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In this report, the dry delivery of polyamide 12 powders by vibrating capillary steel nozzles is investigated and discussed regarding its potential for powder layer preparation in Laser Beam Melting. Therefore, a setup including a steel nozzle assembled on a piezoelectric actuator is presented, which enables the precise control over very small powder quantities by vibration excitation. An analysis reveals that the mass flow through the nozzle can be adjusted by the vibration modes in a certain range depending on the nozzle's specifications, whereas the vibration modes themselves show a complicated behaviour. Using a positioning system in combination with the vibrating nozzle, single-layer patterns consisting of polyamide 12 are produced and characterized regarding surface homogeneity and selectivity using a laser stripe sensor.
The generation of multi-material components by laser beam melting (LBM) is a challenge which requires the invention of new coating devices for preparation of arbitrary powder patterns. One solution is the usage of vibration-controlled nozzles for selective deposition of polymer powders. Powder flow can be initiated by vibration enabling a start-stop function without using any mechanical shutter. In this report, the delivery of polymer powder by vibrating nozzles is investigated with respect to their application in LBM machines. Therefore, a steel nozzle attached to a piezo actor and a weighing cell is used in order to measure the stability and time-dependence of the powder mass flow upon vibration excitation with the usage of different kind of powder formulations. The results show that precompression of the powder inside the nozzle by vibration excitation is essential to realize a reliable start-stop function with reproducible discharge cyles and to prevent a initial flush of powder flow. Moreover, the use of different powder materials showed that mass flow is even possible with powders which are not optimized regarding flowability, but is readily enhanced with a factor of 2 to 3 by admixing Aerosil® fumed silica.
Selective Laser Sintering (SLS) is an additive manufacturing technique whereby a laser melts polymer powder layer by layer to generate three-dimensional parts. It enables the fabrication of parts with high degrees of complexity, nearly no geometrical restrictions, and without the necessity of a tool or a mold. Due to the orientation in the building space, the processing parameters, and the powder properties, the resulting parts possess an increased surface roughness. In comparison to other manufacturing techniques, e.g. injection molding, the surface roughness of SLS parts results from partially melted powder particles on the surface layer. The actual surface roughness must thus be characterized with respect to the part's eventual application. At the moment, there is no knowledge regarding which measuring technique is most suitable for detecting and quantifying SLS parts' surface roughness. The scope of this paper is to compare tactile profile measurement methods, as established in industry, to optical measurement techniques such as Focus Variation, Fringe Projection Technique (FPT), and Confocal Laser Scanning Microscope (CLSM). The advantages and disadvantages of each method are presented and, additionally, the effect of tactile measurement on a part's surface is investigated.
Simultaneous Laser Beam Melting of polymers (SLBM) allows the generation of multi-material components,consisting of different thermoplastic polymers, within one additive building process. Besides the common advantagesof conventional Laser Beam Melting (LBM), multi-material components built by SLBM can fulfill different productrequirements like different chemical resistances or haptic material properties within a single part. To achieve suchparts, different powder materials are deposited next to each other and preheated a few degrees below their meltingtemperatures by infrared emitters and laser radiation (λ = 10.60 μm), before in the last step the preheated powdersare molten simultaneously by an additional laser source (λ = 1.94 μm). In this paper, different polymer powders likepolypropylene (PP) and polyamide 12 (PA12) are used for the generation of multi-material specimens. By varyingdifferent building parameters according to a specified design of experiments, their influence on the part properties isanalyzed. Important building parameters are the intensity and the irradiation time of the laser beam used for meltingthe preheated powders. Besides using tensile tests to determine the tensile strength and the elongation at break, theaverage part height in dependence of the energy input is analyzed. The overall aim is to specify the correlationbetween different building parameters regarding the energy deposition on the resulting part properties.
Powder based Additive Manufacturing technologies offer huge potential for building parts with almost no geometrical restrictions, but both the process controlling as well as the part properties are strongly dependent on different material characteristics of the material, like the flowability. In this work, different weight percentages of nano-scaled silica dioxide particles (Aerosil®) are admixed to pure polyethylene and polypropylene powder and the resulting flowability is determined. Besides using the Hausner ratio as standardized value, the degree of coverage is introduced as a new characteristic to quantify the powder flowability. The degrees of coverage are compared to the Hausner ratios to allow a discussion and evaluation about the different characteristic values. Additionally, tensile bars consisting of polypropylene are generated to determine the porosity by cross sections and the mechanical part properties by tensile testing. As mechanical part properties, the tensile strength and elongation at break are determined and the effects of different powder flowability on these properties are analyzed.
