Fakultät Maschinenbau
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- peer-reviewed (6)
Following a ban on many materials containing bisphenol-A, new bisphenol-free Boron silicates have been found as substitutes. The purpose of this study is to describe the mechanical properties of these bisphenol-free magnetoactive borosilicate polymers containing hard magnetic particles. Samples of 0%, 33% and 66% by wt. were loaded for compression using a universal testing machine. The maximum forces occurring for different travel speeds were compared before and after post-magnetization treatments. The post-magnetization included 2 stages. In addition, the change in mechanical properties within 24 hours after the post-magnetization process was investigated. Furthermore, the influence of speed and particle content were investigated. In general, there is a correlation between the required compressive force and, the level of post-magnetization stress, the increase in travel speed and particle content in the boron silicate. Comparison of the non-post-magnetized and post-magnetized samples using two-tailed t-tests shows that the p-values for all weight fraction changes in NdPrFeB particles and travel speeds are less than 0.001. Also, a comparison between tests in which the traverse speed was varied also showed significant changes in the resulting compression forces. The same is valid for changes in the weight ratio of the NdPrFeB particles in the samples. For post-magnetized samples, no significant difference can be observed in the first 24 hours following magnetization. In summary, the material presents viscoelastic, plastic force-displacement behavior, which can be well recognized by its bi-linear curve shape.
The investigation shows that borosilicate polymers based on NdPrFeB can have their mechanical behavior modified and controlled by post-magnetization processes. This opens new possibilities for many future applications.
Field induced plasticity of magneto-sensitive elastomers for gripping technology applications
(2018)
Properties of Polydimethylsiloxane and Magnetoactive Polymers with Electroconductive Particles
(2018)
Magnetoactive polymers are intelligent materials whose mechanical and electrical characteristics are reversibly influenced by external magnetic stimuli. They consist of a highly elastic polymer matrix in which magnetically soft and/or hard particles are distributed by means of special fabrication processes. In addition to ferromagnetic particles such as carbonyl iron powder, electrically conductive particles may also be embedded into the polymer matrix. After characterizing a range of compounds, this work focuses on a comparison of the electrical properties and the suitability of various materials for applications, with particular emphasis on integration into 3D and 6D printing processes. 6D printing is based on the selective positioning of particles in a 3D polymer matrix with a further three degrees of freedom for a graduated dispersion of the particles at certain points and in desired directions. The aim is therefore to ensure that the polymers containing electroconductive tracks have the best possible electrical properties, that is, low resistivity but are still capable of being printed. A comparison between the traditionally used compounds containing graphite and carbon black is made for the first time. This latter is found to be greatly superior both in terms of electrical conductivity and applicability to 3D printing and 6D printing.
Objective:
Magneto-active Polymers (MAP) are smart materials whose mechanical characteristics, such as elastic and shear moduli, may be controllable by means of an externally applied magnetic field.
Methods:
Various additives may be used to influence the characteristics of the polymer matrix whilst a suspension of soft and/or hard magnetic particles determine the magnetic properties of the composite. Both pre-cure and post-cure magnetization is possible.
Results:
A range of control strategies have been investigated for evaluation of the system using fluids of differing kinematic viscosity.
Conclusion:
Depending on the degree of magnetic field homogeneity, magneto-deformation and magnetostriction contribute to MAP actuation. This paper presents a novel application in the form of a peristaltic MAP tube system, applicable to flow control and pumping of hemorheological fluids in blood circulatory systems for biomedical research purposes.
Thermomechanical shape memory materials have certain disadvantages when it comes to 3D volumetric reproduction intended for rapid prototyping or robotic prehension. The need to constantly supply energy to counteract elastic retraction forces in order to maintain the required geometry, together with the inability to achieve conformal stability at elevated temperatures, limits the application of thermal shape memory polymers. Form removal also presents problems as most viscoelastic materials do not ensure demolding stability. This work demonstrates how magnetoactive boron−organo−silicon oxide polymers under the influence of an applied magnetic field can be used to achieve energy free sustainable volumetric shape memory effects over extended periods. The rheopectic properties of boron−organo−silicon oxide materials sustain form removal without mold distortion.