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To reduce particulate emissions, the use of particulate filters in diesel engines is meanwhile state of the art, while the integration of such systems in gasoline engines is now also necessary in order to comply with today's regulations. Over its lifetime, a gasoline particulate filter (GPF) collects ash components of fuel, lubrication oil, and materials originating from the catalytic coating and from engine abrasion. In the development and application process, synthetic ashing from GPFs is challenging. The ash of the lubrication oil can be increased in various ways, like oil-doped fuel, a separate oil burner, or changes in the piston-cylinder system of the engine. However, these methods show major disadvantages. For this reason, an improved approach is presented in this study, which allows a quick response to changes in combustion (e.g., engine knocking) and producing ash, which is more realistic due to its primary particle size and the density of ash plugs, in a shorter time. Therefore, an approach to accelerate ash loading by active oil injection using a multi-point injection (MPI) system is introduced. With the help of this methodology, an ashing capacity of 1.21 g/h is implemented, which is a high rate compared to other investigations. The primary particle size (evaluated by means of a transmission electron microscope), is in the same size range as those detected at the full-load curve during regular operation. A computer tomographic (CT) analysis of the incinerated particulate filter also shows that a very high density of ash plugs can be realized, which has also been found in the literature for real applications. In addition, with the help of a mass spectrometer (MS) and an intermediate weighing of the particulate filter, the current ash loading of the GPF could be determined with an accuracy of 1%.
Ammonia-based selective catalytic reduction (SCR) systems are the most widely used technology for reduction of nitrogen oxide emissions from lean-burn engines such as diesel engines. However, at low exhaust temperatures, the SCR process is limited by difficulties in the decomposition of the ammonia precursor urea, which is carried on-board using an aqueous solution "AdBlue". In this study, the decomposition of AdBlue urea induced by electrical current and the resulting associated pH shifts were investigated in a divided cell configuration in the liquid phase. The decomposition was found to be favored in both electrochemical compartments, anodic and cathodic, at temperatures of 60-80 degrees C compared to a reference without electrochemical treatment. In addition to the determination of ammonia contents using an ammonia sensor, IC/HPLC analyses were carried out for each sample. Different side products such as biuret, nitrate, cyanuric acid, ammelide, and others were formed. In the anodic compartment, nitrate formation could be observed due to oxidation of ammonia at the electrode surface.
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Difficulties in decomposing AdBlue to ammonia limit the applicability of selective catalytic reduction systems at low exhaust temperatures. Investigations on the decomposition of AdBlue in the liquid phase under elevated pressure at temperatures up to 165 degrees C were carried out. Besides effects of inorganic catalysts, the impact of pH on urea decomposition was examined. After dissolution in aqueous phase, the compounds ZnO, WO3, and MoO3 were found to be effective in liquid-phase AdBlue decomposition. However, the efficiency was dropping significantly over few hours. Decomposition of AdBlue urea was also found to be favored for alkaline and acidic conditions.
Gasoline particulate filters (GPFs) are an appropriate means to meet today's emission standards. As for diesel applications, GPFs can be monitored via differential pressure sensors or using a radio-frequency approach (RF sensor). Due to largely differing soot properties and engine operating modes of gasoline compared to diesel engines (e.g., the possibility of incomplete regenerations), the behavior of both sensor systems must be investigated in detail. For this purpose, extensive measurements on engine test benches are usually required. To simplify the sensor development, a simulation model was developed using COMSOL Multiphysics((R)) that not only allowed for calculating the loading and regeneration process of GPFs under different engine operating conditions but also determined the impact on both sensor systems. To simulate the regeneration behavior of gasoline soot accurately, an oxidation model was developed. To identify the influence of different engine operating points on the sensor behavior, various samples generated at an engine test bench were examined regarding their kinetic parameters using thermogravimetric analysis. Thus, this compared the accuracy of soot mass determination using the RF sensor with the differential pressure method. By simulating a typical driving condition with incomplete regenerations, the effects of the soot kinetics on sensor accuracy was demonstrated exemplarily. Thereby, the RF sensor showed an overall smaller mass determination error, as well as a lower dependence on the soot kinetics.
Tonal components can be regarded as one of the most relevant components for interior sound quality of electric vehicles, especially at low speeds. Sources for these tones are for example the vehicles' drivetrains but also other technical components. Depending on the driving conditions, due to the interaction of various dominant sources, audible tone complexes can occur. Similar to musical intervals, the different frequency ratios within these complexes can result in consonant or dissonant sensations. The strength of this sensation does not only depend on the frequency relation of the tones but also on their relative levels. In this study, different musical intervals were subjectively rated in terms of their specific consonant or dissonant character. Using an adaptive procedure, sound pairs, each consisting of a two-tone signal, where adjusted to equal dissonance by varying the level of the second tone of one of the two-tone signals. Using the same paradigm, also pairs of equal vehicle sound quality were obtained. With these results, it is possible to quantify dissonance, and theinfluence of dissonance on sound quality expressed in terms of level differences of two-tone signals. These results can help to make the concept of dissonance more useful for sound-engineering applications.