The generation of multi-material components using Laser beam melting (LBM) is a challenge which requires the invention of new coating devices for the preparation of arbitrary powder patterns. One solution is the usage of vibration-controlled nozzles for selective deposition of polymer powders. Powder flow can be initiated by vibration even when using powders with low flowability. In this report, the selective deposition of polymer powder by vibrating nozzles is investigated with respect to their application in LBM machines. Therefore, a steel nozzle attached to a piezo actor is applied, whereas the nozzle itself features internal channels which allow the precise control of the powder temperature using heat transfer oil. The setup is used to study the influence of temperature on the powder mass flow. The results show that, next to the vibration mode, the temperature strongly influences the powder mass flow which is done by affecting the moisture and thus the particle-particle adhesion forces. This shows that a precise control of the powder temperature inside the nozzle is required in order to achieve a constant mass flow and thus a successful application of vibrating nozzles inside LBM machines.
This study increases the basic understanding of optical material properties of polymer powders used in selective laser sintering (SLS). Therefore, different polymer powder materials were analyzed regarding their optical material properties with an integration spheres measurement setup. By the measurements a direct connection between the absorption behavior of the solid material and the overall optical material characteristics of the same material in powdery form could be shown. The results were used to develop an advanced explanation model for the optical material properties of powders. At present, existing explanation models only consider the occurring of multiple reflections in the gaps between the particles to explain the overall optical material properties of powder materials. Thus, by also considering the absorption behavior of the single particles, the basic understanding of the beam-matter interaction and their effect on the optical material properties of powder materials can be expanded.
By Laser Beam Melting of polymers (LBM), parts with almost any geometry can be built directly out of CAD files without the need for additional tools. Thus, prototypes or parts in small series production can be generated within short times. Up to now, no multi-material parts have been built by LBM, which is a major limitation of the technology. To realize multi-material parts, new mechanisms for depositing different polymer powders as well as a new irradiation strategy are needed, by which polymers with different melting temperatures can be warmed to their specific preheating temperatures and be molten simultaneously. This is achieved by simultaneous laser beam melting (SLBM). In the process, two different materials are deposited next to each other and preheated a few degrees below their melting temperatures by infrared emitters and laser radiation (λ = 10.60 µm), before in the last step the two preheated powders are molten simultaneously by an additional laser (λ = 1.94 µm). So far, multi-material tensile bars have been realized and analyzed regarding their boundary zone between both materials. The experiments showed that the temperature gradients in the boundary zone and along the building direction seem to be of great importance for the process stability and the resulting part properties. Therefore, a detailed analysis of the occurring temperature gradients during the process is needed to identify adequate process adjustments regarding the temperature controlling. To analyze the temperature gradients, thermocouples positioned inside the powder bed are used. By varying the temperature of the building platform, the influence of different temperature gradients on the resulting part properties is shown.
Simultaneous laser beam melting (SLBM) allows the direct realization of multi-material components consisting of different polymer materials by a single Additive Manufacturing (AM) process. To achieve a high compound strength between different materials by adhesive bonding, a common boundary zone based on diffusion of the macromolecules is necessary and thus, both materials needs to be compatible regarding their specific adhesion compatibility. However, by SLBM also incompatible polymers can be processed to multi-material parts. If two incompatible polymers are processed, a positive locking between the different materials is necessary to achieve a connection between the materials. The positive locking results of a random mixture process of the different powder materials during the powder deposition process by a two chamber recoater system, which leads to the forming of undercuts of one material in the other during the melting and recrystallization. In this paper, thermoplastic elastomer (TPE) and polypropylene (PP) powders, which are incompatible, are processed to multi-material specimens. By qualifying basic material properties, their influence on the process and especially on the forming of undercuts in the boundary zone is analyzed. To also allow the analysis of the influence of both material and process parameters on the resulting part properties, tensile test specimens are built and their tensile strength is determined. Additionally, cross sections of the boundary zone are prepared and analyzed by microscope images.
