolution of the Electrical/Electronic-Architecture, including a Zone Architecture, to enable future functionality. We reveal the impact on the communication network concerning these architectures and present a potential communication technology to facilitate such architectures.
Magnetodielectric properties of magnetoactive elastomers comprising micrometer-sized iron particles dispersed in compliant elastomer matrices are experimentally studied in stepwise time-varying dc magnetic fields. It is found that imposition of magnetic field significantly increases both the effective lossless permittivity of these composite materials as well as their effective conductivity. These magnetodielectric effects are more pronounced for larger concentrations of soft-magnetic filler particles and softer elastomer matrices. The largest observed relative change of the effective dielectric constant in the maximum magnetic field of 0.57 T is of the order of 1000%. The largest observed absolute change of the loss tangent is approximately 0.8. The transient response of the magnetodielectric effect to a step magnetic-field excitation can be rather complex. It changes from a simple monotonic growth with time for small magnetic-field steps (<0.1 T) to a non-monotonic behavior with a significant rapidly appearing overshoot for large magnetic-field steps (>0.3 T). The settling time to the magnetic-field step excitation can reach roughly 1000 s and it depends on the applied magnetic field and sample composition. There is also significant hysteresis of the magnetodielectric effect on the externally applied magnetic field. These findings are attributed to the rearrangement of ferromagnetic filler particles in external magnetic fields. The results will be useful for understanding and predicting the transient behavior of magnetoactive elastomers in applications where the control magnetic field is time dependent. (C) 2017 Elsevier Ltd. All rights reserved.
The dynamic shear modulus of magnetoactive elastomers containing 70 and 80 mass % of carbonyl iron microparticles is measured as a function of strain amplitude via dynamic torsion oscillations in various magnetic fields. The results are presented in terms of the mechanical energy density and considered in the framework of the conventional Kraus model. The form exponent of the Kraus model is further related to a physical model of Huber et al. [Huber et al., J. Phys.: Condens. Matter 8, 409 (1996)] that uses a realistic representation for the cluster network possessing fractal structure. Two mechanical loading regimes are identified. At small strain amplitudes the exponent beta of the Kraus model changes in an externally applied magnetic field due to rearrangement of ferromagnetic-filler particles, while at large strain amplitudes, the exponent beta seems to be independent of the magnetic field. The critical mechanical energy characterizing the transition between these two regimes grows with the increasing magnetic field. Similarities between agglomeration and deagglomeration of magnetic filler under simultaneously applied magnetic field and mechanical shear and the concept of jamming transition are discussed. It is proposed that the magnetic field should be considered as an additional parameter to the jamming phase diagram of rubbers filled with magnetic particles.
Wireless sensor networks usually rely on internal permanent or rechargeable batteries as a power supply, causing high maintenance efforts. An alternative solution is to supply the entire system by harvesting the ambient energy, for example, by transducing ambient vibrations into electric energy by virtue of the piezoelectric effect. The purpose of this paper is to present a simple engineering approach for the bandwidth optimization of vibration energy harvesting systems comprising multiple piezoelectric cantilevers (PECs). The frequency tuning of a particular cantilever is achieved by changing the tip mass. It is shown that the bandwidth enhancement by mass tuning is limited and requires several PECs with close resonance frequencies. At a fixed frequency detuning between subsequent PECs, the achievable bandwidth shows a saturation behavior as a function of the number of cantilevers used. Since the resonance frequency of each PEC is different, the output voltages at a particular excitation frequency have different amplitudes and phases. A simple power-transfer circuit where several PECs with an individual full wave bridge rectifier are connected in parallel allows one to extract the electrical power close to the theoretical maximum excluding the diode losses. The experiments performed on two- and three-PEC arrays show reasonable agreement with simulations and demonstrate that this power-transfer circuit additionally influences the frequency dependence of the harvested electrical power.