The use of alternative fuels in high-power non-road mobile machinery (NRMM) combustion engines is a possible way to substitute fossil fuel. By using pure vegetable oil fuels, like rapeseed oil fuel (DIN 51605), the greenhouse gases can be reduced effectively. Due to the differences in physical and chemical properties, a modification of the engine control unit calibration is necessary to adapt the working process on the fuel. Without modifications, the engine power output with rapeseed oil fuel is lower than with diesel fuel because of the smaller energy content. By adapting the engine settings, like the injection fuel mass, the power loss can be compensated but it accompanies with a higher fuel consumption. The engine emissions at part load conditions show, that there are benefits in particle emissions by using rapeseed oil at similar NOx emissions. Therefore, a design of experiment setup was initiated on a selected engine operation point to determine the effects of further parameters, like rail pressure, manifold pressure and injection pattern, on the process and to see the potential of an optimized calibration.
Bei Ottomotoren mit Direkteinspritzung besteht beim Kaltstart, den Warmlaufphasen und auch durch den Einfluss anderer Parameter wie z. B. des Einspritzzeitpunkts oder des Einspritzdrucks die Problematik, dass Kraftstoff an die Zylinderlaufbahn aufgetragen wird und sich mit dem Motoröl vermischen kann. Eine Verstärkung dieses Kraftstoffauftrags ist unter anderem der Verschiebung der Motorbetriebspunkte zu höheren Mitteldrücken und damit einem Wirkungsgrad optimaleren Betrieb geschuldet. Eine Veränderung der physikalischen und chemischen Eigenschaften des Motoröls durch die Verdünnung mit Kraftstoff ist die Folge. Durch die Verringerung der Viskosität des Motoröls kann es zu einer verminderten Schmierwirkung des Öls kommen, die im schlimmsten Fall zur Schädigung des Motors führt. Existierende Offline-Analysemethoden die zeitintensive Laboranalysen nach sich ziehen, als auch Online-Messverfahren die nicht den technischen Anforderungen hinsichtlich Genauigkeit und einer kurzen Messdauer entsprechen, stellen aktuell die einzigen Messmethoden zur Bestimmung der Schmierölverdünnung dar. Durch neue Entwicklungstrends bei Ottomotoren ist es jedoch unbedingt notwendig, die Mechanismen des Kraftstoffein- und -austrags in das und aus dem Motoröl genauer zu untersuchen. Mit der an der OTH Regensburg neu entwickelten Messtechnik wurde eine Vorgehensweise erarbeitet, mit der die zeitlichen Verläufe des Kraftstoffein- und -austragsverhaltens bei Ottomotoren quantitativ in kurzer Zeit bestimmt und optimiert werden können.
Especially at cold start and the warm-up operation GDI engines have an issue with oil dilution. Parameters such as injection timing and injection pressure impact the entry of fuel in the engine oil as well. With the adjustment of engine operating points to higher mean effective pressures resulting in downsizing concepts also an additional increase of fuel entry occurs. Fuel gets into the oil pan and is mixed with the engine oil so that the physical and chemical properties of the engine oil are changed. With the reduction of engine oil viscosity due to fuel entry a reduced lubricating effect can be caused. In the worst case damage to the engine occurs, To determine oil dilution online and offline measurement methods exist. A rather long analysis time in the laboratory is a disadvantage of the offline methods. Online methods are not correlating with technical requirements in terms of accuracy and a short measurement time. New trends in the development of gasoline engines require investigations of fuel in oil sorption and desorption processes. A new measurement technique which is developed at the OTH Regensburg enables to determine quantitative fuel in oil sorption and desorption processes. With this technique a procedure was generated to measure the oil dilution at gasoline engines and optimize them in a short time.