In this paper, first results regarding the realization of multi-material parts by Simultaneous Laser Beam Melting (SLBM) of polymers are presented. This new approach allows the layerwise generation of parts consisting of different polymer materials within one building process. Besides the typical advantages of additive manufacturing technologies, such parts can fulfill different product requirements concomitant and therefore could enlarge the overall field of application. The powder materials used for this paper are polyethylene (PE) and a polyamide based thermoplastic elastomer (TPE). After depositing the powder materials next to each other, infrared-emitters heat the lower melting polymer and a CO2 laser provides the preheating temperature of the higher melting polymer. In the last step, a thulium fibre laser melts the two preheated powders simultaneously. The realized specimens are characterized by cross sections and their tensile strengths are determined. Additionally, the new approach of the simultaneous energy irradiation is investigated using a Finite Element Analysis in order to gain a more profound process understanding. In that sense, the influence of the size of the exposure area on the reachable maximum temperatures inside that area was analyzed by the simulation and compared to experimental studies.
Purpose – The purpose of this paper is to demonstrate the processability of cohesive PE-HD particles in laser beam melting processes (LBM) of polymers. Furthermore, we present a characterization method for polymer particles, which can predict the quality of the powder deposition via LBM processes. Design/methodology/approach – This study focuses on the application of dry particle coating processes to increase flowability and bulk density of PE-HD particles. Both has been measured and afterwards validated via powder deposition of PE-HD particles in a LBM machine. Findings – For efficient coating in a dry particle coating process, the PE-HD particles and the attached nanoparticles need to show similar surface chemistry, i.e. both need to behave either hydrophobic or hydrophilic. It is demonstrated that dry particle coating is appropriate to enhance flowability and bulk density of PE-HD particles and hence considerably improves LBM processes and the resulting product quality. Originality/value – At present, in LBM processes mainly polyamide (PA), 12 particles are used, which are so far quite expensive in comparison to, for example, PE-HD particles. This work provides a unique and versatile method for nanoparticulate surface modification which may be applied to a wide variety of materials. After the coating, the particles are applicable for the LBM process. Our results provide a correlation between flowability and bulk density and the resulting product quality.
By simultaneous laser beam melting (SLBM), parts consisting of different polymer powders can be additively manufactured within one building process. Besides the advantages of conventional LBM, e.g., not needing additional tools and being able to realize parts with almost any geometry, different product requirements can be achieved within a single part. Product requirements may be different chemical resistances or haptic material properties. Therefore, SLBM enlarges the application field for additive manufacturing in general. In the process, two different materials are deposited on the building platform and preheated a few degrees below the melting temperature of the lower melting polymer by infrared emitters. Afterward, a CO2 laser (λ = 10.6 μm) provides the energy for the temperature difference between the preheating temperatures of both materials. Finally, a digital light processing chip is used to achieve simultaneous and flexible energy deposition for melting both preheated polymers. By illuminating the chip with a laser, parts of the beam can be flexibly guided onto the powder bed or into a beam trap. As laser, a single mode thulium laser (λ = 1.94 μm) is used. After melting the layer, a new layer is deposited and the process starts anew. In this paper, polypropylene and polyamide 12 are used as materials. After analyzing the material and melting behavior during the process by a high-resolution thermal imaging system, the parts are qualified regarding their material compatibility at the boundary zone and porosity by cross sections.
In this paper, first results regarding the realization of multi-material parts by Simultaneous Laser Beam Melting (SLBM) of polymers are presented. This new approach allows the layerwise generation of parts consisting of different polymer materials within one building process. Besides the typical advantages of additive manufacturing technologies, such parts can fulfill different product requirements concomitant and therefore could enlarge the overall field of application. The powder materials used for this paper are polyethylene (PE) and a polyamide based thermoplastic elastomer (TPE). After depositing the powder materials next to each other, infrared-emitters heat the lower melting polymer and a CO2 laser provides the preheating temperature of the higher melting polymer. In the last step, a thulium fibre laser melts the two preheated powders simultaneously.The realized specimens are characterized by cross sections and their tensile strengths are determined. Additionally, the new approach of the simultaneous energy irradiation is investigated using a Finite Element Analysis in order to gain a more profound process understanding. In that sense, the influence of the size of the
exposure area on the reachable maximum temperatures inside that area was analyzed by the simulation and compared to experimental studies.
In this report, the delivery of polyamide 12 (PA 12) powder and powder layer preparation by vibrating steel nozzles is investigated and discussed with respect to its application for laser beam melting. Therefore, a setup was realized which includes a steel nozzle attached to a piezo actor as well as a positioning system. In order t o investigate the mass flow characteristics in dependency on the applied vibration state, a weighing cell is used enabling time-resolved mass flow measurements. Moreover, single-layer patterns consisting of colored and uncolored polyamide 12 were created and characterized regarding surface homogeneity and selectivity before as well as after the melting of the powder layers by a hot plate.