The influence of an external magnetic field on the static shear strain and the effective shear modulus of a magnetoactive elastomer (MAE) is studied theoretically in the framework of a recently introduced approach to the single-particle magnetostriction mechanism [V. M. Kalita et al., Phys. Rev. E 93, 062503 (2016)]. The planar problem of magnetostriction in an MAE with magnetically soft inclusions in the form of a thin disk (platelet) having the magnetic anisotropy in the plane of this disk is solved analytically. An external magnetic field acts with torques on magnetic filler particles, creates mechanical stresses in the vicinity of inclusions, induces shear strain, and increases the effective shear modulus of these composite materials. It is shown that the largest effect of the magnetic field on the effective shear modulus should be expected in MAEs with soft elastomer matrices, where the shear modulus of the matrix is less than the magnetic anisotropy constant of inclusions. It is derived that the effective shear modulus is nonlinearly dependent on the external magnetic field and approaches the saturation value in magnetic fields exceeding the field of particle anisotropy. It is shown that model calculations of the effective shear modulus correspond to a phenomenological definition of effective elastic moduli and magnetoelastic coupling constants. The obtained theoretical results compare well with known experimental data. Determination of effective elastic coefficients in MAEs and their dependence on magnetic field is discussed. The concentration dependence of the effective shear modulus at higher filler concentrations has been estimated using the method of Pade approximants, which predicts that both the absolute and relative changes of the magnetic-field-dependent effective shear modulus will significantly increase with the growing concentration of filler particles.
An effective way to reduce greenhouse gas emissions (GHGs) is to use rurally produced straight jatropha oil as a substitute for diesel fuel. However, the different physical and chemical properties of straight vegetable oils (SVOs) require a customized setup of the combustion engine, particularly of the injection timing and quantity. Therefore, this study demonstrates the differences in the injection and combustion processes of jatropha oil compared to diesel fuel, particularly in terms of its compatibility with exhaust gas recirculation (EGR).
A 2.2 l common-rail diesel engine with a two-stage turbocharging concept was used for testing. To examine the differences in injection rate shaping of diesel fuel and jatropha oil, the injector was tested with an injection rate analyzer using both the fuels. To investigate the combustion process, the engine was mounted at an engine test bench and equipped with a cylinder pressure indication system. All limited emissions, as well as fuel consumption, were measured.
Various injection strategies, boost and rail pressure levels were tested at different EGR rates in terms of their impact on the combustion process. EGR in particular offers a great potential in the case of jatropha oil combustion due to its oxygen content. In addition, the investigation of injection rate shaping in combination with cylinder pressure analysis allowed a detailed thermodynamic evaluation of the combustion process. Ignition delay (ID) was also analyzed using a new method to calculate the start of combustion (SOC)
Based on a prospective scenario analysis, possible vehicle fleet developments for the individual motor car traffic (vehicle categories N1 and M1) are investigated for Germany in order to determine the long-term vehicle fleet structure, final energy demand, and related carbon dioxide emissions until the year 2050. In this framework, a vehicle fleet model was developed which combines a bottom-up consumer demand model with a dynamic stock-flow approach. Special emphasis is thereby given to different electric power-trains and synthetic gaseous fuels based on the power-to-gas technology. In detail, two different main scenarios are developed and, in addition, the impact of different carbon dioxide taxation levels of fossil fuels on the vehicle fleet structure are analysed. The scenario results reveal a broad range of possible future vehicle fleet structures. In the short to medium timeframe, the internal combustion engine dominates the fleet as a result of efficiency improvements and an increased use of natural gas as automotive fuel. The development of electric power-trains is initially marked by hybrid vehicles, whereas battery electric vehicles dominate the fleet structure in the long-term. Under favourable conditions, also synthetic gaseous fuels are competitive which can reduce carbon dioxide emissions even further.
Exchange conditions at the forest floor are complex due to the heterogeneity of sources and sinks and the inhomogeneous radiation but are important for linking soil respiration to measurements in the trunk space or above canopy. Far more attention has therefore been paid to above and within canopy flows, but even studies that addressed forest floor exchange do not present measurements below 1 m or 2 m. We used a multilayer model that explicitly resolves the laminar layer, the buffer layer, and the turbulent layer to calculate fluxes from the measured profiles in the lowest meter above ground and to calculate effective surface concentrations from given fluxes. The calculated fluxes were compared to measured eddy covariance fluxes of sensible heat and O3 and to chamber derived soil fluxes of CO2 and 222Rn. Sensible heat fluxes agreed surprisingly well given the heterogeneity of radiative heating and the generally low fluxes (max. 25 W m−2). The chamber fluxes turned out to be not comparable as the chamber fluxes were too low, probably due to one of the well-known problems of enclosures such as pressure differences, disturbed gradients and exclusion of naturally occurring turbulence events and surface cooling. The O3 fluxes agreed well for high O3 values reaching down to the forest floor during full coupling of the canopy by coherent structures. During most of the time, the model overestimated the fluxes as chemical reactions were dominating within the profile. One new approach was to calculate the effective surface concentration from a given flux and compare this to measured surface concentrations. This allowed the identification of situations with a coupled and decoupled forest floor layer, which has important consequences for respiration measurements in the trunk space or above canopy and should be considered in upcoming studies.
