State-of-Charge Monitoring by Impedance Spectroscopy during Long-Term Self-Discharge of Supercapacitors and Lithium-Ion Batteries
- Frequency-dependent capacitance C(ω) is a rapid and reliable method for the determination of the state-of-charge (SoC) of electrochemical storage devices. The state-of-the-art of SoC monitoring using impedance spectroscopy is reviewed, and complemented by original 1.5-year long-term electrical impedance measurements of several commercially available supercapacitors. It is found that the kinetics of the self-discharge of supercapacitors comprises at least two characteristic time constants in the range of days and months. The curvature of the Nyquist curve at frequencies above 10 Hz (charge transfer resistance) depends on the available electric charge as well, but it is of little use for applications. Lithium-ion batteries demonstrate a linear correlation between voltage and capacitance as long as overcharge and deep discharge are avoided.
Author: | Peter KurzweilORCiD, Mikhail Shamonin (Chamonine)ORCiDGND |
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DOI: | https://doi.org/10.3390/batteries4030035 |
Parent Title (English): | Batteries |
Publisher: | MPDI |
Document Type: | Article |
Language: | English |
Year of first Publication: | 2018 |
Release Date: | 2022/03/16 |
Tag: | aging; capacitance; self-discharge; state-of-charge monitoring; supercapacitor |
Volume: | 4 |
Issue: | 3 |
Article Number: | 35 |
First Page: | 1 |
Last Page: | 13 |
Institutes: | Fakultät Elektro- und Informationstechnik |
Fakultät Elektro- und Informationstechnik / Labor Intelligente Materialien und Strukturen | |
Begutachtungsstatus: | peer-reviewed |
OpenAccess Publikationsweg: | Gold Open Access- Erstveröffentlichung in einem/als Open-Access-Medium |
research focus: | Energie und Mobilität |
Licence (German): | Creative Commons - CC BY - Namensnennung 4.0 International |