By using Additive Manufacturing technologies, like Laser Beam Melting (LBM) of polymers, parts can be realized within single days and necessary modifications can be quickly adapted. With increasing complexity, products are often made out of different polymer materials and the need for multi-material parts is an increasing industry requirement, which cannot be fulfilled by the single material parts realizable by LBM. Therefore, Simultaneous Laser Beam Melting (SLBM) as a new Additive Manufacturing technology offers the possibility to build parts consisting of different polymer materials. The realizable parts combine different material properties, like differing stiffness or chemical resistances, within a single part. Up to now, different materials are deposited next to each other on the building platform, thus the boundary surface between the different polymers is orientated perpendicular to the building direction. For this paper, the polymer powders are alternated in building direction. Thus, the boundary surface is orientated horizontally and is larger, both influencing the boundary surface and resulting part properties, which are analyzed by a high-resolution thermal imaging system and by cross sections.
In this paper, the use of electrostatic polymer powder transfer methods for the preparation of multi-material layers is discussed with respect to the application in Simultaneous Laser Beam Melting (SLBM). Therefore, the basic principles of the single process steps as well as the challenges in combination with SLBM are considered verifying the critical process steps. On that base, process concepts are developed which might enable the fabrication of high quality multi-material parts in the future. Moreover, since the polymer powders typically used with Laser Beam Melting differ strongly from common toners for e. g. electrophotographic printing, an experimental setup was built to study the powder transfer with an electrically chargeable transfer plate using polyamide 12 powder. The results of this study show that transfer of powders usable for Laser Beam Melting can be achieved, but depends on the electric field strength which is a function of the gap between transfer and substrate plate and the intermediate electric potential.
Abstract — In this report, the dry delivery of polyamide 12 (PA 12) powder for the preparation of powder layers in laser beam melting (LBM) is investigated. Therefore, an experimental setup was built which consists of a glass nozzle assembled on a piezo-electric actuator. By applying a sinusoidal voltage signal to the actuator, the nozzle is set into vibration mode which enhances the powder delivery through the nozzle. By using this effect, powder mass flow is controlled and a valve-like start and stop function is realized. In order to identify suitable process parameters, a broad range of vibration modes were investigated using two nozzles made from glass with different orifice diameters. Therefore, the vibration frequency and the voltage signal of the actuator were varied and the resulting mass flow was detected by a balance. It was found that both the frequency and the voltage signal affect the mass flow and its stability but with different impact. Moreover, powder lines were deposited with different velocities in order to characterize the setup regarding applicability for highly selective powder deposition for LBM.
By selective laser sintering (SLS), polymer powders are molten layer by layer to build conventional prototypes or parts in small series with geometrical freedom that cannot be achieved by other manufacturing technologies. The SLS process is mainly defined by the beam–matter interaction between powder material, laser radiation and different material characteristics by itself. However the determination of these different material characteristics is problematic because powder material imposes certain requirements that cannot sufficiently be provided by conventional measurement methods. Hence new fundamental investigation methods to determine the optical and thermal material characteristics like the thermal diffusivity, thermal conductivity, or the influence of different heating rates on the melting behavior are presented in this paper. The different analysis methods altogether improve the process of understanding to allow recommendations for the future process controlling.
By simultaneous laser beam melting (SLBM), different polymer powders can be processed to multi-material parts, which offers the potential to enlarge the field of application for conventional LBM. In a SLBM process, a powder bed consisting of different polymers and therefore with different melting and crystallization temperatures is deposited. Besides the use of infrared emitters for preheating the lower melting polymer, a CO2 laser distributes the necessary preheating temperature of the higher melting polymer. In the last step, a thulium fibre laser distributes the energy necessary for melting the two preheated powders simultaneously. In order to analyze the temperature gradients of the process on the powder surface and in deeper layers, a high-resolution thermal imaging system and thermocouples are used.
In the paper first results regarding the realisation of gradient and multi-material parts manufactured by Laser Beam Melting in powder bed of metals and polymers are published. Gradient properties of additively manufactured metal parts can be achieved by varying the composition of alloying components in the powder and adapting process strategies. As an alternative to atomizing pre-alloyed materials, mixtures of different powders are investigated. For realizing multi-material-parts from polymers, at first relevant material properties concerning compatibility have to be analysed. Therefore the paper shows the main requirements for compatibility between different materials and also first results regarding the compatibility of polymer powders and possible combinations for the manufacturing of multi-material components by laser beam melting of polymers.