Power-to-Gas
(2017)
This chapter provides an overview on the storage technology power-to-gas for the decarbonization of all energy sectors. Other than “negative emissions” with CCS or biomass, which have clear limits in potentials, costs and environmental benefits, storage and energy conversion technologies like power-to-gas and power-to-x enable the decarbonization by neutralizing the CO2 footprint of all energy services. Via the conversion of renewable electricity into chemical energy carriers like renewable hydrogen or renewable hydrocarbons, the existing fossil infrastructure with vast and sufficient storage and transport capacities can be used with carbon neutral renewable energy. After showing the demand for storage technologies, the technology components of power-to-gas are described, building the basis for the storage system power-to-gas itself that is described in detail, including efficiency, potential, CO2 emissions, and costs. In conclusion, a technical pathway of decarbonization including costs is described for the industrial nation of Germany and necessary policy frameworks are derived.
Die Autoren dieses Werkes geben einen umfassenden Überblick über die verschiedenen Aspekte der Energiespeicherung. Sie beschreiben zunächst die Bedeutung von Energiespeichern in der Energieversorgung und definieren ihre Rolle darin. Dann gehen sie auf den Speicherbedarf in der Strom-, Wärme- und Kraftstoffversorgung im Kontext der Energiewende ein. Im Hauptteil werden die verschiedenen Speichertechnologien ausführlich vorgestellt sowie ihre Vor- und Nachteile diskutiert. Praktische Anwendungsbeispiele und die Integration von Speichern über alle Energiesektoren hinweg runden das Buch ab. Zahlreiche Grafiken und Beispiele veranschaulichen das gesamte Feld der Energiespeicher und sind als Ergänzung mehrsprachig online in Farbe verfügbar.
Die 2. Auflage enthält ein neues Kapitel zu den rechtlichen Rahmenbedingungen, neue Studien zum Speicherbedarf, Power-to-X für die chemische Industrie, neue LOHC- und Lageenergiespeicher sowie neueste Trends zu Kostenentwicklung und Batterieanwendungen.
„Endlich ein umfassendes Buch zur Energiewende, das auch für technische Laien verständlich und inspirierend geschrieben ist." Franz Alt, Journalist und Buchautor
„Das großartige Werk sei allen empfohlen, die sich wirklich für die Zukunft unseres Landes interessieren. Es zeigt auf eindrucksvolle Weise: Es wird nicht einfach, aber wir schaffen das.“ Prof. Dr. Harald Lesch, Physiker und Fernsehmoderator
Mechanische Energiespeicher
(2017)
The initiated energy transition leads to extensive changes in the supply of energy. The increasing use of renewable energy causes a shift of the produced power from centralized conventional power plants to decentralized energy plants. Because of this redistribution and the related change of load-flows, new challenges and problems for distribution system operators appear. This includes the integration of new loads and plants into the existing power grid and the guarantee of a high supply security and quality. It also includes strengthened requirements for the use and provision of reactive power. The project “SyNErgie” (“Systemoptimierendes Netz- und Energiemanagement für Verteilungsnetze der Zukunft“) deals with the development of a new reactive power management, which gets embedded in grid planning and controlling processes. One focus of the project is on the integration of decentralized energy plants (DEPs) to the reactive power management. The aim is to develop a decentralized and self-sufficient reactive power control system, which only works with local available information (measures). Therefore is no necessity of a complex communication system to the grid control center. Self-controlled Q-controller in the DEPs get characteristic curves and control the reactive power sources with local measurements (e.g. current, voltage, effective power). This new reactive power control management aims for the reactive power compensation in order to increase the integration capacity of loads and plants in a grid [2]. In order to generate characteristic curves for DEPs, it is necessary to analyze the correlation behavior between the local available measurements at the DEPs and the overall-Q-behavior of the grid group at the transformer. In that regard, influencing quantities should be considered. The aim is to involve und evaluate all relevant influencing quantities in order to determine energy plants and certain operating points, in which the correlation behavior and the prediction for the overall-Q-behavior are sufficient. The next step is to develop a model that fits these correlation behaviors and generate characteristic curves. One method to generate characteristic curves for the Q-controllers is regression analysis. The developed Q-control-system with the characteristic curves will be tested, evaluated and optimized in a following field test in cooperation with distribution system operators.