Differenzierte Kohlenwasserstoffanalytik im Dieselabgas bei verschiedenen Motorbetriebszuständen
(2014)
Die für Dieselfahrzeuge gesetzlich vorgeschriebenen Grenzwerte bezüglich der Schadstoffkomponenten Kohlenwasserstoffe und Kohlenmonoxid können nur durch den Einsatz eines Diesel-Oxidationskatalysators erfüllt werden. Um erhöhte Emissionen infolge eines geschädigten Katalysators zu vermeiden, gilt es, dieses abgasrelevante Bauteil auch während des Betriebes zu überwachen. Die zukünftigen gesetzlichen Anforderungen an die Überwachung erfordern ein Verfahren das eine zuverlässige und hochgenaue Diagnose zulässt. Deshalb entwickelt eine Forschungsgemeinschaft aus Industrieunternehmen und Hochschulen einen neuartigen Kohlenwasserstoffsensor zur hochgenauen Analyse von unverbrannten Kohlenwasserstoffen im Abgasstrang. Hierfür ist die Kohlenwasserstoffzusammensetzung des Dieselabgases bei verschiedenen Motorbetriebszuständen zu ermitteln. Zur differenzierten Untersuchung der Kohlenwasserstoffkomponenten wurde in der Arbeit ein Massenspektrometer eingesetzt, das mit chemischer Ionisation arbeitet. Anhand eines Abgasscreenings konnte eine Reihe von Kohlenwasserstoffen (Alkane, Alkene, Alkine, Alkadiene und aromatische Kohlenwasserstoffe) identifiziert werden, die typisch für das Dieselabgas stehen. Die Moleküle Ethin, Ethen und Propen wurden gezielt betrachtet. Die Ergebnisse zeigen, dass bei kalten Betriebsbedingungen diese drei Komponenten etwa die Hälfte der Gesamtkohlenwasserstoffkonzentration ergeben. Ein weiterer Punkt der Untersuchungen war die Diesel-Partikelfilter-Regeneration. Wie erwartet, lassen sich Kohlenwasserstoffmoleküle mit höheren Massen feststellen, die auf unverbrannten Dieselkraftstoff zurückzuführen sind. Anhand der Ergebnisse zeigte sich.dass sich das mit chemischer Ionisation arbeitende Massenspektrometer hervorragend für ein Abgasscreening eignet. Zahlreiche Kohlenwasserstoffe konnten identifiziert werden, die repräsentativ für das Dieselabgas stehen. Es sollten Moleküle bei verschiedenen Motorbetriebsbedingungen untersucht werden, die einen möglichst großen Anteil an der Gesamtkohlenwasserstoffkonzentration besitzen. Die Auswahl fiel aufgrund der gemessenen Massenspektren, vor und nach dem Diesel-Oxidationskatalysator, auf die Komponenten Ethin, Ethen und Propen. Zudem kann bei diesen Molekülen eine Masseninterferenz mit anderen Abgaskomponenten ausgeschlossen werden. Im unteren Teillastbereich und kaltem Motor machen diese Kohlenwasserstoffe bis zu 50%, gemittelt über alle Messstellen vor, im und nach dem Diesel-Oxidationskatalysator, der Gesamtkohlenwasserstoffkonzentration aus. Bei betriebswarmem Motor reduziert sich ihr Anteil auf ein Drittel Die höchste Konzentration unter den drei Komponenten besitzt dabei Propen. Mit steigendem Drehmoment nimmt der Anteil dieser drei Komponenten fortlaufend ab,was dafür spricht, dass Moleküle mit höheren Massen einen höheren Anteil einnehmen. Die Kohlenwasserstoff-Emissionen bewegen sich bei diesen Motorbetriebspunkten mit betriebswarmem Katalysator jedoch bereits bei sehr niedrigen Werten. Während der untersuchten Diesel-Partikelfilter-Regeneration mit späten Nacheinspritzungen zur Abgastemperaturerhöhung lassen sich Moleküle mit höheren Massen nachweisen. Diese sind typisch für die Reinkomponente Dieselkraftstoff. Der Anteil von Ethin, Ethen und Propen an der THC-Konzentration beträgt dann ca. 40%.
Beitrag und Praesentationsmaterial eines Vortrags ueber differenzierende Kohlenwasserstoffanalytik im Dieselabgas bei verschiedenen Motorbetriebszustaenden. Mit einem neu entwickelten, hochgenauen HC-Sensor werden unverbrannte HC im Abgas untersucht. Die differenzierende Untersuchung erfolgt an einem Massenspektrometer, das mit chemischer Ionisation arbeitet. Die Molekuele Ethin, Ethen und Propen wurden gezielt betrachtet. Es zeigt sich, dass bei kalten Betriebsbedingungen diese drei Komponenten etwa die Haelfte der gesamten HC Konzentration ergeben. Ein weiterer Punkt ist die Regeneration des Dieselpartikelfilters.
Recent developments in exhaust gas legislation make it necessary to focus the research at the particulate emissions from gasoline engines and technologies for their reduction. In addition to the particulates resulting from the combustion of the fuel, the oil emissions represent another possible source for particulate emissions. This paper presents a measurement method which can be used to quantify stationary as well as dynamic oil emissions of gasoline engines. Furthermore, the correlation between the oil emissions and the particulate emissions is the focus of the investigations. Conventional methods for the determination of the oil emissions, such as the gravimetric and the volumetric measurement, are unsuitable since they require long engine operation times to provide useful results. These methods therefore do not allow a fast online measurements during the dynamic operation. For this reason, a new measuring method was used, which allows for a time-resolved online measurement of the oil emissions. This measurement method is based on the sulfur tracer method, which uses the sulfur that is naturally contained in the engine oil as a tracer. The sulfur concentration in the exhaust gas is determined by using an Ion-Molecule-Reaction mass spectrometer. The determination of the particulate emissions corresponds to the PMP regulation. The studies carried out under steady state and dynamic conditions show a clear correlation between the oil consumption and the number of particulates in the exhaust gas. In the case of the dynamic measurements it could also be shown that time-resolved measurements of the oil consumption are possible with the used measurement setup. In addition, it was shown that the number of particulates does not influence the measurement of the SO2-concentration. Furthermore, the different effects of burned and unburned oil emissions have been evaluated by the dosing of the oil into the exhaust gas. The overall conclusion of the measurements shows a strong influence of the oil emissions on the particulate emissions. Therefore, it is crucial to reduce the oil emissions. Possible approaches for this reduction can be improved turbocharger sealing concepts, new piston ring designs or more efficient oil separators for the crankcase ventilation system.