Die Energieeinbringung in Form von elektromagnetischer Strahlung in das Pulverbett beim selektiven Laserstrahlschmelzprozess von Kunststoffen wird maßgeblich durch das Absorptionsverhalten der Pulverwerkstoffe bestimmt. Aufgrund von Vielfachreflexionen an den einzelnen Pulverpartikeln in den Poren weisen Pulverwerkstoffe im Vergleich zu makroskopischen Festkörpern andere Absorptionseigenschaften auf. Im vorliegenden Beitrag wird daher ein geeigneter Messaufbau zur Bestimmung der optischen Materialeigenschaften von verschiedenen Pulverwerkstoffen vorgestellt. Mittels eines Ulbricht-Kugel-Messaufbaus wird der Reflexions-, der Transmissions- und der Absorptionsgrad von pulverförmigen Werkstoffen bei einer Wellenlänge von 10,6 µm eines CO2-Lasers und unterschiedlichen Schichtstärken ermittelt. Neben den Werkstoffen Polyamid 12 und Polyethylen im reinen Zustand werden Mischungen mit Additiven, wie beispielsweise Graphit, analysiert und verglichen. Durch die Beimischungen kann eine für den Schmelzprozess zu geringe Absorption des reinen Kunststoffes wie im Fall von Polyethylen-Pulver bei einer Wellenlänge von 10,6 µm gezielt erhöht werden, wodurch die Entwicklung neuer Pulverwerkstoffe erleichtert wird.
Neue Prozessstrategien zur Herstellung von Multi- Material-Bauteilen und Gradientenwerkstoffen
(2012)
Das additive Fertigungsverfahren, dem gemeinhin die größten Potentiale zugesprochen werden, ist das Laserstrahlschmelzen im Pulverbett von Kunststoffen (LSS-K) und von Metallen (LSS-M). Wie bei anderen Techniken der additiven Fertigung werden Bauteile direkt aus CAD-Dateien ohne zusätzliche Werkzeuge bei enormer konstruktiver Freiheit gefertigt. Die resultierenden Werkstoffeigenschaften sind vergleichbar mit konventionelleren Prozessrouten wie etwa dem Spritzgießen thermoplastischer Polymere beziehungsweise auf der Seite der Metalle dem Schmieden oder Gießen. Derzeit wird der Einsatz des LSS zur Fertigung von Endprodukten in kleinen Stückzahlen erschwert von nicht ausreichender Prozessstabilität und, insbesondere bei Kunststoffen, von der eingeschränkten Werkstoffauswahl. Bisher werden für beide Werkstoffklassen Bauteile aus jeweils einem einzigen Ausgangsmaterial hergestellt. Näherungsweise erzeugt LSS also einheitliche Materialeigenschaften über das gesamte Bauteil hinweg. Ein Ansatz, der in den Teilprojekten A5 und B6 des Sonderforschungsbereichs 814 verfolgt wird, ist die Realisierung von Multi-Material-Bauteilen mittels LSS-K beziehungsweise LSS-M.
Qualification and modification of new polymer powders for laser beam melting using Ulbricht spheres
(2014)
The restricted amount of available materials for Laser Beam Melting (LBM) of polymers is one of the main limitations for expanding the technology. Current qualification methods deal with problems like inadequate powder flowability or high part porosities among others but do not offer a detailed analysis of the important beam-matter-interaction between powder particles and electro-magnetic laser radiation. In this paper, polyethylene powder is qualified for the LBM process and specifically analyzed regarding the optical material properties of the powder for a wavelength of 10.6 μm. By admixing graphite as absorption intensifier the change of the optical material properties and the thereby connected processing parameters are analyzed. Furthermore an explanation approach is given to explain the relation between different transmittances of different powder particles and the optical material properties of the polymer powders.
First results regarding the realisation of multi-material components manufactured by Laser Beam Melting of polymers and metals are published. For realising composite structures from polymer powders by additive manufacturing, at first relevant material properties regarding compatibility have to be analysed. The paper shows the main requirements for compatibility between different materials and offers first results in form of a compatibility matrix of possible combinations for composite structures.For achieving gradient properties of additively manufactured metal parts by using composite materials the composition of alloying components in the powder and adapted process strategies are varied. As an alternative to atomizing pre-alloyed materials, mixtures of different powders are investigated.
Im Rahmen dieses Beitrags wird das Schmelzeemulgieren als Verfahren zur Herstel-lung von Polymermikropartikeln vorgestellt. In diesem Prozess wird zunächst ein Polymergranulat in einer kontinuierlichen Phase in Gegenwart geeigneter Additive in einem Rührbehälter aufgeschmolzen, die Rohemulsion in einer Rotor-Stator-Einheit feinemulgiert und anschließend zu einer Suspension abgekühlt. Der Einfluss von Prozessparametern und Systemzusam-mensetzung auf das Emulgierergebnis wird diskutiert und die Anwendbarkeit des Verfahrens für polymere Mikropartikeln anhand von Polypropylen (PP) und Polyethylen (PE-HD) dargestellt. Die erhaltenen Suspensionen werden zur Überführung in Pulverform sprühgetrocknet und die Fließeigenschaften des Pulvers analysiert. Durch trockenes Beschichten mit pyrogener Kieselsäure kann die Fließfähigkeit der erhaltenen Partikeln weiter verbessert werden. Das Verfahren bietet somit einen neuen Zugang zur Herstellung neuer Ausgangsmaterialien für die Additive Fertigung.
In former works, the optical material properties of different polymer powders used for Laser Beam Melting (LBM) at room temperature have been analyzed. With a measurement setup using two integration spheres, it was shown that the optical material properties of polymer powders differ significantly due to multiple reflections within the powder compared to solid bodies of the same material. Additionally, the absorption behavior of the single particles shows an important influence on the overall optical material properties, especially the reflectance of the powder bed. Now the setup is modified to allow measurements at higher temperatures. Because crystalline areas of semi-crystalline thermoplastics are mainly responsible for the absorption of the laser radiation, the influence of the temperature increase on the overall optical material properties is analyzed. As material, conventional polyamide 12 and polypropylene as new polymer powder material, is used. By comparing results at room temperature and at higher temperatures towards the melting point, the temperature-dependent optical material properties and their influence on the beam-matter interaction during the process are discussed. It is shown that the phase transition during melting leads to significant changes of the optical material properties of the analyzed powders.
Heat staking is a joining technology by which thermoplastic pins are formed by force and temperature to create a form- and force-fitting connection between components. This paper examines the characteristics of 3D printed pins in comparison to conventionally turned pins for heat staking applications. The 3D printed pins are created using fused layer modeling, with variations in horizontal and vertical building directions, as well as different layer thicknesses. The study investigates the impact of significant factors on the heat staking process, including the forming force and temperature. Tensile tests, micrographs, and micro-CT measurements were conducted to determine the properties of the heat-staked joints. Additionally, a stage plan was developed to enhance the understanding of the forming process of both printed and conventionally turned materials. The findings suggest that, under specific process parameters, 3D printed pins exhibit comparable strength to conventionally manufactured pins. The research also demonstrates that the anisotropy resulting from the layer-by-layer construction of the pins significantly influences the strength of the connection. Furthermore, the study reveals that 3D printed pins exhibit good forming accuracy during the heat staking process, and the cavities formed during printing can be substantially reduced.
The use of thermoplastics in lightweight construction is continuing to grow. This implies the need for suitable joining techniques to combine thermoplastics with other materials, such as metals, to gain tailored multi-material parts. In this paper latest results of experimental investigations on laser-based hot-melt bonding and injection molding for laser-structured metal plastic hybrids are presented. As materials stainless steel and short-fiber reinforced polyamide are used. The stainless steel surface is structured with a nanosecond pulse laser before joining to improve the mechanical adhesion between the dissimilar materials. Thereby, different structure depths in the range between 16.6 ± 1.2 µm and 66.5 ± 2.5 µm as well as different hatch distances between 70 and 300 µm are realized. The laser-based joining process is carried out irradiating the metallic surface multiple times. Positioned below the metal in T-joint configuration, the thermoplastic melts as a result of heat transfer and acts as hot-melt cohesive. Besides, hybrid joints are manufactured using injection molding. For experiments, the mold temperature as well as the melt temperature are varied. Regardless of the joining process, the hybrid joints are mechanically characterized by tensile tests. The results demonstrate that for both joining processes strong laser-structured metal plastic hybrids can be realized.
In this paper, first results regarding the realization of laser-based hot-melt bonding of additive manufactured plastics parts to metal sheets for strong and tight multi-material joints are presented. Compared to earlier investigations, in which nearly solely extruded plastic materials were applied, the use of additive manufactured plastics complements the research field with a promising approach. Besides the typical advantages of multi-material joints regarding weight reduction and high strengths, such parts can meet the needs of constructional freedom and the avoiding of tool costs. Materials used for this paper are aluminum (AlMg3), stainless steel (1.4301) and polyamide 12 (PA12). The performed experiments resulting in multi-material joints between metal and polyamide. The realized specimens undergo a tensile shear test and a tightness test, in which the characteristics of the joints are determined.
Due to the growing number of applications for Additive Manufacturing (AM), an increasing need for enhanced quality control methods exists. Here optical measurement techniques are often used for in-situ monitoring in AM. There is a great potential to standardize and improve applications of optical measurement devices in accordance to the increasing requirements of measuring tasks. Beside the optical material qualifications, especially process-oriented changes in optical effects are of great relevance for in-situ evaluations. The optical modifications may be attributed to aggregate specific phase transitions coming along with variable emitted wavelengths. A measuring setup with two integrations spheres and a heated process chamber have been developed to analyze the optical interactions of laser radiation and visual illumination with the powder. The process oriented analysis for selective laser sintering lead to improved operating conditions in the field of in-situ measurements in combination with an accurate evaluation of the absorption ratio of the examined powder.
Mittels des entwickelten additiven Fertigungsprozesses des simultanen, intensitätsselektiven Laserstrahlschmelzens lassen sich Werkstoffverbunde bestehend aus unterschiedlichen Polymerwerkstoffen mit hohen Bauteilfestigkeiten realisieren. Die zukünftig realisierbaren Werkstoffverbunde können dabei durch eine örtlich variable Ausnutzung der unterschiedlichen Werkstoffeigenschaften die hinsichtlich lokal definierter Belastungsprofile gestellten Anforderungen an komplexe Multi-Material-Bauteile erfüllen. Dadurch lassen sich neue Anwendungsfelder für die additive Fertigung von Werkstoffverbunden erschließen.
The mechanical and microstructural investigation of polymer parts (polyamide 12) fabricated by Selective Laser Sintering as part of a Round Robin initiative is presented. The paper focuses on the microstructural analysis of the Round Robin samples and their evaluation regarding their effect on mechanical properties with respect to each other. Therefore optical microscopy on microtomed samples, X-ray computed tomography and Differential Scanning Calorimetry is used to determine the morphology of residual particle cores and of internal pores.
Laser transmission welding is a non-contact and efficient process technology for joining thermoplastic polymers. In the conventional process, laser sources in the wavelength range of 1 μm are usually used. Therefore, most of the laser radiation is transmitted through the upper joining partner and absorbed only in the lower joining partner. As a result, the possibilities to influence the temperature field especially in the upper joining partner are limited. To overcome these limitations, an additional thulium fiber-laser with a wavelength of 1.94 μm is used in this study and coaxially aligned with a diode laser. The use of an additional thulium fiber-laser leads to a significant absorption in the upper joining partner. Through this approach, it is shown that the temperature field and the weld seam geometry can be influenced by using these two different discrete laser wavelengths. Depending on the intensity distribution of both lasers, an increase of the size of the heat affected zone in the upper joining partner can be observed. In order to develop a better process understanding, a thermal finite element model is built up and verified by comparing the calculated size of the heat affected zone for different process parameters with the experimental data. The model is able to represent the influence of both laser sources on the temperature field and is used to calculate characteristics of the temperature field, such as maximum temperatures or cooling rates. The characteristics are then used to explain the weld seam morphology, such as occurrence and size of spherulitic structures in the weld seam.
Conventional Selective Laser Sintering of polymers is restricted to the processing of single materials. The fabrication of components consisting of different material regions is a challenge which cannot be realized by standard coating devices basing on blades or rollers. Thus, advanced coating and deposition techniques are needed which enable the precise and reliable control over very small powder quantities in order to prepare arbitrary powder patterns with high accuracy and repeatability. In this report, the delivery of polymer powder by vibrating nozzles inside laser sintering machines is investigated. Therefore, a steel nozzle attached to a piezo actuator is integrated into a machine, whereas the nozzle itself features internal channels which allow the precise control over the powder temperature using heat transfer oil. The setup is used to study the influence of different system configurations on the powder deposition characteristics as resolution and layer surface roughness. The results show that temperature influences the mass flow depending on the material used and that a precise deposition of powder pattern with microscale resolution is possible with optimized parameters. Finally, the multimaterial powder pattern is fused by a new illumination strategy of laser sintering which is called Simultaneous Intensity-Selective Laser Sintering in order to demonstrate the potential of this new approach.
The mechanical properties of polymer parts built by Selective Laser Sintering are strongly related to the internal microstructure which differs with the applied production parameters. The paper focuses on the back tracing of the pore morphology of laser sintered polyamide-12 samples to the process parameters. Therefore, a data base is used which is supplied by a Round Robin initiative and includes mechanical tensile tests and the microstructural analysis of the pore morphology of several different sample charges built with different machines. The pore morphologies (porosity, pore density, pore shape and pore arrangement) measured by X-ray computed tomography are compared and discussed regarding the employed parameters and the resulting mechanical properties. The investigations point out that pore density is a superior indicator than porosity for mechanical issues. This is especially valid along the build direction since pore morphology has shown to be strongly anisotropic. Moreover, the analysis revealed that pore density is strongly affected by the process temperature, which is proved to be essential for the fabrication of mechanical robust parts using Selective Laser Sintering.
Comparison between the optical properties of injection molded and additive manufactured components
(2018)
Fused Layer Manufacturing (FLM) is an additive technology based on polymer material extrusion. Due to variations in temperature during the manufacturing process and the resulting stress between the stacked layers, the final parts show anisotropic mechanical properties. One possible approach for their reduction is the immediate local preheating of the surface via laser radiation. At first, our research examines the influence of laser parameters as wavelength, power, velocity and area of impact for the preheating of the surface. In addition, an overview of possible parameter combinations is given based on the selection of raw materials, its colors, thicknesses and the manufacturing process. Initially, the absorption level of the materials regarding the emitted wavelength is detected using a spectrophotometer. Subsequently, preheating tests are conducted with different laser types while the temperature is determined by a thermal camera. The selected laser type is planned to get mounted on a prototype-machine for further in-situ preheating experiments on FLM parts during the manufacturing process.
Laser transmission welding is a well-known joining technology for welding thermoplastics. Although the process is already used industrially, fundamental process-structure-property relationships are not fully understood and are therefore the subject of current research. One aspect of these mentioned process-structure-property relationships is the interaction between the temperature field during the welding process, the weld seam morphology of semi-crystalline thermoplastics, and the weld seam strength. In this study, the influence of the line energy on the weld seam morphology of polypropylenes is analyzed. For this purpose, the size of spherulites in the weld seam is investigated, as well as different occurring phases of polypropylene (a- and b-phase). It is shown that both the spherulite size of the a-phase and the amount of b-phase increase with increasing line energy. For the explanation and discussion of the results, a temperature-dependent thermal simulation model is used to derive characteristic attributes of the temperature field (maximum temperatures, cooling rates, temperature gradients).
In this paper, the use of electrophotographic polymer powder transfer for the preparation of multi-material layers is discussed with respect to the application in powder bed-based additive manufacturing technologies as selective laser sintering (SLS). Therefore, the challenges of this task are considered verifying the critical process steps in order to develop a concept for an electrophotograhic laser sintering machine. On that basis, an experimental setup with a two-chamber design is realized which enables the investigation of the electrophotographic powder transfer at typical process conditions of SLS. Using this setup, transfer tests of polypropylene powder patterns were performed and qualitatively analyzed by photographic imaging. The results confirm the high potential of the application of electrophotography for multi-material powder deposition and show how a residual electrophotographic powder deposition can be achieved in general, which is independent from the already produced part height, in order to build up three-dimensional multi-material components.
In order to understand the absorption characteristic, a ray trace model is developed by taking into account the reflection, absorption and refraction. The ray paths are resolved on a sub-powder grid. For validation, the simulation results are compared to analytic solutions of the irradiation of the laser beam onto a plain surface. In addition, the absorptance, reflectance and transmittance of PA12 powder layers measured by an integration sphere setup are compared with the numerical results of our model. It is shown that the effective penetration depth can be lower than the penetration depth in bulk material for polymer powders and, therefore, can increase the energy density at the powder bed surface. The implications for modeling of the selective laser sintering (SLS) process and the processability of fine powder distributions and high powder bed densities are discussed.
A new approach to coat PA12 powders with laser-generated nanoparticles for selective laser sintering
(2018)
The modification of selective laser sintering (SLS) powder materials by nanoadditives offers the possibility to adapt the powder properties to the laser sintering process or the resulting part properties. To avoid agglomeration of the nanofiller, a new approach in which surfactant-free laser-generated colloidal nanoparticles are adsorbed onto the polymer surface directly in an aqueous solution is demonstrated. Based on this novel approach, polyamide 12 (PA12) powders are decorated with metal and oxide nanoparticles and processed via SLS. Electron microscopy and confocal laser scanning imaging are utilized to analyze the dispersion of the filler.